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Site-occupation embedding theory (SOET) [B. Senjean et al., Phys. Rev. B 97, 235105 (2018)] is an in-principle exact embedding method combining wavefunction theory and density functional theory that gave promising results when applied to…

Strongly Correlated Electrons · Physics 2019-08-01 Bruno Senjean

This article provides the first mathematical analysis of the Density Matrix Embedding Theory (DMET) method. We prove that, under certain assumptions, (i) the exact ground-state density matrix is a fixed-point of the DMET map for…

Mathematical Physics · Physics 2023-10-03 Eric Cancès , Fabian M. Faulstich , Alfred Kirsch , Eloïse Letournel , Antoine Levitt

Site-occupation embedding theory (SOET) is an alternative formulation of density-functional theory (DFT) for model Hamiltonians where the fully-interacting Hubbard problem is mapped, in principle exactly, onto an impurity-interacting…

Strongly Correlated Electrons · Physics 2018-06-13 Bruno Senjean , Naoki Nakatani , Masahisa Tsuchiizu , Emmanuel Fromager

We describe a formulation of the density matrix embedding theory at finite temperature. We present a generalization of the ground-state bath orbital construction that embeds a mean-field finite-temperature density matrix up to a given order…

Strongly Correlated Electrons · Physics 2020-03-04 Chong Sun , Ushnish Ray , Zhi-Hao Cui , Miles Stoudenmire , Michel Ferrero , Garnet Kin-Lic Chan

We study the ground state properties of the one-dimensional extended Hubbard model at half-filling from the perspective of its particle reduced density matrix. We focus on the reduced density matrix of $2$ fermions and perform an analysis…

Strongly Correlated Electrons · Physics 2022-04-11 Diego L. B. Ferreira , Thiago O. Maciel , Reinaldo O. Vianna , Fernando Iemini

In this work, we introduce an original self-consistent scheme based on the one-body reduced density matrix ($\gamma$) formalism. A significant feature of this methodology is the utilization of an optimal unitary transformation of the…

Strongly Correlated Electrons · Physics 2023-11-10 Quentin Marécat , Benjamin Lasorne , Emmanuel Fromager , Matthieu Saubanère

Density matrix embedding theory (DMET) formally requires the matching of density matrix blocks obtained from high-level and low-level theories, but this is sometimes not achievable in practical calculations. In such a case, the global band…

Computational Physics · Physics 2022-01-14 Fabian M. Faulstich , Raehyun Kim , Zhi-Hao Cui , Zaiwen Wen , Garnet Kin-Lic Chan , Lin Lin

In this work we get insight into the impact of reduced density matrix functionals on the quality of removal/addition energies obtained using the Extended Koopmans' Theorem (EKT). Within reduced density matrix functional theory (RDMFT) the…

Strongly Correlated Electrons · Physics 2022-12-26 S. Di Sabatino , J. Koskelo , J. A. Berger , P. Romaniello

We extend density matrix embedding theory to periodic systems, resulting in an electronic band structure method for solid-state materials. The electron correlation can be captured by means of a local impurity model using various choices of…

Strongly Correlated Electrons · Physics 2019-09-27 Hung Q. Pham , Matthew R. Hermes , Laura Gagliardi

We present detailed benchmark ground-state calculations of the one- and two-dimensional Hubbard model utilizing the cluster extensions of the rotationally invariant slave-boson (RISB) mean-field theory and the density matrix embedding…

Strongly Correlated Electrons · Physics 2019-03-27 Tsung-Han Lee , Thomas Ayral , Yong-Xin Yao , Nicola Lanata , Gabriel Kotliar

The equivalence in one-electron quantum bath between the practical implementation of density matrix embedding theory (DMET) and the more recent Householder-transformed density matrix functional embedding theory has been shown previously in…

Chemical Physics · Physics 2023-07-24 Sajanthan Sekaran , Oussama Bindech , Emmanuel Fromager

We study the entanglement spectrum (ES) of the Bose-Hubbard model on the two dimensional square lattice at unit filling, both in the Mott insulating and in the superfluid phase. In the Mott phase, we demonstrate that the ES is dominated by…

Strongly Correlated Electrons · Physics 2013-07-02 Vincenzo Alba , Masudul Haque , Andreas M. Laeuchli

Density matrix embedding theory (DMET) [Phys. Rev. Lett.2012, 109, 186404] has been demonstrated as an efficient wave-function-based embedding method to treat extended systems. Despite its success in many quantum lattice models, the…

Chemical Physics · Physics 2018-03-01 Hung Q. Pham , Varinia Bernales , Laura Gagliardi

This thesis describes the development of the density matrix embedding theory (DMET) and its applications to lattice strongly correlated electron problems, including a review of DMET theory and algorithms (Ch 2), investigation of finite size…

Strongly Correlated Electrons · Physics 2018-03-29 Bo-Xiao Zheng

The Eigenstate Thermalization Hypothesis (ETH) posits that the reduced density matrix for a subsystem corresponding to an excited eigenstate is "thermal." Here we expound on this hypothesis by asking: for which class of operators, local or…

Strongly Correlated Electrons · Physics 2018-05-02 James R. Garrison , Tarun Grover

Site-occupation embedding theory (SOET) is an in-principle-exact multi-determinantal extension of density-functional theory for model Hamiltonians. Various extensions of recent developments in SOET [Senjean et al., Phys. Rev. B 97, 235105…

Strongly Correlated Electrons · Physics 2019-08-06 Bruno Senjean , Naoki Nakatani , Masahisa Tsuchiizu , Emmanuel Fromager

We describe the extension of the density matrix embedding theory (DMET) framework to coupled interacting fermion-boson systems. This provides a frequency-independent, entanglement embedding formalism to treat bulk fermion-boson problems. We…

Strongly Correlated Electrons · Physics 2016-08-17 Barbara Sandhoefer , Garnet Kin-Lic Chan

A density functional theory (DFT) of lattice fermion models is presented, which uses the single-particle density matrix gamma_{ij} as basic variable. A simple, explicit approximation to the interaction-energy functional W[gamma] of the…

Strongly Correlated Electrons · Physics 2009-11-07 R. Lopez-Sandoval , G. M. Pastor

In this work, we derive a multi-fragment real-time extension of projected density matrix embedding theory (pDMET) designed to treat non-equilibrium electron dynamics in strongly correlated systems. As in the previously developed static…

Strongly Correlated Electrons · Physics 2023-04-19 Dariia Yehorova , Joshua S. Kretchmer

We investigate the cluster size convergence of the energy and observables using two forms of density matrix embedding theory (DMET): the original cluster form (CDMET) and a new formulation motivated by the dynamical cluster approximation…

Strongly Correlated Electrons · Physics 2017-01-11 Bo-Xiao Zheng , Joshua S. Kretchmer , Hao Shi , Shiwei Zhang , Garnet Kin-Lic Chan