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To obtain accurate independent-particle descriptions for ferromagnetic two-dimensional van der Waals materials, we apply the quasiparticle self-consistent $GW$ (QSGW) method to VI$_3$, CrI$_3$, CrGeTe$_3$, and Fe$_3$GeTe$_2$. QSGW provides…

Strongly Correlated Electrons · Physics 2020-06-09 Y. Lee , Takao Kotani , Liqin Ke

The homogeneous electron gas (HEG) is a key ingredient in the construction of most exchange-correlation functionals of density-functional theory. Often, the energy of the HEG is parameterized as a function of its spin density $n$, leading…

Chemical Physics · Physics 2021-02-10 Susi Lehtola , Miguel A. L. Marques

The construction of density-functional approximations is explored by modeling the adiabatic connection em locally, using energy densities defined in terms of the electrostatic potential of the exchange-correlation hole. These local models…

Chemical Physics · Physics 2016-05-04 Stefan Vuckovic , Tom Irons , Andreas Savin , Andrew M. Teale , Paola Gori-Giorgi

Semilocal density functional theory is the most used computational method for electronic structure calculations in theoretical solid-state physics and quantum chemistry of large systems, providing good accuracy with a very attractive…

Other Condensed Matter · Physics 2016-03-31 L. A. Constantin , E. Fabiano , J. M. Pitarke , F. Della Sala

We present an ab initio method for eletcronic structure calculations, which accounts for the interaction of electrons and magnons in ferromagnets. While it is based on a many body perturbation theory we approximate numerically complex…

Materials Science · Physics 2023-04-19 S. Paischer , G. Vignale , M. I. Katsnelson , A. Ernst , P. Buczek

The "density-density" correlation function of conduction electrons in metal is investigated. It is shown, that the asymptotic behaviour of the CF depends on the shape and the local geometry of the Fermi surface. In particular, the exponent…

Condensed Matter · Physics 2009-10-22 D. I. Golosov , M. I. Kaganov

The local density approximation (LDA) constructed through quantum Monte Carlo calculations of the homogeneous electron gas (HEG) is the most common approximation to the exchange-correlation functional in density functional theory. We…

Other Condensed Matter · Physics 2021-01-15 Mike Entwistle , Matthew Hodgson , Jack Wetherell , Bradley Longstaff , James Ramsden , Rex Godby

In this work, we present a nonlocal expansion scheme to study correlated electron systems aiming at a better description of its spatial fluctuations at all length scales. Taking the nonlocal coupling as a perturbation to the local degrees…

Strongly Correlated Electrons · Physics 2015-05-05 Gang Li

Density functional theory is the workhorse of modern electronic structure calculations, with wide-ranging applications in chemistry, physics, materials science, and machine learning. At its heart lies the exchange-correlation functional, a…

Chemical Physics · Physics 2026-02-20 Fabien Tran , Susi Lehtola , Stefano Pittalis , Miguel A. L. Marques

The force-balance equation of time-dependent density-functional theory presents a promising route towards obtaining approximate functionals, however, so far, no practical correlation functionals have been derived this way. In this work,…

Chemical Physics · Physics 2025-04-08 Nicolas Tancogne-Dejean , Markus Penz , Michael Ruggenthaler , Angel Rubio

Multiorbital models are important to both the correlation physics and topological behavior of quantum materials. LiFeAs is a prototype iron pnictide suitable for indepth investigation of this issue. Its electronic structure is strikingly…

Superconductivity · Physics 2024-08-01 Huihang Lin , Rong Yu , Jian-Xin Zhu , Qimiao Si

We report extensive self-consistent calculations of jellium surface energies, by going beyond the local-density approximation. The density-response function of a bounded free-electron gas is evaluated within the random-phase approximation,…

Materials Science · Physics 2009-10-31 J. M. Pitarke , A. G. Eguiluz

For more than three decades, nearly free electron elemental metals have been a topic of debate because the computed bandwidths are significantly wider in the local density approximation to density-functional theory (DFT) than indicated by…

Strongly Correlated Electrons · Physics 2022-08-02 Subhasish Mandal , Kristjan Haule , Karin M. Rabe , David Vanderbilt

We present a practical and accurate density functional for the exchange-correlation energy of electrons in two dimensions. The exchange part is based on a recent two-dimensional generalized-gradient approximation derived by considering the…

Strongly Correlated Electrons · Physics 2010-06-30 E. Rasanen , S. Pittalis , J. G. Vilhena , M. A. L. Marques

There is a number of explicit kinetic energy density functionals for non-interacting electron systems that are obtained in terms of the electron density and its derivatives. These semilocal functionals have been widely used in the…

Other Condensed Matter · Physics 2011-12-22 David Garcia-Aldea , J. E. Alvarellos

Quantitatively accurate electronic structure calculations rely on the proper description of electron correlation. A judicious choice of the approximate quantum chemistry method depends upon the importance of dynamic and nondynamic…

Chemical Physics · Physics 2019-05-09 Eloy Ramos-Cordoba , Eduard Matito

The ground-state properties of superfluid nuclear systems with ^1S_0 pairing are studied within a local energy-density functional (LEDF) approach. A new form of the LEDF is proposed with a volume part which fits the Friedman- Pandharipande…

Nuclear Theory · Physics 2011-04-15 S. A. Fayans , D. Zawischa

The Electron Localization Function (ELF) -- as proposed originally by Becke and Edgecombe -- has been widely adopted as a descriptor of atomic shells and covalent bonds. The ELF takes into account the antisymmetry of Fermions but it…

Materials Science · Physics 2015-09-15 Stefano Pittalis , Alain Delgado , Carlo Andrea Rozzi

The Hohenberg-Kohn density functional was long ago shown to reduce to the Thomas-Fermi approximation in the non-relativistic semiclassical (or large-$Z$) limit for all matter, i.e, the kinetic energy becomes local. Exchange also becomes…

Materials Science · Physics 2016-08-24 Kieron Burke , Antonio Cancio , Tim Gould , Stefano Pittalis

We comment on article by Yi Zhang , Hanna Terletska, Ka-Ming Tam, Yang Wang, Markus Eisenbach, Liviu Chioncel, and Mark Jarrell [Phys. Rev. B {\bf 100}, 054205 (2019)]\cite{Zhang} in which to study substitution disordered systems, they…

Mesoscale and Nanoscale Physics · Physics 2020-01-22 Rostam Moradian , Sina Moradian , Rouhollah Gholami