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We use dynamic light scattering and computer simulations to study equilibrium dynamics and dynamic heterogeneity in concentrated suspensions of colloidal hard spheres. Our study covers an unprecedented density range and spans seven decades…

Supercooled liquids exhibit spatial heterogeneity in the dynamics of their fluctuating atomic arrangements. The length and time scales of the heterogeneous dynamics are central to the glass transition and influence nucleation and growth of…

Materials Science · Physics 2018-05-09 Pei Zhang , Jason J. Maldonis , Ze Liu , Jan Schroers , Paul M. Voyles

One of the hallmarks of molecular dynamics in deeply supercooled liquids is the non-exponential character of the relaxation functions. It has been a long standing issue if 'universal' features govern the lineshape of glassy dynamics…

By employing a simplified nonlinear memory function proposed recently by the present author, a universal equation for a collective-intermediate scattering function derived based on the time-convolutionless mode-coupling theory is…

Statistical Mechanics · Physics 2020-05-20 Michio Tokuyama

In polymers melts and supercooled liquids, the glassy dynamics is characterized by the rattling of monomers or particles in the cage formed by their neighbors. Recently, a direct correlation in such systems, described by a universal scaling…

Soft Condensed Matter · Physics 2010-09-09 Cristiano De Michele , Emanuela Del Gado , Dino Leporini

We study the Langevin dynamics of diffusive particles with regular pairwise interactions under mean-field scaling. By approximating empirical distributions with conditional distributions, we establish coercive and contractive properties for…

Probability · Mathematics 2026-05-28 Songbo Wang

We explore several potential issues that have been raised over the years regarding the "entropic droplet" scenario of activated transport in liquids, due to Wolynes and coworkers, with the aim of clarifying the status of various…

Disordered Systems and Neural Networks · Physics 2014-12-05 Vassiliy Lubchenko , Pyotr Rabochiy

Performing molecular dynamics simulations, we investigate the enormous slowdowns of water dynamics when approaching a glass transition or a solid interface. We show that both effects can be described on common grounds within a theoretical…

Soft Condensed Matter · Physics 2015-06-19 Felix Klameth , Michael Vogel

We study dynamic heterogeneities in a model glass-former whose overlap with a reference configuration is constrained to a fixed value. The system phase-separates into regions of small and large overlap, so that dynamical correlations remain…

Disordered Systems and Neural Networks · Physics 2012-07-19 C. Cammarota , A. Cavagna , I. Giardina , G. Gradenigo , T. S. Grigera , G. Parisi , P. Verrocchio

We propose an alternative theory for the relaxation of density fluctuations in glass-forming fluids. We derive an equation of motion for the density correlation function which is local in time and is similar in spirit to the equation of…

Soft Condensed Matter · Physics 2022-06-01 Grzegorz Szamel

The structure, thermodynamics and slow activated dynamics of the equilibrated metastable regime of glass-forming fluids remains a poorly understood problem of high theoretical and experimental interest. We apply a highly accurate…

Soft Condensed Matter · Physics 2024-08-21 Subhashish Chaki , Baicheng Mei , Kenneth S. Schweizer

We numerically elucidate the microscopic mechanisms controlling the relaxation dynamics of a three-dimensional lattice glass model that has static properties compatible with the approach to a random first-order transition. At low…

Disordered Systems and Neural Networks · Physics 2024-02-09 Yoshihiko Nishikawa , Ludovic Berthier

Recent numerical simulations indicate that several different equilibrium glass transitions may be characterized by diverging correlation lengths, and that these divergences are described by a non-mean-field, Ising-like, critical exponent. I…

Statistical Mechanics · Physics 2012-09-26 J. S. Langer

We test a hypothesis for the origin of dynamical heterogeneity in slowly relaxing systems, namely that it emerges from soft (Goldstone) modes associated with a broken continuous symmetry under time reparametrizations. We do this by…

Disordered Systems and Neural Networks · Physics 2013-10-30 Karina E. Avila , Horacio E. Castillo , Azita Parsaeian

We investigate the characteristic length scales associated with the glass transition phenomenon. By studying an atomic glass-forming liquid in negatively curved space, for which the local order is well identified and the amount of…

Statistical Mechanics · Physics 2010-02-10 François Sausset , Gilles Tarjus

We present a quantitative theory for a relaxation function in a simple glass-forming model (binary mixture of particles with different interaction parameters). It is shown that the slowing down is caused by the competition between locally…

Materials Science · Physics 2009-11-13 Edan Lerner , Itamar Procaccia

We study the relaxation dynamics of flux lines in dirty high-temperature superconductors using numerical simulations of a London-Langevin model of the interacting vortex lines. By analysing the equilibrium dynamics in the vortex liquid…

Superconductivity · Physics 2015-06-25 Sebastian Bustingorry , Leticia F. Cugliandolo , Daniel Dominguez

Relaxation dynamics, as a key to understand glass formation and glassy properties, remains an elusive and challenging issue in condensed matter physics. In this work, in situ high-pressure synchrotron high-energy x-ray photon correlation…

We discuss the relaxation dynamics of a simple structural glass which has been quenched below its glass transition temperature. We demonstrate that time correlation functions show strong aging effects and investigate in what way the…

Statistical Mechanics · Physics 2009-10-31 Walter Kob , Jean-Louis Barrat

In a recent publication we established an analogy between the free energy of a hard sphere system and the energy of an elastic network [1]. This result enables one to study the free energy landscape of hard spheres, in particular to define…

Disordered Systems and Neural Networks · Physics 2007-08-08 Carolina Brito , Matthieu Wyart