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The second-order Green's function method (GF2) was shown recently to be an accurate self-consistent approach for electronic structure of correlated systems since the self-energy accounts for both the weak and some of the strong correlation.…

Chemical Physics · Physics 2016-03-31 Daniel Neuhauser , Roi Baer , Dominika Zgid

The second-order Matsubara Green's function method (GF2) is a robust temperature dependent quantum chemistry approach, extending beyond the random-phase approximation. However, till now the scope of GF2 applications was quite limited as…

Chemical Physics · Physics 2017-09-20 Daniel Neuhauser , Roi Baer , Dominika Zgid

We examine fractional charge and spin errors in self-consistent Green's function theory within a second-order approximation (GF2). For GF2 it is known that the summation of diagrams resulting from the self-consistent solution of the Dyson…

Computational Physics · Physics 2016-11-15 Jordan J. Phillips , Alexei A. Kananenka , Dominika Zgid

Despite recent advances, systematic quantitative treatment of the electron correlation problem in extended systems remains a formidable task. Systematically improvable Green's function methods capable of quantitatively describing weak and…

Chemical Physics · Physics 2016-11-15 Alexander A. Rusakov , Dominika Zgid

We report an implementation of self-consistent Green's function many-body theory within a second-order approximation (GF2) for application with molecular systems. This is done by iterative solution of the Dyson equation expressed in matrix…

Chemical Physics · Physics 2016-11-15 Jordan J. Phillips , Dominika Zgid

A stochastic method is described for estimating Green's functions (GF's), appropriate to linear advection-diffusion-reaction transport problems, evolving in arbitrary geometries. By allowing straightforward construction of approximate,…

We present a real-time second-order Green's function (GF) method for computing excited states in molecules and nanostructures, with a computational scaling of $O(N_{\rm e}^3$), where $N_{\rm e}$ is the number of electrons. The cubic scaling…

Chemical Physics · Physics 2024-01-29 Leopoldo Mejía , Jia Yin , David R. Reichman , Roi Baer , Chao Yang , Eran Rabani

We develop a stochastic resolution of identity approach to the real-time second-order Green's function (real-time sRI-GF2) theory, extending our recent work for imaginary-time Matsubara Green's function {\em J. Chem. Phys.} {\bf 151},…

Chemical Physics · Physics 2019-09-17 Wenjie Dou , Tyler Y. Takeshita , Ming Chen , Roi Baer , Daniel Neuhauser , Eran Rabani

We present an approach to renormalized second-order Green's function perturbation theory (GF2) which avoids all dependency on continuous variables, grids or explicit Green's functions, and is instead formulated entirely in terms of static…

Chemical Physics · Physics 2020-06-26 Oliver J. Backhouse , Max Nusspickel , George H. Booth

We apply tensor hypercontraction (THC) to reduce the computational scaling of expensive fully self-consistent Green's function methods. We present an efficient MPI-parallel algorithm and its implementation for evaluating the correlated…

Chemical Physics · Physics 2024-12-30 Pavel Pokhilko , Chia-Nan Yeh , Miguel A. Morales , Dominika Zgid

We present an efficient second-order finite difference scheme for solving the 2D sine-Gordon equation, which can inherit the discrete energy conservation for the undamped model theoretically. Due to the semi-implicit treatment for the…

Numerical Analysis · Mathematics 2017-06-28 Xiaorong Kang , Wenqiang Feng , Kelong Cheng , Chunxiang Guo

Including finite-temperature effects from the electronic degrees of freedom in electronic structure calculations of semiconductors and metals is desired; however, in practice it remains exceedingly difficult when using zero-temperature…

Chemical Physics · Physics 2016-11-24 Alicia Rae Welden , Alexander A. Rusakov , Dominika Zgid

In this work we introduce the Dual Boson Diagrammatic Monte Carlo technique for strongly interacting electronic systems. This method combines the strength of dynamical mean-filed theory for non-perturbative description of local correlations…

Strongly Correlated Electrons · Physics 2020-11-06 M. Vandelli , V. Harkov , E. A. Stepanov , J. Gukelberger , E. Kozik , A. Rubio , A. I. Lichtenstein

A recent technique, proposed to alleviate the ``sign problem disease'', is discussed in details. As well known the ground state of a given Hamiltonian $H$ can be obtained by applying the imaginary time propagator $e^{-H \tau}$ to a given…

Condensed Matter · Physics 2009-10-31 S. Sorella , L. Capriotti

The dual-fermion approach provides a formally exact prescription for calculating properties of a correlated electron system in terms of a diagrammatic expansion around dynamical mean-field theory (DMFT). Most practical implementations,…

Strongly Correlated Electrons · Physics 2017-08-02 Jan Gukelberger , Evgeny Kozik , Hartmut Hafermann

The newly developed Gorkov-Green's function approach represents a promising path to the ab initio description of medium-mass open-shell nuclei. We discuss the implementation of the method at second order with a two-body interaction, with…

Nuclear Theory · Physics 2015-06-17 V. Soma , C. Barbieri , T. Duguet

We present a Green's function technique for studying the nonlinear conductance of a nanocontact system with two electrodes at different chemical potentials. The retarded Green's function for a single-impurity Anderson model with two…

Mesoscale and Nanoscale Physics · Physics 2011-01-04 Jongbae Hong

We present the Stochastic Green Function (SGF) algorithm designed for bosons on lattices. This new quantum Monte Carlo algorithm is independent of the dimension of the system, works in continuous imaginary time, and is exact (no error…

Statistical Mechanics · Physics 2008-11-03 V. G. Rousseau

Background. The Gorkov approach to self-consistent Green's function theory has been formulated in [V. Som\`a, T. Duguet, C. Barbieri, Phys. Rev. C 84, 064317 (2011)]. Over the past decade, it has become a method of reference for…

Nuclear Theory · Physics 2022-04-29 Carlo Barbieri , Thomas Duguet , Vittorio Somà

We present the method of the self-consistent calculation of thermodynamical and correlation functions. This approach is based on the GRPA (generalized random phase approximation) scheme with the inclusion of the mean field corrections.…

Statistical Mechanics · Physics 2016-08-31 I. V. Stasyuk , A. M. Shvaika , K. V. Tabunshchyk
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