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Graphene grown on metal surface, Cu(111), with a boron nitride(BN) buffer layer is studied for the first time. Our first-principles calculations reveal that charge is transferred from the copper substrate to graphene through the BN buffer…

Materials Science · Physics 2007-12-27 Y. H. Lu , P. M. He , Y. P. Feng

The nucleation of graphene on a transition metal (TM) surface, either on a terrace or near a step edge, is systematically explored using density functional theory (DFT) calculations and applying the two-dimensional (2D) crystal nucleation…

Materials Science · Physics 2011-04-04 Junfeng Gao , Joanne Yip , Jijun Zhao , Boris I. Yakobson , Feng Ding

Two-dimensional alloys of carbon and nitrogen represent an urgent interest due to prospective applications in nanomechanical and optoelectronic devices. Stability of these chemical structures must be understood as a function of their…

Materials Science · Physics 2015-02-09 Vitaly V. Chaban , Oleg V. Prezhdo

As a two-dimensional material, graphene can be naturally obtained via epitaxial growth on a suitable substrate. Growth condition optimization usually requires an atomistic level understanding of the growth mechanism. In this article, we…

Materials Science · Physics 2012-04-06 Ping Wu , Huijun Jiang , Wenhua Zhang , Zhenyu Li , Zhonghuai Hou , Jinlong Yang

Graphene nanoflakes (GNFs) were synthesized by atmospheric pressure chemical vapour deposition of propane (C3H8) employing Ni (salen) powder without the introduction of a substrate. The graphitic nature of the GNFs was examined by an X-ray…

Applied Physics · Physics 2019-09-10 Joydip Sengupta , Kaustuv Das , U N Nandi , Chacko Jacob

The healing of graphene grown from a metallic substrate is investigated using tight-binding Monte Carlo simulations. At temperatures (ranging from 1000 to 2500 K), an isolated graphene sheet can anneal a large number of defects suggesting…

Materials Science · Physics 2010-09-02 Sondes Karoui , Hakim Amara , Christophe Bichara , François Ducastelle

Graphene and carbon nanotubes (CNTs) share the same atomic structure of hexagonal carbon lattice. Yet, their synthesis differs in many aspects, including the shape and size of the catalyst. Here, we demonstrate a floating-catalyst chemical…

Nitrogen is frequently included in chemical vapour deposition feed gases to accelerate diamond growth. While there is no consensus for an atomistic mechanism of this effect, existing studies have largely focused on the role of sub-surface…

Materials Science · Physics 2020-11-11 Lachlan M. Oberg , Marietta Batzer , Alastair Stacey , Marcus W. Doherty

The integration of graphene (Gr) with nitride semiconductors is highly interesting for applications in high-power/high-frequency electronics and optoelectronics. In this work, we demonstrated the direct growth of Gr on Al0.5Ga0.5N/sapphire…

We synthesized three-dimensional nanoporous graphene films by a chemical vapor deposition method with nanoporous copper as a catalytic substrate. The resulting nanoporous graphene has the same average pore size as the underlying copper…

Materials Science · Physics 2015-04-20 Zhiqiang Tu , Shangfei Wu , Fan Yang , Yongfeng Li , Liqiang Zhang , Hongwen Liu , Hong Ding , Pierre Richard

Understanding the competition between first-layer lateral expansion and second-layer nucleation is essential for layer-controlled graphene growth via chemical vapor deposition (CVD). Building on our previous phase diagram framework based on…

Materials Science · Physics 2026-05-21 Tongtong Wang , Ke Jin , Yishi Zhang , Dajun Shu

A recent experimental study showed that an induced folded flap of graphene can spontaneously drive itself its tearing and peeling off a substrate, thus producing long, micrometer sized, regular trapezoidal-shaped folded graphene…

Materials Science · Physics 2018-08-28 Alexandre F. Fonseca , Douglas S. Galvao

Understanding the influence that copper substrate surface symmetry and oxygen impurities have on the growth of graphene by chemical vapor deposition is important for developing techniques for producing high quality graphene. Therefore, we…

Large area graphene sheets grown by chemical vapor deposition can potentially be employed as a transparent electrode in photovoltaics if their sheet resistance can be significantly lowered, without any loss in transparency. Here, we report…

Materials Science · Physics 2015-12-16 Ahmed A. Maarouf , Amal Kasry , Bhupesh Chandra , Glenn J. Martyna

The fundamental properties of graphene are making it an attractive material for a wide variety of applications. Various techniques have been developed to produce graphene and recently we discovered the synthesis of large area graphene by…

Graphitic nitrogen-doped graphene is an excellent platform to study scattering processes of massless Dirac fermions by charged impurities, in which high mobility can be preserved due to the absence of lattice defects through direct…

Mesoscale and Nanoscale Physics · Physics 2017-06-05 Jiayu Li , Li Lin , Dingran Rui , Qiucheng Li , Jincan Zhang , Ning Kang , Yanfeng Zhang , Hailin Peng , Zhongfan Liu , H. Q. Xu

Few-layer graphene (FLG) is grown on copper and nickel substrates at high rates using a novel flame synthesis method in open-atmosphere environments. Transmittance and resistance properties of the transferred films are similar to those…

We propose an innovative, easy-to-implement approach to synthesize large-area singlecrystalline graphene sheets by chemical vapor deposition on copper foil. This method doubly takes advantage of residual oxygen present in the gas phase.…

Thermal decomposition of silicon carbide is a promising approach for the fabrication of graphene. However, the atomistic growth mechanism of graphene remains unclear. This paper describes the development of a new charge-transfer interatomic…

Materials Science · Physics 2018-03-13 So Takamoto , Takahiro Yamasaki , Jun Nara , Takahisa Ohno , Chioko Kaneta , Asuka Hatano , Satoshi Izumi

A model for the formation of carbon nanotubes (CNTs) and layered graphene in an arc discharge method is developed on the basis of observed erosion of graphite anode under various experimental conditions and analyses of the morphology of the…

Materials Science · Physics 2019-07-23 Soumen Karmakar