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In this work, the single-component Cu metallic glass was fabricated by the physical vapor deposition on the Zr (0001) crystal substrate at 100 K using the classical molecular dynamic simulation. The same deposition process was performed on…

Materials Science · Physics 2016-07-21 Yang Yu , Yunyun Chen , Fenping Cui

We carried out molecular dynamics simulations (MD) using realistic empirical potentials for the vapor deposition (VD) of CuZrAl glasses. VD glasses have higher densities and lower potential and inherent structure energies than the…

Computational Physics · Physics 2017-09-15 G. B. Bokas , L. Zhao , D. Morgan , I. Szlufarska

Physical vapor deposition (PVD) is widely used in manufacturing ultra-thin layers of amorphous organic solids. Here, we demonstrate that these films exhibit a sharp transition from glassy solid to liquid-like behavior with thickness below…

Soft Condensed Matter · Physics 2016-10-12 Yue Zhang , Ethan Glor , Mu Li , Tianyi Liu , kareem Wahid , William Zhang , Robert Riggleman , Zahra Fakhraai

Glass films prepared by a process of physical vapor deposition have been shown to have thermodynamic and kinetic stability comparable to those of ordinary glasses aged for thousands of years. A central question in the study of…

Soft Condensed Matter · Physics 2016-11-23 Daniel Reid , Ivan Lyubimov , Mark Ediger , Juan de Pablo

Recently, ultrastable glasses have been created through vapor deposition. Subsequently, computer simulation algorithms have been proposed that mimic the vapor deposition process and result in simulated glasses with increased stability. In…

Soft Condensed Matter · Physics 2015-01-15 Hannah Staley , Elijah Flenner , Grzegorz Szamel

Molecular dynamics simulations were performed to study the effects of Si solute on the glass formation and crystallization of Pd liquid. Pure Pd sample prepared by quenching process with cooling rate of $10^{13}$ K/s can be in an amorphous…

Mesoscale and Nanoscale Physics · Physics 2019-02-20 Z. J. Yang , L. Tang , T. Q. Wen , K. M. Ho , C. Z. Wang

Vapor deposition of molecules on a substrate often results in glassy materials of high kinetic stability and low enthalpy. The extraordinary properties of such glasses are attributed to high rates of surface diffusion during sample…

Soft Condensed Matter · Physics 2015-05-20 Deepanjan Bhattacharya , Vlad Sadtchenko

Vapor deposition can yield glasses that are more stable than those obtained by the traditional melt-quenching route. However, it remains unclear whether vapor-deposited glasses are "allowable" or "forbidden," that is, if they are equivalent…

Materials Science · Physics 2020-04-27 Zhe Wang , Tao Du , N. M. Anoop Krishnan , Morten M. Smedskjaer , Mathieu Bauchy

A growing body of experimental work indicates that physical vapor deposition provides an effective route for preparation of stable glasses, whose properties correspond in some cases to those expected for glasses that have been aged for…

Soft Condensed Matter · Physics 2015-06-16 Ivan Lyubimov , Mark D. Ediger , Juan J. de Pablo

Copper sulfide (CuS) has garnered significant attention in various fields of application due to its unique electronic, optical, and catalytic features. In this study, we present the chemical vapor deposition (CVD)-based synthesis of…

Materials Science · Physics 2023-05-16 Abdulsalam Aji Suleiman , Reza Rahighi , Amir Parsi , Talip Serkan Kasırga

We have obtained effective medium theory (EMT) interatomic potential parameters suitable for studying Cu-Mg metallic glasses. We present thermodynamic and structural results from simulations of such glasses over a range of compositions. We…

Materials Science · Physics 2007-05-23 Nicholas P. Bailey , Jakob Schiøtz , Karsten W. Jacobsen

We investigate the low temperature properties of two-dimensional Lennard-Jones glass films, prepared in silico both by liquid cooling and by physical vapor deposition. We identify deep in the solid phase a crossover temperature $T^*$, at…

Soft Condensed Matter · Physics 2018-01-30 Beatriz Seoane , Daniel R. Reid , Juan J. de Pablo , Francesco Zamponi

Glass films created by vapor-depositing molecules onto a substrate can exhibit properties similar to those of ordinary glasses aged for thousands of years. It is believed that enhanced surface mobility is the mechanism that allows vapor…

Soft Condensed Matter · Physics 2017-11-03 Ludovic Berthier , Patrick Charbonneau , Elijah Flenner , Francesco Zamponi

Glasses produced via physical vapor deposition can display greater kinetic stability and lower enthalpy than glasses prepared by liquid cooling. While the reduced enthalpy has often been used as a measure of the stability, it is not obvious…

Soft Condensed Matter · Physics 2016-04-06 Julian Helfferich , Ivan Lyubimov , Daniel Reid , Juan J. de Pablo

Two different preparation methods (liquid-quenching and evaporation) of chalcogenide glasses have been investigated by molecular dynamics simulations. Our particular aim was to determine how the structural changes occur due to the different…

Disordered Systems and Neural Networks · Physics 2016-08-31 J. Hegedus , K. Kohary , S. Kugler

Physically vitrifying single-element metallic glass requires ultrahigh cooling rates, which are still unachievable for most of the closest-packed metals. Here, we report a facile synthetic strategy for creating mono-atomic palladium…

Solid-state amorphization of crystalline copper nanolayers embedded in a Cu64Zr36 metallic glass is studied by molecular dynamics simulations for different orientations of the crystalline layer. We show that solid-state amorphization is…

Materials Science · Physics 2015-05-07 Tobias Brink , Daniel Şopu , Karsten Albe

Despite their technological relevance, a full microscopic understanding of glasses is still lacking. This applies even more to their surfaces whose properties largely differ from that of the bulk material. Here, we experimentally…

Soft Condensed Matter · Physics 2022-11-23 Li Tian , Clemens Bechinger

Glasses obtained from vapor deposition on a cold substrate have superior thermodynamic and kinetic stability with respect to ordinary glasses. Here we perform molecular dynamics simulations of vapor deposition of a model glass-former and…

Soft Condensed Matter · Physics 2023-05-24 Fabio Leoni , Fausto Martelli , C. Patrick Royall , John Russo

The extreme slowing down associated with glass formation in experiments and in simulations results in serious difficulties to prepare deeply quenched, well annealed, glassy material. Recently, methods to achieve such deep quenching were…

Soft Condensed Matter · Physics 2020-07-08 Bhanu Prasad Bhowmik , Valery Iylin , Itamar Procaccia
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