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Accurate theoretical prediction of the band offsets at interfaces of semiconductor heterostructures can often be quite challenging. Although density functional theory has been reasonably successful to carry out such calculations and…

Photo-induced switching from the low-spin state to the high-spin state is studied in a model of spin-crossover materials, in which long-range interactions are induced by elastic distortions due to different molecular sizes the two spin…

Statistical Mechanics · Physics 2015-05-13 Seiji Miyashita , Per Arne Rikvold , Takashi Mori , Yusuké Konishi , Masamichi Nishino , Hiroko Tokoro

We theoretically study the crossover between spin Hall effect and spin swapping, a recently predicted phenomenon that consists in the interchange between the current flow and its spin polarization directions [Lifshits and Dyakonov, Phys.…

Mesoscale and Nanoscale Physics · Physics 2015-05-15 Hamed Ben Mohamed Saidaoui , Y. Otani , A. Manchon

The total energies and the spin states for atoms and their first ions with Z = 1-86 are calculated within the the local spin-density approximation (LSDA) and the generalized-gradient approximation (GGA) to the exchange-correlation (xc)…

Chemical Physics · Physics 2015-05-20 Eli Kraisler , Guy Makov , Itzhak Kelson

In modeling low-dimensional electronic nanostructures, the evaluation of the electron-electron interaction is a challenging task. Here we present an accurate and practical density-functional approach to the two-dimensional many-electron…

Strongly Correlated Electrons · Physics 2010-10-29 S. Pittalis , E. Rasanen

Through the introduction of a new electron spin transport mechanism, a 2D donor electron spin quantum computer architecture is proposed. This design addresses major technical issues in the original Kane design, including spatial…

Quantum Physics · Physics 2010-06-29 L. C. L. Hollenberg , A. D. Greentree , A. G. Fowler , C. J. Wellard

The spin-crossover in organometallic molecules constitutes one of the most promising routes towards the realization of molecular spintronic devices. In this article, we explore the hybridization-induced spin-crossover in metal-organic…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Jakob Steinbauer , Silke Biermann , Sumanta Bhandary

Using the strongly constrained and appropriately normed (SCAN) and SCAN+U approximations for describing electron exchange-correlation (XC) within density functional theory, we investigate the oxidation energetics, lattice constants, and…

Materials Science · Physics 2018-09-27 Gopalakrishnan Sai Gautam , Emily A. Carter

We study the spin-crossover molecule Fe(phen)$_2$(NCS)$_2$ using density functional theory (DFT) plus dynamical mean-field theory, which allows access to observables not attainable with traditional quantum chemical or electronic structure…

Materials Science · Physics 2015-06-30 Jia Chen , Andrew Millis , Chris Marianetti

Spin-crossover compounds, which are characterized by magnetic ions showing low-spin and high-spin states at thermally accessible energies, are ubiquitous in nature. We here focus on the effect of an exchange interaction on the collective…

Statistical Mechanics · Physics 2009-11-13 Carsten Timm , Charles J. Pye

In recent work, generalized gradient approximations (GGA's) have been constructed from the energy density of the Airy gas for exchange but not for correlation. We report the random phase approximation (RPA) conventional correlation energy…

Materials Science · Physics 2009-06-30 Lucian A. Constantin , Adrienn Ruzsinszky , John P. Perdew

The electron density, its gradient, and the Kohn-Sham orbital kinetic energy density are the local ingredients of a meta-generalized gradient approximation (meta-GGA). We construct a meta-GGA density functional for the exchange-correlation…

Materials Science · Physics 2009-02-20 Jianmin Tao , John P. Perdew , Viktor N. Staroverov , Gustavo E. Scuseria

The concept of swapping the two most important spin interactions -- exchange and spin-orbit coupling -- is proposed based on two-dimensional multilayer van der Waals heterostructures. Specifically, we show by performing realistic ab initio…

Mesoscale and Nanoscale Physics · Physics 2020-11-05 Klaus Zollner , Martin Gmitra , Jaroslav Fabian

Substitutional donor atoms in silicon are promising qubits for quantum computation with extremely long relaxation and dephasing times demonstrated. One of the critical challenges of scaling these systems is determining inter-donor distances…

Efforts to achieve efficient injection of spin-polarized electrons into a semiconductor, a key prerequisite for developing electronics that exploit the electron's spin degree of freedom, have so far met with limited success. Here we report…

Mesoscale and Nanoscale Physics · Physics 2015-06-12 Sarmita Majumder , Bartek Kardasz , George Kirczenow , Anthony SpringThorpe , Karen L. Kavanagh

A new method of computing multipolar exchange interaction in spin-orbit coupled systems is developed using multipolar tensor expansion of the density matrix in LDA+U electronic structure calculation. Within mean-field approximation,…

Strongly Correlated Electrons · Physics 2014-03-06 Shu-Ting Pi , Ravindra Nanguneri , Sergey Savrasov

Spin is a fundamental property of any many-electron system. The ability of density functional theory to accurately predict the physical properties of a system, while varying its spin, is crucial for describing magnetic materials and…

Chemical Physics · Physics 2024-11-05 Alon Hayman , Eli Kraisler , Tamar Stein

In electronics, information has been traditionally stored, processed and communicated using an electron's charge. This paradigm is increasingly turning out to be energy-inefficient, because movement of charge within an…

Mesoscale and Nanoscale Physics · Physics 2009-09-22 Supriyo Bandyopadhyay , Marc Cahay

Electronic structure calculations are routinely carried out within the framework of density-functional theory, often with great success. For electrons in reduced dimensions, however, there is still a need for better approximations to the…

Strongly Correlated Electrons · Physics 2009-09-22 S. Pittalis , E. Rasanen , E. K. U. Gross

Unlike the local density approximation (LDA) and the generalized gradient approximation (GGA), calculations with meta-generalized gradient approximations (meta-GGA) are usually done according to the generalized Kohn-Sham (gKS) formalism.…

Materials Science · Physics 2016-06-01 Zeng-hui Yang , Haowei Peng , Jianwei Sun , John P. Perdew