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The aromatic molecule benzene is considered the essential building block for larger polycyclic aromatic hydrocarbons (PAHs) in space. Despite benzene's importance in the formation of PAHs, the formation mechanisms of interstellar benzene…

Astrophysics of Galaxies · Physics 2025-02-26 G. S. Kocheril , C. Zagorec-Marks , H. J. Lewandowski

Interstellar Polycyclic Aromatic Hydrocarbon (PAH) molecules exist in diverse forms depending on the local physical environment. Formation of ionized PAHs (anions and cations) is favourable in the extreme conditions of the ISM. Besides in…

Astrophysics of Galaxies · Physics 2017-12-27 Mridusmita Buragohain , Amit Pathak , Peter Sarre , Nand Kishor Gour

Using atomistic simulations, we characterize the adsorption process of organic molecules on carbon nanoparticles, both of which have been reported to be abundant in the interstellar medium (ISM). It is found that the aromatic organics are…

Astrophysics of Galaxies · Physics 2018-11-14 H. Qi , S. Picaud , M. Devel , E. liang , Z. Wang

Although H$_{2}$ is the simplest and the most abundant molecule in the Universe, its formation in the interstellar medium, especially in the photodissociation regions is far from being fully understood. According to suggestions, the…

Astrophysics of Galaxies · Physics 2023-07-26 David P. Jelenfi , Anita Schneiker , Attila Tajti , Gabor Magyarfalvi , Gyorgy Tarczay

Polycyclic aromatic hydrocarbons (PAHs) and fullerenes play a major role in the physics and chemistry of the interstellar medium. Based on a number of recent experimental and theoretical investigations we developed a model in which PAHs are…

Astrophysics of Galaxies · Physics 2022-11-09 M. S. Murga , V . V. Akimkin , D. S. Wiebe

Nitrogen-bearing polycyclic aromatic hydrocarbons (N-PAHs) are key precursors to complex organic molecules in both the interstellar medium and the nitrogen-rich planetary atmospheres. Despite the recent detections of nitrogen-functionalized…

To investigate the gas-phase hydrogenation processes of large, astronomically relevant cationic polycyclic aromatic hydrocarbon (PAH) molecules under the interstellar environments, the ion-molecule collision reaction between six PAH cations…

Astrophysics of Galaxies · Physics 2024-05-28 Lijun Hua , Xiaoyi Hu , Junfeng Zhen , Xuejuan Yang

The formation of Polycyclic Aromatic Hydrocarbons in the circumstellar outflows of evolved stars is reviewed, with an emphasis on carbon stars on the Asymptotic Giant Branch. Evidence for PAHs present in their winds is provided by…

Solar and Stellar Astrophysics · Physics 2015-05-20 Isabelle Cherchneff

Two key questions of the chemistry of Polycyclic Aromatic Hydrocarbons (PAHs) in the interstellar medium (ISM) are addressed: i) the way carbon is returned from PAHs to the interstellar gas after the very efficient accretion of C+ ions onto…

Astrophysics of Galaxies · Physics 2025-05-14 Alain Omont , Holger F. Bettinger

The high interstellar abundances of polycyclic aromatic hydrocarbons (PAHs) and their size distribution are the result of complex chemical processes implying dust, UV radiation, and the main gaseous components (H, C+, and O). These…

Astrophysics of Galaxies · Physics 2021-07-07 A. Omont , H. F. Bettinger

We present a model for the hydrogenation states of Polycyclic Aromatic Hydrocarbons (PAHs) in the diffuse interstellar medium. First, we study the abundance of hydrogenation and charge states of PAHs due to photo-ionization,…

Astrophysics · Physics 2007-05-23 My Ha Vuong , Bernard H. Foing

Methylated polycyclic aromatic hydrocarbons (PAHs) have been hypothesised to be present in the interstellar medium (ISM) through their 3.4 and 6.9 $\mu$m absorption bands. To investigate the hydrogenation of these methylated PAHs, the…

Astrophysics of Galaxies · Physics 2026-02-11 A. T. Hopkinson , F. G. Doktor , J. Pitfield , M. Moll , J. D. Thrower , L. Hornekær

The fullerene C$_{60}$, one of the largest molecules identified in the interstellar medium (ISM), has been proposed to form top-down through the photo-chemical processing of large (more than 60 C-atoms) polycyclic aromatic hydrocarbon (PAH)…

Instrumentation and Methods for Astrophysics · Physics 2019-02-20 Weiwei Zhang , Yubing Si , Junfeng Zhen , Tao Chen , Harold Linnartz , Alexander G. G. M. Tielens

Interstellar polycyclic aromatic hydrocarbon (PAHs) are an important component of the interstellar medium of galaxies, containing some 10 percent of the elemental carbon. Their vibrational emission dominates the mid-infrared spectra of…

Astrophysics of Galaxies · Physics 2026-03-06 A. G. G. M. Tielens

The physical and chemical conditions in photodissociation regions (PDRs) are largely determined by the influence of far ultraviolet radiation. Far-UV photons can efficiently dissociate molecular hydrogen, a process that must be balanced at…

Astrophysics of Galaxies · Physics 2018-06-08 P. Castellanos , A. Candian , H. Andrews , A. G. G. M. Tielens

In order to find out capable molecular source of astronomically well observed infrared (IR) spectrum, asymmetric molecular configuration polycyclic aromatic hydrocarbon (PAH) was analyzed by the density functional theory (DFT) analysis.…

Astrophysics of Galaxies · Physics 2015-10-27 Norio Ota

Polycyclic Aromatic Hydrocarbons (PAHs) are considered as a major constituent of interstellar dust. They have been proposed as the carriers of the Aromatic Infrared Bands (AIBs) observed in emission in the mid-IR. They likely have a…

Astrophysics of Galaxies · Physics 2009-04-22 C. Joblin , O. Berne , A. Simon , G. Mulas

Evolved stars are primary sources for the formation of polycyclic aromatic hydrocarbons (PAHs) and dust grains. Their circumstellar chemistry is usually designated as either oxygen-rich or carbon-rich, although dual-dust chemistry objects,…

Solar and Stellar Astrophysics · Physics 2015-12-23 N. L. J. Cox , P. Pilleri , O. Berne , J. Cernicharo , C. Joblin

Polycyclic aromatic hydrocarbons (PAHs) are some of the major dust components in the interstellar medium (ISM). We present our evolution models for the abundance of PAHs in the ISM on a galaxy-evolution timescale. We consider shattering of…

Astrophysics of Galaxies · Physics 2015-06-18 Ji Yeon Seok , Hiroyuki Hirashita , Ryosuke S. Asano

Hydrogen depleted environments are considered an essential requirement for the formation of fullerenes. The recent detection of C60 and C70 fullerenes in what was interpreted as the hydrogen-poor inner region of a post-final helium shell…

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