Related papers: Spin state crossover in Co3BO5
The coupled valence and spin state transition (VSST) taking place in (Pr0.7Sm0.3)0.7Ca0.3CoO3 was investigated by soft x-ray absorption spectroscopy (XAS) experiments carried out at the Pr-M4,5, Co-L2,3, and O-1s edges. This VSST is found…
The structural and magnetic properties of two mixed-valence cobaltites with formal population of 0.30 Co$^{4+}$ ions per f.u., (Pr$_{1-y}$Y$_{y}$)$_{0.7}$Ca$_{0.3}$CoO$_3$ ($y=0$ and 0.15), have been studied down to very low temperatures by…
In this paper we have studied, by means of high-resolution neutron powder diffraction and magnetic susceptibility, the structural and magnetic features of selected samples of the HoBaCo2O5+delta layered cobaltite in the low oxygen content…
We have systematically investigated the influence of gradual replacement of Ca by Gd on the magnetic and complex dielectric properties of the well-known geometrically frustrated spin-chain system, Ca3Co2O6 (T_N= 24 K with additional…
We present the study of magnetization, thermal expansion, specific heat, resistivity, and a.c. susceptibility of (Pr$_{1-y}$Eu$_y$)$_{0.7}$Ca$_{0.3}$CoO$_3$ cobaltites. The measurements were performed on ceramic samples with $y = 0.12 -…
A positive muon spin rotation and relaxation ($\mu^+$SR) experiment on [Ca$_2$CoO$_3$]$_{0.62}$[CoO$_2$], ({\sl i.e.}, Ca$_3$Co$_4$O$_9$, a layered thermoelectric cobaltite) indicates the existence of two magnetic transitions at $\sim$ 100…
Solid solutions of the magnetic insulators Ba3Cr2O8 and Sr3Cr2O8 (Ba3-xSrxCr2O8) have been prepared in polycrystalline form for the first time. Single crys- talline material was obtained using a mirror image floating zone technique. X-ray…
We have investigated the valence, spin, and orbital state of the Co ions in the one-dimensional cobaltate Ca3Co2O6 using x-ray absorption and x-ray magnetic circular dichroism at the Co-L2,3 edges. The Co ions at both the octahedral Co_oct…
The electronic structure of the perovskite LaCoO$_3$ for different spin states of Co ions was calculated in the LDA+U approach. The ground state was found to be a nonmagnetic insulator with Co ions in a low-spin state. Somewhat higher in…
The crystalline structure, magnetism, and magnetocaloric effect of a GdCrO$_3$ single crystal grown with the laser-diode-heated floating-zone technique have been studied. The GdCrO$_3$ single crystal crystallizes into an orthorhombic…
We present single-crystal neutron-diffraction data for the spin-chain compound Ca3Co2O6. The intensity and line shapes of the two families of Bragg peaks characterising both the antiferromagnetic and the ferromagnetic components of the…
The low temperature properties of the Kagome-type system Co3V2O8 have been studied by powder neutron diffraction both in zero field and in applied magnetic field of up to 8 T. Below 6 K, the zero-field ground state is ferromagnetic with the…
NMR studies have been carried out on a single crystal sample of TbBaCo2O5.5 with the oxygen-deficient perovskite structure. We have also carried out neutron diffraction studies and added new results to our previously published data. By…
By means of neutron scattering we have determined new branches of magnetic excitations in orbitally active CoO (TN=290 K) up to 15 THz and for temperatures from 6 K to 450 K. Data were taken in the (111) direction in six single-crystal…
We present a study of the structure, the electric resistivity, the magnetic susceptibility, and the thermal expansion of La$_{1-x}$Eu$_x$CoO$_3$. LaCoO$_3$ shows a temperature-induced spin-state transition around 100 K and a metal-insulator…
Transport, thermal and magnetic measurements have been carried out on (Pr1-ySmy)1-xCaxCoO3. The system exhibits a structural phase transition accompanied by the spin state change from the intermediate spin (IS) state to the low spin (LS)…
Single crystals of a metal organic complex \ce{(C5H12N)CuBr3} (\ce{C5H12N} = piperidinium, pipH for short) have been synthesized and the structure was determined by single-crystal X-ray diffraction. \ce{(pipH)CuBr3} crystallizes in the…
We have studied the thermodynamic properties of single-crystalline TbFe3(BO3)4. Magnetization measurements have been carried out as a function of magnetic field (up to 50 T) and temperature up to 350K with the magnetic field both parallel…
The layered perovskites $R$Cr(BO$_3$)$_2$ ($R$ = Y and Ho) with magnetic triangular lattices were studied by performing ac/dc susceptibility, specific heat, elastic and inelastic neutron scattering, and dielectric constant measurements. The…
We have performed non-resonant x-ray diffraction, resonant soft and hard x-ray magnetic diffraction, soft x-ray absorption and x-ray magnetic circular dichroism measurements to clarify the electronic and magnetic states of the Co3+ ions in…