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Methanol, one of the simplest complex organic molecules in the Interstellar Medium (ISM), has been shown to be present and extended in cold environments such as starless cores. We aim at studying methanol emission across several starless…

Astrophysics of Galaxies · Physics 2021-12-22 S. Spezzano , A. Fuente , P. Caselli , A. Vasyunin , D. Navarro-Almaida , M. Rodríguez-Baras , A. Punanova , C. Vastel , V. Wakelam

Complex organic molecules (COMs) in starless cores provide critical insights into the early stages of star formation and prebiotic chemistry. We present a chemical survey of 16 starless cores (including five prestellar cores) in the Orion A…

Cold cores are an early step of star formation, characterized by densities > 10$^4$ cm$^{-3}$, low temperatures (< 15 K), and very low external UV radiation. We investigate the physico-chemical processes at play to tracing the origin of…

Astrophysics of Galaxies · Physics 2023-01-04 A. Taillard , V. WakelaM , P. Gratier , E. Dartois , M. Chabot , J. A. Noble , J. V. Keane , A. C. A. Boogert , D. Harsono

Molecular emission is a powerful tool for studying the physical and chemical structures of dense cores. The distribution and abundance of different molecules provide information on the chemical composition and physical properties in these…

Astrophysics of Galaxies · Physics 2025-07-31 K. Giers , S. Spezzano , Y. Lin , M. T. Valdivia-Mena , P. Caselli , O. Sipilä

Formaldehyde is a key precursor in the formation routes of many complex organic molecules (COMs) in space. It is also an intermediate step in CO hydrogenation sequence that leads to methanol formation on the surface of interstellar grains…

Astrophysics of Galaxies · Physics 2025-02-04 A. F. Punanova , K. Borshcheva , G. S. Fedoseev , P. Caselli , D. S. Wiebe , A. I. Vasyunin

The inheritance of material across the star and planet formation process is traced by deuterium fractionation. We report here the first detection of doubly deuterated methanol towards pre-stellar cores. We study the deuterium fractionation…

Astrophysics of Galaxies · Physics 2023-01-11 Yuxin Lin , Silvia Spezzano , Paola Caselli

The detection of complex organic molecules (COMs) toward dense, collapsing prestellar cores has sparked interest in the fields of astrochemistry and astrobiology, yet the mechanisms for COM formation are still debated. It was originally…

Astrophysics of Galaxies · Physics 2023-04-05 Samantha Scibelli , Yancy Shirley

The presence of methyl alcohol or methanol (CH$_3$OH) in several astrophysical environments has been characterized by its high abundance that depends on both the production rate and the destruction rate. In the present work, the…

Astrophysics · Physics 2008-11-26 S. Pilling , R. Neves , A. C. F. Santos , H. M. Boechat-Roberty

Isotopic fractionation is a very powerful tool to follow the evolution of material from one stage to the next in the star-formation process. Pre-stellar cores exhibit some of the highest levels of deuteration because their physical…

Astrophysics of Galaxies · Physics 2026-02-20 S. Spezzano , W. Riedel , P. Caselli , O. Sipilä , Y. Lin , H. A. Bunn , E. Redaelli , L. H. Coudert , A. Megías , I. Jimenez-Serra

The destiny of complex organic molecules (COMs) in star-forming regions is interlinked with various evolutionary phases. Therefore, identifying these species in diversified environments of identical star-forming regions would help to…

The deuteration of molecules forming in the ices such as methanol (CH$_3$OH) is sensitive to the physical conditions during their formation in dense cold clouds and can be probed through observations of deuterated methanol in hot cores.…

Dense cloud cores present chemical differentiation due to the different distribution of C-bearing and N-bearing molecules, the latter being less affected by freeze-out onto dust grains. In this letter we show that two C-bearing molecules,…

Astrophysics of Galaxies · Physics 2016-08-17 Silvia Spezzano , Luca Bizzocchi , Paola Caselli , Jorma Harju , Sandra Brünken

Recent observations indicate that organic molecules are prevalent towards starless and prestellar cores. Deuteration of these molecules has not been well-studied during the starless phase. Published observations of singly-deuterated…

Astrophysics of Galaxies · Physics 2020-12-02 Hannah E. Ambrose , Yancy L. Shirley , Samantha Scibelli

Pre-stellar cores represent the earliest stage of the star- and planet-formation process. By characterizing the physical and chemical structure of these cores we can establish the initial conditions for star and planet formation and…

Astrophysics of Galaxies · Physics 2023-07-05 S. S. Jensen , S. Spezzano , P. Caselli , T. Grassi , T. Haugbølle

Methanol is a key species in astrochemistry since it is the most abundant organic molecule in the ISM and is thought to be the mother molecule of many complex organic species. Estimating the deuteration of methanol around young protostars…

(Abridged) We present evidence that low-mass starless cores, the simplest units of star formation, are systematically differentiated in their chemical composition. Molecules including CO and CS almost vanish near the core centers, where the…

Astrophysics · Physics 2008-11-26 M. Tafalla , P. C. Myers , P. Caselli , C. M. Walmsley , C. Comito

The aim of this study is to investigate the distribution and excitation of the methanol gas around Cep A and to describe the physical conditions of the region. In addition the large scale abundance distribution is determined in order to…

The study of deuteration in pre-stellar cores is important to understand the physical and chemical initial conditions in the process of star formation. In particular, observations toward pre-stellar cores of methanol and deuterated…

Context. Recent Monte Carlo simulations and laboratory studies of interstellar ices have proposed an alternative pathway involving the radical-molecule H-atom abstraction reaction in the overall mechanism of methanol (CH3OH) formation in…

Astrophysics of Galaxies · Physics 2026-01-14 K. -Y. Huang , E. Méndez-Robayo , S. Viti , Mario -A. Higuera -G

Methanol (CH$_3$OH) is found to be abundant and widespread towards the Central Molecular Zone, the inner few hundred parsecs of our Galaxy. Its origin is, however, not fully understood. It was proposed that the high cosmic ray ionisation…

Astrophysics of Galaxies · Physics 2017-01-25 Audrey Coutens , Jonathan M. C. Rawlings , Serena Viti , David A. Williams
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