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We propose and computationally study a method for simultaneously orienting the angular momentum of asymmetric top molecules along: 1) a laboratory-fixed direction; 2) the molecular intermediate moment of inertia axis; 3) the laser field…

Quantum Physics · Physics 2022-11-21 Emil J. Zak

The control of ultrafast molecular rotational motion has benefited from the development of innovative techniques in strong-field laser physics. Here, we theoretically demonstrate a novel type of coherent control by inducing rotation of an…

Chemical Physics · Physics 2018-08-27 Alec Owens , Andrey Yachmenev , Jochen Küpper

Since its invention in 1999, optical centrifuge has become a powerful tool for controlling molecular rotation and studying molecular dynamics and molecular properties at extreme levels of rotational excitation. The technique has been…

Instrumentation and Detectors · Physics 2020-05-20 Ian MacPhail-Bartley , Walter W. Wasserman , Alexander A. Milner , V. Milner

We demonstrate experimentally a method of all-optical selective rotational control in gas mixtures. Using an optical centrifuge - an intense laser pulse whose linear polarization rotates at an accelerated rate, we simultaneously excite two…

Chemical Physics · Physics 2024-06-19 P. Amani , A. A. Milner , V. Milner

We demonstrate experimentally a method of varying the degree of directionality in laser-induced molecular rotation. To control the ratio between the number of clockwise and counter-clockwise rotating molecules (with respect to a fixed…

Chemical Physics · Physics 2021-05-05 Alexander A. Milner , Valery Milner

We introduce a new optical tool - a "two-dimensional optical centrifuge", capable of aligning molecules in extreme rotational states. Unlike the conventional centrifuge, which confines the molecules in the plane of their rotation, its…

Chemical Physics · Physics 2016-05-18 A. A. Milner , A. Korobenko , V. Milner

We introduce a new scheme for controlling the sense of molecular rotation. By varying the polarization and the delay between two ultrashort laser pulses, we induce unidirectional molecular rotation, thereby forcing the molecules to rotate…

Quantum Physics · Physics 2015-05-13 Sharly Fleischer , Yuri Khodorkovsky , Yehiam Prior , Ilya Sh. Averbukh

Laser control of molecular rotation is an area of active research. A number of recent studies has aimed at expanding the reach of rotational control to extreme, previously inaccessible rotational states, as well as controlling the…

Quantum Physics · Physics 2015-01-13 V. Milner , J. W. Hepburn

We use an optical centrifuge to align asymmetric top $\mathrm{SO_2}$ molecules by adiabatically spinning their most polarizable O-O axis. The effective centrifugal potential in the rotating frame confines sulfur atoms to the plane of the…

Chemical Physics · Physics 2016-05-11 A. Korobenko , V. Milner

We experimentally demonstrate that the rotation of molecules embedded in helium nanodroplets can be controlled with an optical centrifuge, allowing for the study of molecular dynamics inside the strongly interacting many-body environment of…

Quantum Physics · Physics 2025-11-11 Ian MacPhail-Bartley , Alexander A. Milner , Frank Stienkemeier , Valery Milner

An optical centrifuge is a laser pulse which enables controlled rotational excitation of molecules. Centrifuged molecules rotating with well-defined angular frequencies are ideal candidates to probe many-body quantum systems at the…

Chemical Physics · Physics 2025-10-10 K. Wang , A. Hardikar , A. A. Milner , V. Milner

The rich information content of measurements in the molecular frame rather than the laboratory frame has motivated the development of several methods for aligning gas phase molecules in space. Even so, for asymmetric tops the problem of…

Atomic Physics · Physics 2016-11-23 Varun Makhija , Xiaoming Ren , Drue Gockel , Anh-Thu Le , Vinod Kumarappan

Several laser techniques have been suggested and demonstrated recently for preparing polarizable molecules in rapidly spinning states with a disc-like angular distribution. We consider motion of these spinning discs in inhomogeneous fields,…

Chemical Physics · Physics 2015-05-20 Johannes Floss , Erez Gershnabel , Ilya Sh. Averbukh

We experimentally study the optical- and terahertz- induced rotational dynamics of asymmetric molecules in the gas phase. Terahertz and optical fields are identified as two distinct control handles over asymmetric molecules, as they couple…

Chemical Physics · Physics 2016-09-07 Ran Damari , Shimshon Kallush , Sharly Fleischer

We investigate theoretically the ability of an optical centrifuge - a laser pulse whose linear polarization is rotating at an accelerated rate, to control molecular rotation in the regime when the rigid-rotor approximation breaks down due…

Quantum Physics · Physics 2025-12-11 J. M. García-Garrido , V. Milner , C. P. Koch , R. González-Férez

Inducing and controlling the ultrafast molecular rotational dynamics using shaped laser fields is essential in numerous applications. Several approaches exist that allow following the coherent molecular motion in real-time, including…

We use an optical centrifuge to excite coherent rotational wave packets in N$_2$O, CS$_2$ and OCS molecules with rotational quantum numbers reaching up to J=465, 690 and 1186, respectively. Time-resolved rotational spectroscopy at such…

Chemical Physics · Physics 2017-10-25 A. A. Milner , A. Korobenko , J. W. Hepburn , V. Milner

Alignment and orientation of molecules by intense, ultrashort laser fields are crucial for a variety of applications in physics and chemistry. These include control of high harmonics generation, molecular orbitals tomography, control of…

We consider deflection of polarizable molecules by inhomogeneous optical fields, and analyze the role of molecular orientation and rotation in the scattering process. It is shown that molecular rotation induces spectacular rainbow-like…

Quantum Physics · Physics 2015-05-19 E. Gershnabel , I. Sh. Averbukh

The capability to control molecular rotation for field-free orientation, which arranges molecules in specific spatial directions without external fields, is crucial in physics, chemistry, and quantum information science. However,…

Quantum Physics · Physics 2025-12-25 Qian-Qian Hong , Zhe-Jun Zhang , Chuan-Cun Shu , Jun He , Daoyi Dong , Dajun Ding
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