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An isolated system of interacting quantum particles is described by a Hamiltonian operator. Hamiltonian models underpin the study and analysis of physical and chemical processes throughout science and industry, so it is crucial they are…

Hamiltonian learning is an important procedure in quantum system identification, calibration, and successful operation of quantum computers. Through queries to the quantum system, this procedure seeks to obtain the parameters of a given…

Quantum Physics · Physics 2023-08-25 Arkopal Dutt , Edwin Pednault , Chai Wah Wu , Sarah Sheldon , John Smolin , Lev Bishop , Isaac L. Chuang

In quantum mechanics, predictions are made by way of calculating expectation values of observables, which take the form of Hermitian operators. It is far less common to exploit non-Hermitian operators to perform measurements. Here, we show…

Quantum Physics · Physics 2015-11-04 Eliot Bolduc , Genevieve Gariepy , Jonathan Leach

The quantum circuit model is the de-facto way of designing quantum algorithms. Yet any level of abstraction away from the underlying hardware incurs overhead. In the era of near-term, noisy, intermediate-scale quantum (NISQ) hardware with…

Quantum Physics · Physics 2021-08-27 Laura Clinton , Johannes Bausch , Toby Cubitt

We study the efficiency of algorithms simulating a system evolving with Hamiltonian $H=\sum_{j=1}^m H_j$. We consider high order splitting methods that play a key role in quantum Hamiltonian simulation. We obtain upper bounds on the number…

Quantum Physics · Physics 2010-10-12 Anargyros Papageorgiou , Chi Zhang

A Hamiltonian based approach using spatially localized projection operators is introduced to give precise meaning to the chemically intuitive idea of the electronic energy on a quantum subsystem. This definition facilitates the study of…

Quantum Physics · Physics 2015-06-11 Yaser R. Khan , Paul Brumer

By use of the recently derived $universal$ discrete imaginary-time propagator of the harmonic oscillator, both thermodynamic and Hamiltonian energies can be given analytically, and evaluated numerically at each imaginary time step, for…

Quantum Physics · Physics 2024-07-01 Siu A. Chin

Ground-state preparation for a given Hamiltonian is a common quantum-computing task of great importance and has relevant applications in quantum chemistry, computational material modeling, and combinatorial optimization. We consider an…

Quantum Physics · Physics 2022-10-18 Yu-Qin Chen , Shi-Xin Zhang , Chang-Yu Hsieh , Shengyu Zhang

In quantum mechanics the time operator $\Theta$ satisfies the commutation relation $[\Theta,H]=i$, and thus it may be thought of as being canonically conjugate to the Hamiltonian $H$. The time operator associated with a given Hamiltonian…

High Energy Physics - Theory · Physics 2015-06-03 Carl M. Bender , M. Gianfreda

Over the last few decades, developments in the physical limits of computing and quantum computing have increasingly taught us that it can be helpful to think about physics itself in computational terms. For example, work over the last…

Quantum Physics · Physics 2007-05-23 Michael P. Frank

Computing many-body ground state energies and resolving electronic structure calculations are fundamental problems for fields such as quantum chemistry or condensed matter. Several quantum computing algorithms that address these problems…

Quantum Physics · Physics 2023-01-12 Karen J. Morenz Korol , Kenny Choo , Antonio Mezzacapo

Many applications of practical interest rely on time evolution of Hamiltonians that are given by a sum of Pauli operators. Quantum circuits for exact time evolution of single Pauli operators are well known, and can be extended trivially to…

Quantum Physics · Physics 2020-09-16 Ewout van den Berg , Kristan Temme

We present a straightforward method for obtaining exact classical and quantum molecular Hamiltonians in terms of arbitrary coordinates. As compared to other approaches the resulting expression are rather compact, the physical meaning of…

Chemical Physics · Physics 2009-11-13 Yonggang Yang , Oliver Kühn

Hamiltonian simulation is a promising application for quantum computers to achieve a quantum advantage. We present classical algorithms based on tensor network methods to optimize quantum circuits for this task. We show that, compared to…

Quantum Physics · Physics 2023-06-05 Conor Mc Keever , Michael Lubasch

Estimating the expectation value of an operator corresponding to an observable is a fundamental task in quantum computation. It is often impossible to obtain such estimates directly, as the computer is restricted to measuring in a fixed…

The diagonalization of the metrical and canonical Hamilton operators of a scalar field with an arbitrary coupling, with a curvature in N-dimensional homogeneous isotropic space is considered in this paper. The energy spectrum of the…

General Relativity and Quantum Cosmology · Physics 2011-04-20 Yu. V. Pavlov

Simulating real-time dynamics under a Hamiltonian is a central goal of quantum information science. While numerous Hamiltonian-simulation quantum algorithms have been proposed, the effects of physical noise have rarely been incorporated…

Quantum Physics · Physics 2026-03-13 Keisuke Murota , Synge Todo , Suguru Endo

Achieving noise resilience is an outstanding challenge in Hamiltonian-based quantum computation. To this end, energy-gap protection provides a promising approach, where the desired quantum dynamics are encoded into the ground space of a…

Quantum Physics · Physics 2024-12-11 Yingkang Cao , Suying Liu , Haowei Deng , Zihan Xia , Xiaodi Wu , Yu-Xin Wang

Quantum process characterization is a fundamental task in quantum information processing, yet conventional methods, such as quantum process tomography, require prohibitive resources and lack scalability. Here, we introduce an efficient…

Quantum Physics · Physics 2025-04-11 Yusen Wu , Yukun Zhang , Chuan Wang , Xiao Yuan

Quantum dynamics simulations of reactive molecular processes are commonly performed in a low-dimensional space spanned by highly optimized reactive coordinates. Usually, these sets of reactive coordinates consist of non-linear coordinates.…

Chemical Physics · Physics 2018-01-01 Julius P. P. Zauleck , Sebastian Thallmair , Regina de Vivie-Riedle