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Using first-principles calculations, we predict that tunable ferroelectricity can be realized in oxide perovskites with the Grenier structure and ordered oxygen vacancies. Specifically, we show that $R_{1/3}A_{2/3}\mathrm{FeO}_{2.67}$…

Materials Science · Physics 2023-07-12 Yongjin Shin , Giulia Galli

Structural, magnetic and dielectric properties have been studied for Yb$_2$CoMnO$_6$. Nano-crystalline sample of Yb$_2$CoMnO$_6$ synthesized by sol-gel method and structural analysis shows that the sample crystallizes in monoclinic crystal…

Strongly Correlated Electrons · Physics 2020-10-28 Ilyas Noor Bhatti , Imtiaz Noor Bhatti , Rabindra Nath Mahato , M. A. H. Ahsan

Using a broad band dielectric spectroscopy approach (1 to 10^14 Hz) we prove that the tungsten bronze Ca0.3Ba0.7Nb2O6 (CBN-30) displays a ferroelectric phase transition of mixed displacive and order-disorder character, and its paraelectric…

The nematic-nematic transitions in a nematic compound DIO are studied in homogeneously planar and homeotropic aligned cells using dielectric spectroscopy in the frequency range 0.1 Hz to 10 MHz over a wide range of temperatures. Three…

Soft Condensed Matter · Physics 2022-03-10 Neelam Yadav , Yuri P. Panarin , Jagdish K. Vij , Wanhe Jiang , Georg H. Mehl

We present general guidelines for finding solid-state systems that could serve as coherent electron spin-photon interfaces even at relatively high temperatures, where phonons are abundant but cooling is easier, and show that transition…

Quantum Physics · Physics 2023-09-04 E. Poem , S. Gupta , I. Morris , K. Klink , L. Singh , T. Zhong , J. N. Becker , O. Firstenberg

The crystal structure of the PbMg$_{1/3}$Ta$_{2/3}$O$_3$ (PMT) relaxor ferroelectric was studied under hydrostatic pressure up to $\sim 7$ GPa by means of powder neutron diffraction. We find a drastic pressure-induced decrease of the lead…

Materials Science · Physics 2007-05-23 S. N. Gvasaliya , V. Pomjakushin , B. Roessli , Th. Straessle , S. Klotz , S. G. Lushnikov

Dielectric measurements on 0.65[Pb(Ni_1/3Nb_2/3)O_3]-0.35PbTiO_3 ceramic in the temperature range 90K to 470K shows a relaxor ferroelectric transition around 350K with a Vogel-Fulcher freezing temperature of 338K and appearance of a…

Materials Science · Physics 2007-06-08 Satendra Pal Singh , Akhilesh Kumar Singh , Dhananjai Pandey , S. M. Yusuf

The transient negative capacitance (NC) of solid ferroelectric materials used in field effect transistors can reduce the power dissipation of electronics. Here we show that similar negative capacitance appears in the recently discovered…

Soft Condensed Matter · Physics 2024-12-30 Netra Prasad Dhakal , Alex Adaka , Robert J. Twieg , Antal Jákli

We suggest a random field based model for calculation of physical properties of mixed ferroelectric relaxors. Our model naturally incorporates the different orientations of electric dipoles (related to different solid solution components)…

Materials Science · Physics 2007-05-23 M. D. Glinchuk , E. A. Eliseev , V. A. Stephanovich , B. Hilczer

For Sn$_2$P$_2$S$_6$ ferroelectrics the second order phase transitions line is observed until reaching the tricritical point at transition temperature lowering to 250 K by compression. Observed temperature-pressure phase diagram agrees with…

Ferroelectric nematic liquid crystals represent not only interesting fundamental science, but they also hold promise for storage capacitors with high power density or new information display technology having sub-millisecond switching. In…

We report a neutron diffraction study of the multiferroic mechanism in (ND4)2FeCl5D2O, a molecular compound that exhibits magnetically induced ferroelectricity. This material exhibits two successive magnetic transitions on cooling: a…

Twisted heterostructures of two-dimensional crystals offer almost unlimited scope for the design of novel metamaterials. Here we demonstrate a room-temperature ferroelectric semiconductor that is assembled using mono- or few- layer MoS2.…

Recent results have demonstrated an exceptionally high dielectric constant in the range 200 K-330 K in a crystalline tianium oxide : Rb2Ti2O5. In this article, the possibility of a structural transition giving rise to ferroelectricity is…

Magnetization curves of two rectangular metal-organic coordination networks formed by the organic ligand TCNQ (7,7,8,8-tetracyanoquinodimethane) and two different (Mn and Ni) 3d transition metal atoms [M(3d)] show marked differences that…

Using molecular dynamics simulation, we study dipolar glass in crystals composed of slightly spheroidal, polar particles and spherical, apolar impurities between metal walls. We present physical pictures of ferroelectric glass, which have…

Soft Condensed Matter · Physics 2017-03-27 Kyohei Takae , Akira Onuki

Relaxor ferroelectric PbMg_1/3Ta_2/3O_3 ceramics and thin films were investigated by means of broad-band dielectric, time-domain terahertz (THz) and Fourier-transform infrared (IR) spectroscopy in the frequency range 100 Hz - 90 THz at…

Materials Science · Physics 2009-11-13 S. Kamba , D. Nuzhnyy , S. Veljko , V. Bovtun , J. Petzelt , Y. L. Wang , J. Levoska , M. Tyunina , J. Macutkevic , N. Setter , J. Banys

Relaxor behavior and lattice dynamics have been studied for a single crystal of K$_{1-x}$Li$_x$TaO$_3$ $(x=0.05)$, where a small amount of a Ca impurity ($\sim 15$~ppm) was incorporated. The dielectric measurements revealed Debye-like…

Materials Science · Physics 2009-11-11 S. Wakimoto , G. A. Samara , R. K. Grubbs , E. L. Venturini , L. A. Boatner , G. Xu , G. Shirane , S. -H. Lee

We report here a comprehensive study on structural, magnetic, caloric and electronic properties of the monoclinic phase of double perovskite compound Tm2CoMnO6 (TCMO) in its polycrysttaline format. Magnetic measurements confirm the presence…

Materials Science · Physics 2023-07-13 A. Banerjee , Gangadhar Das , V. Rajaji , S. Majumdar , P. K. Chakrabarti

A Landau-type phenomenological cluster theory was presented to model the freezing process of local polarization in relaxors. Based on the theory, the proportion of frozen polarization in Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_3$-PbTiO$_3$ (PMNT) was…

Materials Science · Physics 2009-11-07 Zhi-Rong Liu , Yong Zhang , Bing-Lin Gu , Xiao-Wen Zhang
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