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Interatomic Coulombic decay (ICD) plays a crucial role in weakly bound complexes exposed to intense or high-energy radiation. So far, neutral or ionic atoms or molecules have been prepared in singly excited electron or hole states which can…

Interatomic Coulombic decay (ICD) processes play a crucial role in weakly bound complexes exposed to intense or high-energy radiation. Using large helium nanodroplets, we demonstrate that ICD is efficient even when the droplets are…

Interatomic Coulombic decay (ICD) is induced in helium (He) nanodroplets by photoexciting the n=2 excited state of He^+ using XUV synchrotron radiation. By recording multiple coincidence electron and ion images we find that ICD occurs in…

Atomic and Molecular Clusters · Physics 2017-07-24 M. Shcherbinin , A. C. LaForge , V. Sharma , M. Devetta , R. Richter , R. Moshammer , T. Pfeifer , M. Mudrich

The autoionization dynamics of superexcited superfluid He nanodroplets doped with Na atoms is studied by extreme-ultraviolet (XUV) time-resolved electron spectroscopy. Following excitation into the higher-lying droplet absorption band, the…

We report on the experimental observation of interatomic Coulombic decay (ICD) in pure $^4$He nanoclusters of mean sizes between $N \approx$ 5000 and 30000 and the subsequent scattering of energetic He$^+$ fragments inside the neutral…

During the last 15 years a novel decay mechanism of excited atoms has been discovered and investigated. This so called ''Interatomic Coulombic Decay'' (ICD) involves the chemical environment of the electronically excited atom: the…

Irradiation of condensed matter with ionizing radiation generally causes direct photoionization as well as secondary processes that often dominate the ionization dynamics. Here, large helium (He) nanodroplets with radius >40 nm doped with…

Atomic and Molecular Clusters · Physics 2024-12-06 L. Ben Ltaief , K. Sishodia , J. D. Asmussen , A. R. Abid , S. R. Krishnan , H. B. Pedersen , N. Sisourat , M. Mudrich

An ultrafast mechanism belonging to the family of interatomic Coulombic decay (ICD) phenomena is proposed. When two excited species are present, an ultrafast energy transfer can take place bringing one of them to its ground state and…

Ionization of matter by energetic radiation generally causes complex secondary reactions which are hard to decipher. Using large helium nanodroplets irradiated by XUV photons, we show that the full chain of processes ensuing primary…

Atomic and Molecular Clusters · Physics 2023-07-26 L. Ben Ltaief , K. Sishodia , S. Mandal , S. De , S. R. Krishnan , C. Medina , N. Pal , R. Richter , T. Fennel , M. Mudrich

Atoms and molecules attached to rare gas clusters are ionized by an interatomic autoionization process traditionally termed 'Penning ionization' when the host cluster is resonantly excited. Here we analyze this process in the light of the…

To exploit the high intensity of laser radiation, we propose to select frequencies at which single-photon absorption is of too low energy and two or more photons are needed to produce states of an atom that can undergo interatomic Coulombic…

Atomic and Molecular Clusters · Physics 2012-01-04 Philipp V. Demekhin , Spas D. Stoychev , Alexander I. Kuleff , Lorenz S. Cederbaum

Interatomic coulombic decay (ICD) is a relaxation process induced by electronic correlation. In this work we study the ICD process in a two coupled Quantum wells (QWs) nano-structure. We study a simple one-dimensional effective potential…

Mesoscale and Nanoscale Physics · Physics 2015-06-11 Tamar Goldzak , Liron Gantz , Ido Gilary , Gad Bahir , Nimrod Moiseyev

We report theory for time-resolved spectator resonant Interparticle Coulombic Decay (ICD) processes. Following excitation by a short extreme ultraviolet pulse, the spectrum of the resonant ICD electron develops. Strong-field ionization is…

Quantum Physics · Physics 2020-04-29 Elke Fasshauer , Lars Bojer Madsen

Excited atoms and molecules can utilize their excess energy to ionize a neighboring system by a process named interatomic and intermolecular Coulombic decay (ICD). ICD is ultrafast, in the femtosecond regime, and has many modes of…

Chemical Physics · Physics 2026-03-10 Alan G. Falkowski , Alexander I. Kuleff , Lorenz S. Cederbaum

When a vacancy is created in an inner-valence orbital of a dimer of atoms or molecules, the resulting species can undergo interatomic/intermolecular Coulombic decay (ICD): the hole is filled through a relaxation process that leads to a…

Chemical Physics · Physics 2023-05-18 Valentina Parravicini , Thomas-C. Jagau

The electron removal and excitation channels in argon dimer target and helium ion projectile collision systems that facilitate interatomic Coulombic decay (ICD) are investigated. We implement an independent-atom and independent-electron…

Atomic and Molecular Clusters · Physics 2026-03-25 Darij Starko , Tom Kirchner

Superfluid He nanodroplets resonantly excited by extreme ultraviolet (XUV) pulses exhibit complex relaxation dynamics, including the formation of metastable excited He$^*$ atoms trapped in bubbles, the desorption of excited atoms from the…

Light-induced energy confinement in nanoclusters via plasmon excitations influences applications in nanophotonics, photocatalysis, and the design of controlled slow electron sources. The resonant decay of these excitations through the…

Atomic and Molecular Clusters · Physics 2023-06-21 Rasheed Shaik , Hari R. Varma , Mohamed El-Amine Madjet , Fulu Zheng , Thomas Frauenheim , Himadri S. Chakraborty

Tremendous advances in laser pump-probe techniques open the door for the observation in real time of ultrafast \textit{electronic} processes. Particularly attractive is the visualization of interatomic processes where one can follow the…

Atomic and Molecular Clusters · Physics 2007-05-23 Alexander I. Kuleff , Lorenz S. Cederbaum

We report the first observation of intermolecular Coulombic decay (ICD) in liquid water following inner-valence ionization. By combining a monochromatized table-top high-harmonic source with a liquid micro-jet, we recorded electron-electron…

Atomic and Molecular Clusters · Physics 2022-04-05 Pengju Zhang , Conaill Perry , Tran Trung Luu , Danylo Matselyukh , Hans Jakob Wörner
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