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We propose a preconditioner that can accelerate the rate of convergence of the Multiple Shooting Shadowing (MSS) method. This recently proposed method can be used to compute derivatives of time-averaged objectives (also known as…

Numerical Analysis · Mathematics 2019-10-02 Karim Shawki , George Papadakis

A density functional theory for a macroion suspension is examined, where the excess free energy corresponds to the macroion self energy arising from the polarisation of the supporting electrolyte solution. This is treated within a…

Soft Condensed Matter · Physics 2007-05-23 Patrick B. Warren

A consistent device model to describe current-voltage characteristics of metal/insulator/metal systems is developed. In this model the insulator and the metal electrodes are described within the same theoretical framework by using density…

Materials Science · Physics 2015-05-13 F. Neumann , Y. A. Genenko , C. Melzer , H. von Seggern

In this article we present a new multigrid preconditioner for the linear systems arising in the semismooth Newton method solution of certain control-constrained, quadratic distributed optimal control problems. Using a piecewise constant…

Numerical Analysis · Mathematics 2016-02-16 Andrei Draganescu , Jyoti Saraswat

A long-standing puzzle in density-functional theory is the issue of the long-range behavior of the Kohn-Sham exchange-correlation potential at metal surfaces. As an important step towards its solution, it is proved here, through a rigurouos…

Materials Science · Physics 2015-05-18 C. M. Horowitz , C. R. Proetto , J. M. Pitarke

This work aims to accelerate the convergence of proximal gradient methods used to solve regularized linear inverse problems. This is achieved by designing a polynomial-based preconditioner that targets the eigenvalue spectrum of the normal…

In this work we present a space-time least squares isogeometric discretization of the Schr\"odinger equation and propose a preconditioner for the arising linear system in the parametric domain. Exploiting the tensor product structure of the…

Numerical Analysis · Mathematics 2023-12-01 Andrea Bressan , Alen Kushova , Giancarlo Sangalli , Mattia Tani

We present a first-principles approach to describe magnetic and superconducting systems and the phenomena of competition between these electronic effects. We develop a density functional theory: SpinSCDFT, by extending the Hohenberg-Kohn…

Superconductivity · Physics 2016-05-10 A. Linscheid , A. Sanna , F. Essenberger , E. K. U. Gross

This paper introduces inexact versions of several block-splitting preconditioners for solving the three-by-three block linear systems arising from a special class of indefinite least squares problems. We first establish the convergence…

Numerical Analysis · Mathematics 2026-05-26 Mohaddese Kaveh Shaldehi , Davod Khojasteh Salkuyeh

Kohn-Sham density functional theory (KS-DFT) has found widespread application in accurate electronic structure calculations. However, it can be computationally demanding especially for large-scale simulations, motivating recent efforts…

Computational Physics · Physics 2024-06-25 Feitong Song , Ji Feng

We present a new charge self-consistent scheme combining Density Functional and Dynamical Mean Field Theory, which uses Green's function of multiple scattering-type. In this implementation the many-body effects are incorporated into the…

Strongly Correlated Electrons · Physics 2017-10-11 A. Östlin , L. Vitos , L. Chioncel

The possibility of an inhomogeneous charge density wave phase is investigated in a system of two coupled electron and hole monolayers separated by a hexagonal boron nitride insulating layer. The charge density wave state is induced through…

Mesoscale and Nanoscale Physics · Physics 2018-12-26 S. Saberi-Pouya , M. Zarenia , T. Vazifehshenas , F. M. Peeters

We demonstrate how the separation of the total energy of a self-bound system into a functional of the internal one-body Fermionic density and a function of an arbitrary wave vector describing the center-of-mass kinetic energy can be used to…

Nuclear Theory · Physics 2009-12-14 J. Messud , M. Bender , E. Suraud

We review the role of self-consistency in density functional theory. We apply a recent analysis to both Kohn-Sham and orbital-free DFT, as well as to Partition-DFT, which generalizes all aspects of standard DFT. In each case, the analysis…

Chemical Physics · Physics 2016-11-22 Adam Wasserman , Jonathan Nafziger , Kaili Jiang , Min-Cheol Kim , Eunji Sim , Kieron Burke

We present a closed description of the charge carrier injection process from a conductor into an insulator. Common injection models are based on single electron descriptions, being problematic especially once the amount of charge-carriers…

Materials Science · Physics 2007-05-23 F. Neumann , Y. A. Genenko , C. Melzer , S. V. Yampolskii , H. von Seggern

We present parameter-robust preconditioners for linear systems that arise after applying static condensation to a hybridizable discontinuous Galerkin (HDG) discretization of the time-dependent Stokes problem. Building upon the theoretical…

Numerical Analysis · Mathematics 2026-04-09 Esteban Henríquez , Jeonghun J. Lee , Sander Rhebergen

The charge delocalization error, besides nondynamic correlation, has been a major challenge to density functional theory. Contemporary functionals undershoot the dissociation of symmetric charged dimers A2+, a simple but stringent test,…

Chemical Physics · Physics 2021-07-26 Emil Proynov , Jing Kong

The Interior-Point Methods are a class for solving linear programming problems that rely upon the solution of linear systems. At each iteration, it becomes important to determine how to solve these linear systems when the constraint matrix…

Optimization and Control · Mathematics 2024-04-18 Catalina J. Villalba , Aurelio R. L. Oliveira

We consider the extension of the standard single-determinant Kohn-Sham method to the case of a multiconfiguration trial wavefunction. By applying the rigorous Kohn-Sham method to this case, we construct the proper interacting and…

Strongly Correlated Electrons · Physics 2008-12-08 Yair Kurzweil , M. Head-Gordon

Numerical simulation of fracture contact poromechanics is essential for various applications, including CO2 sequestration, geothermal energy production and underground gas storage. Modeling this problem accurately presents significant…

Numerical Analysis · Mathematics 2025-01-14 Yury Zabegaev , Inga Berre , Eirik Keilegavlen , Kundan Kumar