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Recently, Garcke et al.[Garcke, Hinze, Kahle, A stable and linear time discretization for a thermodynamically consistent model for two-phase incompressible flow, Applied Numerical Mathematics 99, pp. 151-171, 2016] developed a consistent…

Numerical Analysis · Mathematics 2017-02-16 Jessica Bosch , Christian Kahle , Martin Stoll

Kohn-Sham density functional theory is one of the most widely used electronic structure theories. In the pseudopotential framework, uniform discretization of the Kohn-Sham Hamiltonian generally results in a large number of basis functions…

Numerical Analysis · Mathematics 2015-05-27 Lin Lin , Jianfeng Lu , Lexing Ying , E. Weinan

Density functional theory (DFT) provides convenient electronic structure methods for the study of molecular systems and materials. Regular Kohn-Sham DFT calculations rely on unitary transformations to determine the ground-state electronic…

Chemical Physics · Physics 2022-10-10 Greta Jacobson , Juan M. Marmolejo-Tejada , Martín A. Mosquera

The Helmholtz equation poses significant computational challenges due to its oscillatory solutions, particularly for large wavenumbers. Inspired by the Schur complement system for elliptic problems, this paper presents a novel…

Numerical Analysis · Mathematics 2025-05-02 Yi Yu , Marcus Sarkis , Guanglian Li , Zhiwen Zhang

We examine the density-functional theory of macroscopic insulators, obtained in the large-cluster limit or under periodic boundary conditions. For polar crystals, we find that the two procedures are not equivalent. In a large-cluster case,…

Materials Science · Physics 2009-10-28 X. Gonze , Ph. Ghosez , R. W. Godby

In this work we have applied the recently formulated self-compressed inhomogeneous stabilized jellium model [M. Payami and T. Mahmoodi, Can. J. Phys. {\bf 89}, 967 (2011)] to describe the equilibrium electronic and geometric properties of…

Materials Science · Physics 2017-09-22 M. Payami , T. Mahmoodi

We introduce a new implementation of time-dependent density-functional theory which allows the \emph{entire} spectrum of a molecule or extended system to be computed with a numerical effort comparable to that of a \emph{single} standard…

Materials Science · Physics 2009-11-13 Dario Rocca , Ralph Gebauer , Yousef Saad , Stefano Baroni

The numerical modeling of fracture contact thermo-poromechanics is crucial for advancing subsurface engineering applications, including CO2 sequestration, production of geo-energy resources, energy storage and wastewater disposal…

Numerical Analysis · Mathematics 2025-10-14 Yury Zabegaev , Inga Berre , Eirik Keilegavlen

By introducing the self-energy density functionals for the dissipative interactions between the reduced system and its environment, we develop a time-dependent density-functional theory formalism based on an equation of motion for the…

Quantum Physics · Physics 2009-11-13 Xiao Zheng , Fan Wang , Chi Yung Yam , Yan Mo , GuanHua Chen

We modify the well-known interior penalty finite element discretization method so that it allows for element-by-element assembly. This is possible due to the introduction of additional unknowns associated with the interfaces between…

Numerical Analysis · Mathematics 2020-06-15 Delyan Z. Kalchev , Panayot S. Vassilevski

We present a subspace projection technique to conduct large-scale Kohn-Sham density functional theory calculations using spectral finite-element discretization. The proposed method treats both metallic and insulating materials in a single…

Computational Physics · Physics 2015-10-26 Phani Motamarri , Vikram Gavini

For a class of ergodic parabolic semilinear stochastic partial differential equations (SPDEs) with gradient structure, we introduce a preconditioning technique and design high-order integrators for the approximation of the invariant…

Numerical Analysis · Mathematics 2025-12-22 Charles-Edouard Bréhier , Adrien Busnot Laurent , Arnaud Debussche , Gilles Vilmart

This paper studies and analyzes a preconditioned Krylov solver for Helmholtz problems that are formulated with absorbing boundary layers based on complex coordinate stretching. The preconditioner problem is a Helmholtz problem where not…

Numerical Analysis · Computer Science 2010-08-19 Bram Reps , Wim Vanroose , Hisham bin Zubair

A new polynomial preconditioner for symmetric complex linear systems based on Hermitian and skew-Hermitian splitting (HSS) for complex symmetric linear systems is herein presented. It applies to Conjugate Orthogonal Conjugate Gradient…

Numerical Analysis · Mathematics 2016-04-18 Enrico Bertolazzi , Marco Frego

A novel low complexity method to perform self-consistent electronic-structure calculations using the Kohn-Sham formalism of density functional theory is presented. Localization constraints are neither imposed nor required thereby allowing…

Computational Physics · Physics 2007-05-23 M. J. Rayson

The Lippmann-Schwinger equation is an integral equation formulation for acoustic and electromagnetic scattering from an inhomogeneous media and quantum scattering from a localized potential. We present the sparsifying preconditioner for…

Numerical Analysis · Mathematics 2014-09-17 Lexing Ying

This work presents a fully theoretical and self consistent framework for calculating the third-order nonlinear susceptibility of CdSe/ZnS--MOF composite quantum dots. The approach unifies finite-potential quantum confinement,the Liouville…

Mesoscale and Nanoscale Physics · Physics 2025-11-06 Jingxu Wu , Yifan Yang , Jie Shi , Yuwei Yin , Yifan He , Chenjia Li

Typical density functional theory (DFT) and approximations thereto solve the many-electron ground state problem by working from a numerically efficient non-interacting Kohn-Sham reference system; and benefit from useful minimization…

Chemical Physics · Physics 2025-04-02 Tim Gould

In this paper, we construct and analyze preconditioners for the interior penalty discontinuous Galerkin discretization posed in the space $H(\mathrm{div})$. These discretizations are used as one component in exactly divergence-free…

Numerical Analysis · Mathematics 2024-11-25 Will Pazner

This chapter presents controlled approximations of Kohn-Sham density functional theory (DFT) that enable very large scale simulations. The work is motivated by the study of defects in crystalline solids, though the ideas can be used in…

Materials Science · Physics 2021-12-14 Kaushik Bhattacharya , Vikram Gavini , Michael Ortiz , Mauricio Ponga , Phanish Suryanarayana