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The Jarzynski equality (JE) provides a nonequilibrium method to measure and calculate the free energy difference (FED). Note that if two systems share the same Hamiltonian at two equilibrium states, respectively, they share the same FED…

Statistical Mechanics · Physics 2020-07-16 Liyun Zhu , Jiao Wang

The theory of phenomenological Non-equilibrium Thermodynamics is extended by includimg stochastic processes in order to account for recently derived thermodynamical relations such as the Jarzynski equality. Four phenomenological axioms are…

Chaotic Dynamics · Physics 2016-07-20 Wolfgang Muschik

In this review paper, we discuss the statistical description in non-equilibrium regimes of energy fluctuations originated by the interaction between a quantum system and a measurement apparatus applying a sequence of repeated quantum…

Bridging equilibrium and nonequilibrium statistical physics attracts sustained interest. Hallmarks of nonequilibrium systems include a breakdown of detailed balance, and an absence of a priori potential function corresponding to the…

Statistical Mechanics · Physics 2015-04-24 Ying Tang , Ruoshi Yuan , Jianhong Chen , Ping Ao

The work fluctuations of an oscillator in contact with a heat reservoir and driven out of equilibrium by an external force are studied experimentally. The oscillator dynamics is modeled by a Langevin equation. We find both experimentally…

Statistical Mechanics · Physics 2009-11-11 Frederic Douarche , Sergio Ciliberto , Artem Petrosyan

Jarzynski Equality (JE) and the thermodynamic integration method are conventional methods to calculate free energy difference (FED) between two equilibrium states with constant temperature of a system. However, a number of ensemble samples…

Statistical Mechanics · Physics 2020-09-01 Weitao Chen

The characteristic function for the joint measurement of the changes of two commuting observables upon an external forcing of a quantum system is derived. In particular, the statistics of the internal energy, the exchanged heat and the work…

Statistical Mechanics · Physics 2009-02-18 Peter Talkner , Michele Campisi , Peter Hänggi

The Jarzynski equality is one of the most influential results in the field of non equilibrium statistical mechanics. This celebrated equality allows to calculate equilibrium free energy differences from work distributions of nonequilibrium…

Statistical Mechanics · Physics 2017-09-13 Shahaf Asban , Saar Rahav

The Fluctuation Theorem and the Jarzynski equality are examined in the light of recent experimental tests. For a particle dragged through a solvent, it is shown that $Q,$ the heat exchanged with the reservoir, obeys the asymptotic…

Statistical Mechanics · Physics 2009-11-10 Onuttom Narayan , Abhishek Dhar

We investigate the connection between recent results in quantum thermodynamics and fluctuation relations by adopting a fully quantum mechanical description of thermodynamics. By including a work system whose energy is allowed to fluctuate,…

Quantum Physics · Physics 2017-03-27 Álvaro M. Alhambra , Lluis Masanes , Jonathan Oppenheim , Christopher Perry

In conventional thermodynamics, it is widely acknowledged that the realization of an isothermal process for a system requires a quasi-static controlling protocol. Here we propose and design a strategy to realize a finite-rate isothermal…

Statistical Mechanics · Physics 2017-07-25 Geng Li , H. T. Quan , Z. C. Tu

The Jarzynski equality (JE) is known as an exact identity for nonequillibrium systems. The JE was originally formulated for isolated and isothermal systems, while Adib reported an JE extended to an isoenergetic process. In this paper, we…

Statistical Mechanics · Physics 2015-05-27 Hitoshi Katsuda , Masayuki Ohzeki

Recent progress on micro- and nanometer scale manipulation has opened the possibility to probe systems small enough that thermal fluctuations of energy and coordinate variables can be significant compared with their mean behavior. We…

Mesoscale and Nanoscale Physics · Physics 2012-11-02 O. -P. Saira , Y. Yoon , T. Tanttu , M. Möttönen , D. V. Averin , J. P. Pekola

We experimentally verify the Jarzynski and W\"ojcik quantum heat exchange fluctuation relation by implementing the interferometric technique in liquid-state Nuclear Magnetic Resonance setup and study the exchange heat statistics between two…

Statistical Mechanics · Physics 2019-10-30 Soham Pal , T S Mahesh , Bijay Kumar Agarwalla

A main goal of single-molecule experiments is to evaluate equilibrium free energy differences by applying fluctuation relations to repeated work measurements along irreversible processes. We quantify the error that is made in a free energy…

Statistical Mechanics · Physics 2009-06-22 Alessandro Mossa , Sara de Lorenzo , Josep Maria Huguet , Felix Ritort

Five previously unknown inequalities relating equilibrium free energy differences and non-equilibrium work fluctuations are derived, and lucid path to derivation of many similar inequalities is presented. These results are based upon…

Statistical Mechanics · Physics 2011-05-24 Alexander Davydov

Nonequilibrium processes of small systems such as molecular machines are ubiquitous in biology, chemistry and physics, but are often challenging to comprehend. In the past two decades, several exact thermodynamic relations of nonequilibrium…

Statistical Mechanics · Physics 2018-02-26 Thai M. Hoang , Rui Pan , Jonghoon Ahn , Jaehoon Bang , H. T. Quan , Tongcang Li

We present some aspects of the fidelity approach to phase transitions based on lower and upper bounds on the fidelity susceptibility that are expressed in terms of thermodynamic quantities. Both commutative and non commutative cases are…

Statistical Mechanics · Physics 2012-10-02 N. S. Tonchev , J. G. Brankov

The quantum Jarzynski equality and the Crooks relation are fundamental laws connecting equilibrium processes with nonequilibrium fluctuations. They are promising tools to benchmark quantum devices and measure free energy differences. While…

Statistical Mechanics · Physics 2023-11-07 Dominik Hahn , Maxime Dupont , Markus Schmitt , David J. Luitz , Marin Bukov

The connection between work and changes in the Hamiltonian for a system with a time-dependent Hamiltonian has recently been called into question, casting doubt on the usefulness of the Jarzynski equality for calculating free energy changes.…

Statistical Mechanics · Physics 2015-05-13 Eric N. Zimanyi , Robert J. Silbey