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We introduce a novel many body method which combines two powerful many body techniques, viz., quantum Monte Carlo and coupled cluster theory. Coupled cluster wave functions are introduced as importance functions in a Monte Carlo method…

Nuclear Theory · Physics 2013-12-04 Alessandro Roggero , Abhishek Mukherjee , Francesco Pederiva

Geometric configuration and energy of a hydrogen molecule centered between two point-shaped tips of equal charge are calculated with the variational quantum Monte-Carlo (QMC) method without the restriction of the Born-Oppenheimer (BO)…

Mesoscale and Nanoscale Physics · Physics 2020-05-29 W. Schattke , T. Frederiksen , M. A. Van Hove , R. Díez Muiño

We perform a variational quantum Monte Carlo simulation of an interacting Fermi gas confined in a three dimensional harmonic potential. This gas is considered as the precursor system from which a molecular bosonic gas is formed. Based on…

Other Condensed Matter · Physics 2009-11-11 R. Jauregui , R. Paredes , G. Toledo Sanchez

In this article, we report a fully ab initio variational Monte Carlo study of the linear, and periodic chain of Hydrogen atoms, a prototype system providing the simplest example of strong electronic correlation in low dimensions. In…

Strongly Correlated Electrons · Physics 2015-05-30 Lorenzo Stella , Claudio Attaccalite , Sandro Sorella , Angel Rubio

The Diffusion Monte Carlo method with constant number of walkers, also called Stochastic Reconfiguration as well as Sequential Monte Carlo, is a widely used Monte Carlo methodology for computing the ground-state energy and wave function of…

Statistics Theory · Mathematics 2024-12-09 Michel Caffarel , Pierre del Moral , Luc de Montella

Using the finite simulation-cell homogeneous electron gas (HEG) as a model, we investigate the convergence of the correlation energy to the complete basis set (CBS) limit in methods utilising plane-wave wavefunction expansions. Simple…

Computational Physics · Physics 2012-09-11 James J. Shepherd , Andreas Grüneis , George H. Booth , Georg Kresse , Ali Alavi

The equation of state of liquid metallic hydrogen is solved numerically. Investigations are carried out at temperatures, which correspond both to the experimental conditions under which metallic hydrogen is produced on earth and the…

Chemical Physics · Physics 2016-02-25 V. T. Shvets

The ground state of the two-dimensional three-band Hubbard model in oxide superconductors is investigated by using the variational Monte Carlo method. The Gutzwiller-projected BCS and spin- density wave (SDW) functions are employed in the…

Strongly Correlated Electrons · Physics 2009-11-07 Takashi Yanagisawa , Soh Koike , Kunihiko Yamaji

Highly accurate results for the homogeneous electron gas (HEG) have only been achieved to date within a diffusion Monte Carlo (DMC) framework. Here, we introduce a newly developed stochastic technique, Full Configuration Interaction Quantum…

Quantum Gases · Physics 2012-02-22 James J. Shepherd , George Booth , Andreas Grüneis , Ali Alavi

We propose a new ansatz for the ground-state wave function of quantum many-body systems on a lattice. The key idea is to cover the lattice with plaquettes and obtain a state whose configurational weights can be optimized by means of a…

Strongly Correlated Electrons · Physics 2015-05-13 Fabio Mezzacapo , Norbert Schuch , Massimo Boninsegni , J. Ignacio Cirac

We present a simple, robust and highly efficient method for optimizing all parameters of many-body wave functions in quantum Monte Carlo calculations, applicable to continuum systems and lattice models. Based on a strong zero-variance…

Other Condensed Matter · Physics 2009-11-11 C. J. Umrigar , Julien Toulouse , Claudia Filippi , S. Sorella , R. G. Hennig

We use a diffusion Monte Carlo method to calculate the lowest energy state of a uniform gas of bosons interacting through different model potentials, both strictly repulsive and with an attractive well. We explicitly verify that at low…

Condensed Matter · Physics 2009-10-31 S. Giorgini , J. Boronat , J. Casulleras

Ultracold atoms in optical lattices are versatile testbeds to study and manipulate equilibrium and out-of-equilibrium aspects of quantum many-body systems whose behavior can be described by Hubbard-type Hamiltonians. In this paper, we…

Quantum Gases · Physics 2025-08-05 Tista Banerjee

Establishing the phase diagram of hydrogen is a major challenge for experimental and theoretical physics. Experiment alone cannot establish the atomic structure of solid hydrogen at high pressure, because hydrogen scatters X-rays only…

The ground state of solid $^4$He is studied using the diffusion Monte Carlo method and a new trial wave function able to describe the supersolid. The new wave function is symmetric under the exchange of particles and reproduces the…

Other Condensed Matter · Physics 2009-11-13 C. Cazorla , G. E. Astrakharchik , J. Casulleras , J. Boronat

In this paper, we present a systematic stability analysis of the quadrature-based moment method (QBMM) for the one-dimensional Boltzmann equation with BGK or Shakhov models. As reported in recent literature, the method has revealed its…

Numerical Analysis · Mathematics 2018-12-21 Qian Huang , Shuiqing Li , Wen-An Yong

High-order perturbative $\textit{ab initio}$ calculations are challenging due to the rapidly growing configuration space and the difficulty of assessing convergence. In this letter, we introduce perturbation theory quantum Monte Carlo…

Nuclear Theory · Physics 2026-05-06 Xin Zhen , Rongzhe Hu , Junchen Pei , Furong Xu

We present phaseless auxiliary-field (AF) quantum Monte Carlo (QMC) calculations of the ground states of some hydrogen-bonded systems. These systems were selected to test and benchmark different aspects of the new phaseless AF QMC method.…

Computational Physics · Physics 2007-05-23 W. A. Al-Saidi , Henry Krakauer , Shiwei Zhang

We investigate the accuracy of a number of wavefunction based methods at the heart of quantum chemistry for metallic systems. Using Hartree-Fock as a reference, perturbative (M{\o}ller-Plesset, MP) and coupled cluster (CC) theories are used…

Chemical Physics · Physics 2013-10-24 James J. Shepherd , Andreas Grüneis

The quantum Monte Carlo algorithm is arguably one of the most powerful computational many-body methods, enabling accurate calculation of many properties in interacting quantum systems. In the presence of the so-called sign problem, the…

Strongly Correlated Electrons · Physics 2018-02-23 Chia-Chen Chang , Miguel A. Morales
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