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In first-principles calculations, hybrid functional is often used to improve accuracy from local exchange correlation functionals. A drawback is that evaluating the hybrid functional needs significantly more computing effort. When…

Materials Science · Physics 2018-02-05 Maoyuan Wang , Gui-Bin Liu , Hong Guo , Yugui Yao

The Jacob's ladder of density functional theory (DFT) proposes the compelling view that by extending the form of successful approximations -- being guided by exact conditions and selected (least empirical) norms -- upper rungs will do…

Materials Science · Physics 2025-02-25 Jacques K. Desmarais , Alessandro Erba , Giovanni Vignale , Stefano Pittalis

The $\vartheta$-MGGA class of density functionals is formally reformulated as Hessian-level meta-generalized gradient approximations (HL-MGGAs). In contrast to standard meta-GGAs that rely on the orbital-dependent kinetic-energy density or…

Chemical Physics · Physics 2026-04-09 Pooria Dabbaghi , Juan Maria García Lastra , Piotr de Silva

In this contribution we assess the performance of two different exchange-correlation functionals in the first-principle prediction of the lattice thermal conductivity of bulk semiconductors, namely the local density approximation (LDA) and…

Materials Science · Physics 2018-11-16 Marco Arrigoni , Georg K. H. Madsen

In ab initio pseudopotential calculations within density-functional theory the nonlinear exchange-correlation interaction between valence and core electrons is often treated linearly through the pseudopotential. We discuss the accuracy and…

Materials Science · Physics 2009-10-30 Martin Fuchs , Michel Bockstedte , Eckhard Pehlke , Matthias Scheffler

Rare-earth oxides (REOs) are an important class of materials owing to their unique properties, including high ionic conductivities, large dielectric constants, and elevated melting temperatures, making them relevant to several technological…

We construct a meta-generalized-gradient approximation which properly balances the nonlocality contributions to the exchange and correlation at the semilocal level. This non-empirical functional shows good accuracy for a broad palette of…

Chemical Physics · Physics 2013-05-17 L. A. Constantin , E. Fabiano , F. Della Sala

We advance spin noise spectroscopy to an ultrafast tool to resolve high frequency spin dynamics in semiconductors. The optical non-demolition experiment reveals the genuine origin of the inhomogeneous spin dephasing in n-doped GaAs wafers…

Mesoscale and Nanoscale Physics · Physics 2010-04-22 Georg M. Müller , Michael Römer , Jens Hübner , Michael Oestreich

We estimate the gravitational wave spectra generated in strongly supercooled phase transitions by bubble collisions and fluid motion. We derive analytically in the thin-wall approximation the efficiency factor that determines the share of…

Cosmology and Nongalactic Astrophysics · Physics 2023-02-03 Marek Lewicki , Ville Vaskonen

The total energies and the spin states for atoms and their first ions with Z = 1-86 are calculated within the the local spin-density approximation (LSDA) and the generalized-gradient approximation (GGA) to the exchange-correlation (xc)…

Chemical Physics · Physics 2015-05-20 Eli Kraisler , Guy Makov , Itzhak Kelson

Despite their practical success, modern seq2seq architectures are unable to generalize systematically on several SCAN tasks. Hence, it is not clear if SCAN-style compositional generalization is useful in realistic NLP tasks. In this work,…

Computation and Language · Computer Science 2021-09-17 Rahma Chaabouni , Roberto Dessì , Eugene Kharitonov

We perform first-principles calculation to study the electronic structure of HgBa$_{2}$Ca$_{n-1}$Cu$_{n}$O$_{2n+2+x}$ copper oxides up to $n = 6$ for the undoped parent compound $(x = 0)$ and up to $n = 3$ for the doped compound $(x > 0)$…

Strongly Correlated Electrons · Physics 2022-10-19 Alpin N. Tatan , Jun Haruyama , Osamu Sugino

An alternative type of approximation for the exchange and correlation functional in density functional theory is proposed. This approximation depends on a variable $u$ that is able to detect inhomogeneities in the electron density $\rho$…

Materials Science · Physics 2019-01-02 Fabien Tran , Peter Blaha

Density functional theory (DFT) is a widespread and effective tool in electronic structure calculations for ground-state electron systems. Its success has prompted exploration into the use of DFT for non-collective excited states. The delta…

Chemical Physics · Physics 2025-08-12 Ethan Pollack , Rohan Maniar , John P. Perdew

Semilocal density functionals for the exchange-correlation energy are needed for large electronic systems. The Tao-Perdew-Staroverov-Scuseria (TPSS) meta-generalized gradient approximation (meta-GGA) is semilocal and usefully accurate, but…

Materials Science · Physics 2009-06-30 John P. Perdew , Adrienn Ruzsinszky , Gabor I. Csonka , Lucian A. Constantin , Jianwei Sun

Efforts to achieve efficient injection of spin-polarized electrons into a semiconductor, a key prerequisite for developing electronics that exploit the electron's spin degree of freedom, have so far met with limited success. Here we report…

Mesoscale and Nanoscale Physics · Physics 2015-06-12 Sarmita Majumder , Bartek Kardasz , George Kirczenow , Anthony SpringThorpe , Karen L. Kavanagh

We investigate fundamental properties of meta-generalized-gradient approximations (meta-GGAs) to the exchange-correlation energy functional, which have an implicit density dependence via the Kohn-Sham kinetic-energy density. To this…

Chemical Physics · Physics 2014-12-10 F. G. Eich , Maria Hellgren

In modeling low-dimensional electronic nanostructures, the evaluation of the electron-electron interaction is a challenging task. Here we present an accurate and practical density-functional approach to the two-dimensional many-electron…

Strongly Correlated Electrons · Physics 2010-10-29 S. Pittalis , E. Rasanen

Herein, we reported giant tunability of the physical properties of 2DEGs at the spinel/perovskite interface of {\gamma}-Al2O3/SrTiO3 (GAO/STO). By modulating the carrier density thus the band filling with ionic-liquid gating, the system…

Spectroscopic techniques based on core-level excitations provide powerful tools for probing molecular and electronic structures with high spatial resolution. However, accurately calculating spectral features at the L or M edges is…

Chemical Physics · Physics 2025-09-09 Sarah Pak , Muhammed A. Dada , Niranjan Govind , Daniel R. Nascimento
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