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Recent experiments showed that the chemical reaction rate is modified, either increased or decreased, by strongly coupling a nuclear vibration mode to the single mode of an optical cavity. Herein we investigate how the rate of an…

Chemical Physics · Physics 2020-05-04 Nguyen Thanh Phuc , Pham Quang Trung , Akihito Ishizaki

We present a microscopic semi-analytical theory for the description of organic molecules interacting strongly with a cavity mode. Exciton-vibration coupling within the molecule and exciton-cavity interaction are treated on an equal footing…

Mesoscale and Nanoscale Physics · Physics 2016-11-15 Ning Wu , Johannes Feist , Francisco J. Garcia-Vidal

Polaritonic states arise when a bright optical transition of a molecular ensemble is resonantly matched to an optical cavity mode frequency. Here, we lay the groundwork to study the behavior of polaritons in clean, isolated systems by…

Chemical Physics · Physics 2023-10-20 Adam D. Wright , Jane C. Nelson , Marissa L. Weichman

The polarization dependence of nonequilibrium transitions in a multistable cavity-polariton system is studied under a nanosecond long resonant optical excitation at the normal and magic angle incidences with various polarizations of the…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 S. S. Gavrilov , A. S. Brichkin , A. A. Demenev , A. A. Dorodnyy , S. I. Novikov , S. G. Tikhodeev , N. A. Gippius , V. D. Kulakovskii

In vibrational strong coupling (VSC), molecular vibrations strongly interact with the modes of an optical cavity to form hybrid light-matter states known as vibrational polaritons. Experiments show that the kinetics of thermally activated…

Quantum Physics · Physics 2021-05-04 Matthew Du , Jorge A. Campos-Gonzalez-Angulo , Joel Yuen-Zhou

We theoretically designed and experimentally demonstrated a mechanism to protect a spatially segregated mixed light-matter state, known as intercavity exciton-polariton in strongly coupled optical cavities. This excitation, shared across…

Molecular polaritons, hybrid light-matter states resulting from strong cavity coupling of optical transitions, may provide a new route to guide chemical reactions. However, demonstrations of cavity-modified reactivity in clean benchmark…

Chemical Physics · Physics 2024-08-20 Liying Chen , Ashley P. Fidler , Alexander M. McKillop , Marissa L. Weichman

Recent experiments have demonstrated that molecular polaritons, hybrid states of light and matter formed by the strong coupling between molecular electronic or vibrational excitations and an optical cavity, can substantially modify the…

Chemical Physics · Physics 2021-07-08 Nguyen Thanh Phuc

Recently, we predicted theoretically that in cavities that support several longitudinal modes, strong coupling can occur in very different manners, depending on the system parameters. Distinct longitudinal cavity modes are either entangled…

Quantum Physics · Physics 2023-10-10 M. Godsi , A. Golombek , M. Balasubrahmaniyam , T. Schwartz

Microcavity polaritons are composite half-light half-matter quasi-particles, which have recently been demonstrated to exhibit rich physical properties, such as non-equilibrium Bose-Einstein condensation, parametric scattering and…

We create exciton-polaritons in a zero-dimensional (0D) microcavity filled with organic ladder-type conjugated polymer in the strong light-matter interaction regime. Photonic confinement at wavelength scale is realized in the longitudinal…

Mesoscale and Nanoscale Physics · Physics 2019-01-23 Fabio Scafirimuto , Darius Urbonas , Ullrich Scherf , Rainer F. Mahrt , Thilo Stöferle

Polariton thermalization is a key process in achieving light-matter Bose--Einstein condensation, spanning from solid-state semiconductor microcavities at cryogenic temperatures to surface plasmon nanocavities with molecules at room…

Microcavity polaritons are strongly interacting hybrid light-matter quasiparticles, which are promising for the development of novel light sources and active photonic devices. Here, we report polariton lasing in the UV spectral range in…

We investigate the influence of exciton-phonon coupling on the dynamics of a strongly coupled quantum dot-photonic crystal cavity system and explore the effects of this interaction on different schemes for non-classical light generation. By…

The strong light-matter coupling of a microcavity mode to tightly bound Frenkel excitons in organic materials emerged as a versatile, room-temperature compatible platform to study nonlinear many-particle physics and bosonic condensation.…

We demonstrate that collective vibrational strong coupling of molecules in thermal equilibrium can give rise to significant local electronic polarizations in the thermodynamic limit. We do so by first showing that the full non-relativistic…

Recent experiments and theory demonstrate that the the ground state properties and chemical reactivity of molecules can be modified inside an optical cavity. The vibrational strong or ultrastrong coupling results in the formation of…

Chemical Physics · Physics 2022-12-01 Qi Yu

Organic microcavities are photonic nanostructures that strongly confine the electromagnetic field, allowing exotic quantum regimes of light-matter interaction with disordered organic semiconductors. The unambiguous interpretation of the…

Quantum Physics · Physics 2017-06-07 Felipe Herrera , Frank C. Spano

A model designed to mimic the implications of the collective optical response of molecular ensembles in optical cavities on molecular vibronic dynamics is investigated. Strong molecule-radiation field coupling is often reached when a large…

Chemical Physics · Physics 2022-10-05 Bingyu Cui , Abraham Nitzan

We present a study of the macroscopic dynamics of a polariton condensate formed by non-resonant optical excitation in a quasi-one-dimensional ring-shaped microcavity. The presence of a gradient in the cavity photon energy creates a…