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The past decade has seen the emergence of ab initio computational methods for calculating phonon-limited carrier mobilities in semiconductors with predictive accuracy. More realistic calculations ought to take into account additional…

Materials Science · Physics 2023-04-12 Joshua Leveillee , Xiao Zhang , Emmanouil Kioupakis , Feliciano Giustino

Scattering of carriers with ionized impurities governs charge transport in doped semiconductors. However, electron interactions with ionized impurities cannot be fully described with quantitative first-principles calculations, so their…

Materials Science · Physics 2021-10-12 I-Te Lu , Jin-Jian Zhou , Jinsoo Park , Marco Bernardi

Accurate determination of carrier transport properties in two-dimensional (2D) materials is critical for designing high-performance nano-electronic devices and quantum information platforms. While first-principles calculations effectively…

Mesoscale and Nanoscale Physics · Physics 2020-12-04 Sathwik Bharadwaj , Ashwin Ramasubramaniam , L. R. Ram-Mohan

First-principles prediction of thermal conductivity and radiative properties is crucial. However, computing phonon scattering, especially for four-phonon scattering, could be prohibitively expensive, and the thermal conductivity even for…

Materials Science · Physics 2023-11-23 Ziqi Guo , Zherui Han , Dudong Feng , Guang Lin , Xiulin Ruan

The orientational dependence of charge carrier mobilities in organic semiconductor crystals and the correlation with the crystal structure are investigated by means of quantum chemical first principles calculations combined with a model…

Materials Science · Physics 2011-04-26 V. Stehr , J. Pfister , R. F. Fink , B. Engels , C. Deibel

We present a simple and efficient approximation to the electron-phonon scattering rate suitable for high-throughput screening of candidate materials for thermoelectric devices, based on electronic transport. The method is applied to…

Materials Science · Physics 2015-11-30 Georgy Samsonidze , Boris Kozinsky

Details are presented of an efficient formalism for calculating transmission and reflection matrices from first principles in layered materials. Within the framework of spin density functional theory and using tight-binding muffin-tin…

Materials Science · Physics 2015-06-25 K. Xia , M. Zwierzycki , M. Talanana , P. J. Kelly , G. E. W. Bauer

The ab-initio theory of low-field electronic transport properties such as carrier mobility in semiconductors is well-established. However, an equivalent treatment of electronic fluctuations about a non-equilibrium steady state, which are…

Materials Science · Physics 2021-04-14 Alexander Y. Choi , Peishi Cheng , Benjamin Hatanpaa , Austin J. Minnich

The scattering of carriers by charged dislocations in semiconductors is studied within the framework of the linearized Boltzmann transport theory with an emphasis on examining consequences of the extreme anisotropy of the scattering…

Disordered Systems and Neural Networks · Physics 2013-01-09 Bhavtosh Bansal , Rituparna Ghosh , V. Venkataraman

One of the fundamental properties of semiconductors is their ability to support highly tunable electric currents in the presence of electric fields or carrier concentration gradients. These properties are described by transport coefficients…

Materials Science · Physics 2020-02-19 Samuel Poncé , Wenbin Li , Sven Reichardt , Feliciano Giustino

Recent discovery of new materials for thermoelectric energy conversion is enabled by efficient prediction of materials' performance from first-principles, without empirically fitted parameters. The novel simplified approach for computing…

Materials Science · Physics 2018-05-02 Georgy Samsonidze , Boris Kozinsky

As applied to the numerical simulation of electron transport and scattering processes in semiconductors an efficient model describing the scattering of electrons by the ionized impurities is proposed. On the example of GaAs at 77 and 300 K…

General Physics · Physics 2014-03-07 Dmitry Pozdnyakov

Efficient ab initio computational methods for the calculation of thermoelectric transport properties of materials are of great avail for energy harvesting technologies. The BoltzTraP code has been largely used to efficiently calculate…

We present a method to analyze the results of first-principles based calculations of electronic currents including inelastic electron-phonon effects. This method allows us to determine the electronic and vibrational symmeties in play, and…

Mesoscale and Nanoscale Physics · Physics 2008-06-11 Magnus Paulsson , Thomas Frederiksen , Hiromu Ueba , Nicolas Lorente , Mads Brandbyge

Over the last two decades a plethora of new thermoelectric materials, their alloys, and their nanostructures were synthesized. The ZT figure of merit, which quantifies the thermoelectric efficiency of these materials increased from values…

Materials Science · Physics 2023-07-27 Neophytos Neophytou , Pankaj Priyadarshi , Zhen Li , Patrizio Graziosi

The electronic and thermoelectric (TE) transport properties of 13 n-type and p-type half-Heusler alloys are computationally examined using Boltzmann transport. The electronic scattering times resulting from all relevant phonon interactions…

Thermoelectrics are a promising class of materials for renewable energy owing to their capability to generate electricity from waste heat, with their performance being governed by a competition between charge and thermal transport. A…

The temperature dependence of experimental charge carrier mobility is commonly used as a predictor of the dominant carrier scattering mechanism in semiconductors, particularly in thermoelectric applications. In this work, we critically…

Materials Science · Physics 2022-10-05 Alex M. Ganose , Junsoo Park , Anubhav Jain

Electron microscopy is a powerful tool for studying the properties of materials down to their atomic structure. In many cases, the quantitative interpretation of images requires simulations based on atomistic structure models. These…

We develop a practical first-principles methodology to determine nonradiative carrier capture coefficients at defects in semiconductors. We consider transitions that occur via multiphonon emission. Parameters in the theory, including…

Materials Science · Physics 2015-03-25 Audrius Alkauskas , Qimin Yan , Chris G. Van de Walle
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