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In a previous work a model was proposed for the phase transitions of crystals with localized magnetic moments which at low temperature have a "conical" arrangement that at higher T transforms into a more symmetrical structure (depending on…

Statistical Mechanics · Physics 2009-11-13 Vittorio Massidda

The results of a single-crystal X-ray-diffraction study of the evolution of crystal structures of VI3 with temperature with emphasis on phase transitions are presented. Some related specific-heat and magnetization data are included. The…

The interplay between magnetism and crystal structures in three CaFe$_{2}$As$_{2}$ samples is studied. For the nonmagnetic quenched crystals, different crystalline domains with varying lattice parameters are found, and three phases…

The investigation of the magnetic phase transitions in the parent compounds of Fe-based superconductors is regarded essential for an understanding of the pairing mechanism in the related superconducting compounds. Even though the chemical…

Superconductivity · Physics 2017-12-01 Jonas Warmuth , Martin Bremholm , Philip Hofmann , Jens Wiebe , Roland Wiesendanger

The magnetic properties of a material are determined by a subtle balance between the various interactions at play, a fact that makes the design of new magnets a daunting task. High-throughput electronic structure theory may help to explore…

Materials Science · Physics 2019-10-16 James Nelson , Stefano Sanvito

The low-temperature crystal structure of Fe1.13Te, which exhibits an anomalous two-step magnetic transition, was clarified by the systematic x-ray diffraction measurements. It was found that two-step structural phase transition,…

Magnetic and magnetocaloric properties of Y$_{1-x}$Gd$_{x}$Co$_{2}$ compounds, where x = 0.2, 0.4, 0.6, 0.8 and 1.0, were investigated experimentally and theoretically. Crystal structures were characterized by X-ray diffraction (Rietveld…

The nuclear and magnetic structure of Fe1+y(Te1-x,Sex) (0 < x < 0.20) compounds was analyzed between 2 K and 300 K by means of Rietveld refinement of neutron powder diffraction data. Samples with x < 0.075 undergo a tetragonal to monoclinic…

We employ first principles total energy and phonon calculations to address the structure and stability of Al$_2$Fe. This structure, which is reported as stable in the assessed Al-Fe phase diagram, is distinguished by an unusually low…

Materials Science · Physics 2011-07-05 M. Mihalkovič , M. Widom

Single crystals of $R$Mg$_{2}$Cu$_{9}$ ($R$=Y, Ce-Nd, Gd-Dy, Yb) were grown using a high-temperature solution growth technique and were characterized by measurements of room-temperature x-ray diffraction, temperature-dependent specific heat…

Highly-strained BiFeO3 exhibits a "tetragonal-like, monoclinic" crystal structure found only in epitaxial films (with an out-of-plane lattice parameter exceeding the in-plane value by >20%). Previous work has shown that this phase is…

Materials Science · Physics 2011-08-17 Wolter Siemons , Michael D. Biegalski , Joong Hee Nam , Hans M. Christen

Information about the crystal structures in the range of morphotropic phase boundary of ferroelectric perovskite solid solutions is important for understanding their intricate properties which result in wide opportunities for practical…

Materials Science · Physics 2025-11-04 Alexei A. Bokov , Haiyan Guo , Zuo-Guang Ye

We suceeded in the preparation of polycrystalline Ca_2FeReO_6 which has a Curie temperature of 540 K, the highest value of all magnetic perovskites investigated up to now. This material has been characterised by X-ray and neutron powder…

Materials Science · Physics 2007-05-23 W. Westerburg , O. Lang , C. Felser , W. Tremel , M. Waldeck , F. Renz , P. Guetlich , C. Ritter , G. Jakob

The evolution of the nuclear and magnetic structures of TlFe$_{1.6}$Se$_2$ was determined in the temperature range of 5-450\,K using single crystal neutron diffraction. The Fe layers in these materials develop a corrugation in the…

Precursor powders of BaMg2-xCoxFe16O27 with (x = 0.0, 1.0, and 2.0) were prepared using high-energy ball milling, and the effects of chemical composition and sintering temperature on the structural and magnetic properties were investigated…

Materials Science · Physics 2018-05-09 S. H. Mahmood , Q. Al-Shiab , I. Bsoul , Y. Maswadeh , A. Awadallah

Multiple structure and symmetry types and their transformations are discovered in quasi-two-dimensional (quasi-2D) Cr2Ge2Te6 crystal in surprisingly very narrow temperature range of 2 K and magnetic field range of 0.07 T using a homebuilt…

Materials Science · Physics 2018-03-22 Tengfei Guo , Zongwei Ma , Gaoting Lin , Xuan Luo , Yubin Hou , Yuping Sun , Zhigao Sheng , Qingyou Lu

Modern high-performance permanent magnets are made from alloys of rare earth and transition metal elements, and large magnetization is achieved in the alloys with high concentration of transition metals. We applied evolutionary search…

Materials Science · Physics 2021-05-26 Takahiro Ishikawa , Taro Fukazawa , Guangzong Xing , Terumasa Tadano , Takashi Miyake

We have grown a YCrO$_3$ single crystal by the floating-zone method and studied its temperature-dependent crystalline structure and magnetization by X-ray powder diffraction and PPMS DynaCool measurements. All diffraction patterns were well…

Strongly Correlated Electrons · Physics 2024-03-08 Qian Zhao , Yinghao Zhu , Si Wu , Junchao Xia , Pengfei Zhou , Kaitong Sun , Hai-Feng Li

Layered delafossite-type compounds and related transition metal dichalcogenides, characterized by their triangular net structures, serve as prototypical systems for exploring the intricate interplay between crystal structure and magnetic…

Materials Science · Physics 2025-02-11 Felix Eder , Catherine Witteveen , Enrico Giannini , Fabian O. von Rohr

We present a comprehensive magnetic and structural phase diagram for $\mathrm{Y_{1-x}Lu_xBaCo_4O_7}$, established through neutron diffraction and magnetization measurements. Our results outline the evolution of various nuclear structures,…

Strongly Correlated Electrons · Physics 2023-12-08 Sevda Sahinbay , Hong Zheng , John F. Mitchell , Stephan Rosenkranz , Omar Chmaissem