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Carrier multiplication (CM), a photo-physical process to generate multiple electron-hole pairs by exploiting excess energy of free carriers, is explored for efficient photovoltaic conversion of photons from the blue solar band,…

Carrier multiplication (CM), where the absorption of a single photon results in the generation of several electron-hole pairs via impact ionization, plays a pivotal role in the quest for enhancing the performance of solar cells beyond the…

Although van der Waals layered transition metal dichalcogenides from transient absorption spectroscopy have successfully demonstrated an ideal carrier multiplication (CM) performance with an onset of nearly 2Eg,interpretation of the CM…

Mesoscale and Nanoscale Physics · Physics 2021-04-20 Jun Suk Kim , Minh Dao Tran , Sung-Tae Kim , Daehan Yoo , Sang-Hyun Oh , Ji-Hee Kim , Young Hee Lee

We report here an assessment of carrier multiplication (CM) yields in PbSe and PbS nanocrystals (NCs) by a quantitative analysis of biexciton and exciton dynamics in transient photoluminescence decays. Interest in CM, the generation of more…

Materials Science · Physics 2009-11-13 Gautham Nair , Scott M Geyer , Liang-Yi Chang , Moungi G Bawendi

Hot-carrier solar cells use the photon excess energy, that is, the energy exceeding the absorber bandgap, to do additional work. These devices have the potential to beat the upper limit for the photovoltaic power conversion efficiency set…

Materials Science · Physics 2025-02-21 Priya Viji , Constantin Tormann , Clemens Göhler , Martijn Kemerink

Engineering semiconductors to enhance carrier multiplication (CM) could lead to increased photovoltaic cell performance and a significant widening of the materials range suitable for future solar technologies. Semiconductor nanocrystals…

Mesoscale and Nanoscale Physics · Physics 2007-08-30 Gautham Nair , Moungi G Bawendi

Solar cells employing quantum wells can enhance the light absorption but suffer from the difficulty in photogenerated carrier extraction. Here, we analyzed the spectral response and the photocarrier collection mechanism of p-i-n multiple…

Applied Physics · Physics 2020-06-02 Kasidit Toprasertpong , Tomoyuki Inoue , Yoshiaki Nakano , Masakazu Sugiyama

Intermediate band solar cells hold the promise of ultrahigh power conversion efficiencies using a single semiconductor junction. Many current implementations use materials with bandgaps too small to achieve maximum efficiency or use…

Applied Physics · Physics 2020-07-15 Ross Cheriton , Sharif M. Sadaf , Luc Robichaud , Jacob J. Krich , Zetian Mi , Karin Hinzer

Carrier multiplication (CM) describes a strong charge-carrier interaction process in semiconductor colloidal nanocrystals (NCs), wherein two band-edge excitons are simultaneously created by an absorbed photon with at least twice the bandgap…

Optics · Physics 2026-04-07 Zhen Zhang , Encheng Sun , Jian Li , Chunfeng Zhang , Fengrui Hu , Min Xiao , Xiaoyong Wang

Methods of exceeding the detailed balance limit for a single junction solar cell have included down-converting high energy photons to produce two photons; and carrier multiplication, whereby high energy photons produce more than one…

Materials Science · Physics 2011-05-30 Z. R. Abrams , A. Niv , C. Gladden , M. Gharghi , X. Zhang

The use of photoferroic materials that combine ferroelectric and light harvesting properties in a photovoltaic device is a promising route to significantly improve the efficiency of solar cells. These materials do not require the formation…

Materials Science · Physics 2020-03-04 Ivano E. Castelli , Thomas Olsen , Yunzhong Chen

Photovoltaic cells usually have two terminals, one collecting electrons and the other collecting holes. Can more terminals improve such solar cells? Energy-filtering terminals could collect "hot" carriers (electrons or holes not yet relaxed…

Mesoscale and Nanoscale Physics · Physics 2025-07-18 Bruno Bertin-Johannet , Thibaut Thuégaz , Janine Splettstoesser , Robert S. Whitney

It was shown in the recent experiments that the hybrid organic/inorganic resonant structures can provide a flexible materials platform aimed at the design of novel light emitting devices. The applications of hybrid structures for…

Materials Science · Physics 2008-01-25 Vladimir M. Agranovich , Gerard Czajkowski

There remains wide interest in solar cells being made using inexpensive materials and simple device manufacturing techniques to harvest ever-increasing amounts of energy. New semiconductor materials and new quantum nanostructures are…

Signal Processing · Electrical Eng. & Systems 2022-11-15 Husien Salama

Carrier selective (CS) silicon solar cells are increasingly explored using a variety of different materials. However, the optimum properties of such CS materials are not well understood. In this context, through detailed analytical and…

Applied Physics · Physics 2017-04-24 Nithin Chatterji , Aldrin Antony , Pradeep R. Nair

Hot carrier-based energy conversion systems could double the efficiency of conventional solar energy technology or drive photochemical reactions that would not be possible using fully thermalized, ``cool'' carriers, but current strategies…

It is known that silicon is an indirect band gap material, reducing its efficiency in photovoltaic applications. Using surface plasmons in metallic nanoparticles embedded in a solar cell has recently been proposed as a way to increase the…

Other Condensed Matter · Physics 2009-11-13 Martin Kirkengen , Joakim Bergli , Yuri M. Galperin

Selenium is an elemental semiconductor with a wide bandgap suitable for a range of optoelectronic and solar energy conversion technologies. However, developing such applications requires an in-depth understanding of the fundamental material…

Recently, significant progress in the development of III-V/Si dual-junction solar cells has been achieved. This not only boosts the efficiency of Si-based photovoltaic solar cells, but also offers the possibility of highly efficient green…

We demonstrate for the first time that impact ionization (II) [the inverse of Auger recombination (AR)] occurs with very high efficiency in semiconductor nanocrystals (NCs). Interband optical excitation of PbSe NCs at low pump intensities,…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 R. D. Schaller , V. I. Klimov
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