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Metal halide perovskites (MHPs) are known to undergo several structural phase transitions, from lower to higher symmetry, upon heating. While structural phase transitions have been investigated by a wide range of optical, thermal and…

Materials Science · Physics 2022-03-07 Shunran Li , Zhenghong Dai , Conrad A. Kocoj , Eric I. Altman , Nitin P. Padture , Peijun Guo

Antiperovskites share the same structure as perovskites, but allow completely different chemistries and nominal charge states of anions to be stabilized. This gives rise to many interesting phenomena, including septet superconductivity and…

Materials Science · Physics 2026-02-09 He Zhu , Turan Birol

We report the discovery of a new noncentrosymmetric superconductor CaPtAs. It crystallizes in a tetragonal structure (space group $I4_1md$, No.109), featuring three dimensional honeycomb networks of Pt-As and a much elongated $c$-axis ($a =…

Superconductivity · Physics 2020-01-22 W. Xie , P. R. Zhang , B. Shen , W. B. Jiang , G. M. Pang , T. Shang , C. Cao , M. Smidman , H. Q. Yuan

We studied the effect of hydrostatic pressure (P) on the structural phase transitions and superconductivity in the ternary and pseudo-ternary iron arsenides CaFe2As2, BaFe2As2, and (Ba0.55K0.45)Fe2As2, by means of measurements of electrical…

Superconductivity · Physics 2015-05-13 M. S. Torikachvili , S. L. Budko , Ni Ni , P. C. Canfield

We report the superconducting properties of single crystals of the intermetallic perovskite-related compound BaBi$_{3}$. The superconducting transition temperature ($T_{c}=5.82$~K) was obtained from heat capacity measurements. Using the…

Superconductivity · Physics 2015-06-19 Neel Haldolaarachchige , S. K. Kushwaha , Quinn Gibson , R. J. Cava

We report systematic investigation of high pressure crystal structures and structural phase transition upto 46 GPa in CaFeAsF and 40 GPa in SrFeAsF at 40 K using powder synchrotron x-ray diffraction experiments and Rietveld analysis of the…

Neutron powder diffraction measurements, combined with magnetization and resistivity data, have been carried out in the doped perovskite La$_{1-x}$Ca$_x$MnO$_3$ ($x=0.47$, 0.50, and 0.53) to elucidate the structural, magnetic, and…

Strongly Correlated Electrons · Physics 2009-10-31 Q. Huang , J. W. Lynn , R. W. Erwin , A. Santoro , D. C. Dender , V. N. Smolyaninova , K. Ghosh , R. L. Greene

Pure phases of a new oxyarsenide superconductor of the nominal composition CeOFe0.9Co0.1As was successfully synthesized by solid state reaction in sealed silica ampoules at 1180 C. It crystallizes in the layered tetragonal ZrCuSiAs type…

Superconductivity · Physics 2009-03-24 J. Prakash , S. J. Singh , S. Patnaik , A. K. Ganguli

We report synthesis of non-centrosymmetric BiPd single crystal by self flux method. The BiPd single crystal is crystallized in monoclinic structure with the P21 space group. Detailed SEM (Scanning Electron Microscopy) results show that the…

Superconductivity · Physics 2016-01-20 Rajveer Jha , Reena Goyal , P. Neha , V. Maurya , A. Srivastava , Anurag Gupta , S. Patnaik , V. P. S. Awana

The recent surprising discovery of superconductivity with critical temperature $T_c$ = 32 K in MoB$_2$ above 70 GPa has led to the search for related materials that may superconduct at similarly high $T_c$ values and lower pressures. We…

Transport and magnetic studies of PbTaSe$_2$ under pressure suggest existence of two superconducting phases with the low temperature phase boundary at $\sim 0.25$ GPa that is defined by a very sharp, first order, phase transition. The first…

By means of synchrotron X-ray diffraction, we studied the effect of high pressure, P, up to 13 GPa on the room temperature crystal structure of superconducting CaC6. In this P range, no change of the pristine space group symmetry,…

Single crystals of Ca$_3$(Ir$_{1-x}$Rh$_x$)$_4$Sn$_{13}$ (3-4-13) were synthesized by flux growth and characterized by X-ray diffraction, EDX, magnetization, resistivity and radio frequency magnetic susceptibility tunnel diode resonator…

Bismuth displays puzzling superconducting properties. In its crystalline equilibrium phase, it does not seem to superconduct at accessible low temperatures. However, in the amorphous phase it displays superconductivity at ~ 6 K. Under…

Single crystals of Bi$_{2} $Rh$ _{3}$S$ _{2}$ and Bi$_{2} $Rh$ _{3.5}$S$ _{2}$ were synthesized by solution growth and the crystal structures, thermodynamic and transport properties of both compounds were studied. In the case of Bi$_{2}…

We report measurements of the specific heat and resistivity (T < 1 K) for high quality polycrystals of U(Pt1-xPdx)3 with x < 0.006. The Tc-x phase diagram can be constructed, and superconductivity is destroyed for x = 0.006; this is…

Strongly Correlated Electrons · Physics 2009-10-31 M. J. Graf , R. J. Keizer , A. de Visser , J. J. M. Franse

The evolution of pressure induced superconductivity in single crystal as well as polycrystalline samples of BaFe2As2 has been investigated through temperature dependent electrical resistivity studies in 0-7 GPa pressure range. While the…

Superconductivity · Physics 2015-05-13 Awadhesh Mani , Nilotpal Ghosh , S. Paulraj , A. Bharathi , C. S. Sundar

We report the transport, thermodynamic, $\mu$SR and neutron study of the Ca$_{0.74(1)}$La$_{0.26(1)}$(Fe$_{1-x}$Co$_{x}$)As$_{2}$ single crystals, mapping out the temperature-doping level phase diagram. Upon Co substitution on the Fe site,…

The newly discovered BaPt$_2$As$_2$ shows a structural distortion at around 275~K, followed by the emergence of superconductivity at lower temperatures. Here we identify the presence of charge density wave (CDW) order at room temperature…

Superconductivity · Physics 2016-11-18 C. Y. Guo , W. B. Jiang , M. Smidman , F. Han , C. D. Malliakas , B. Shen , Y. F. Wang , Y. Chen , X. Lu , M. G. Kanatzidis , H. Q. Yuan

Systematic measurements of the resistivity, heat capacity, susceptibility and Hall coefficient are presented for single crystal samples of the electron-doped superconductor Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$. These data delineate an $x-T$ phase…

Superconductivity · Physics 2009-05-02 Jiun-Haw Chu , James G. Analytis , Chris Kucharczyk , Ian R. Fisher