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We extend density matrix embedding theory to periodic systems, resulting in an electronic band structure method for solid-state materials. The electron correlation can be captured by means of a local impurity model using various choices of…

Strongly Correlated Electrons · Physics 2019-09-27 Hung Q. Pham , Matthew R. Hermes , Laura Gagliardi

Choosing optimal representation methods of atomic and electronic structures is essential when machine learning properties of materials. We address the problem of representing quantum states of electrons in a solid for the purpose of machine…

Computational Physics · Physics 2022-02-08 Nikolaj Rørbæk Knøsgaard , Kristian Sommer Thygesen

We benchmark many-body perturbation theory against density functional theory (DFT) for the band gaps of solids. We systematically compare four $GW$ variants $-$ $G_{0}W_{0}$ using the Godby-Needs plasmon-pole approximation…

Materials Science · Physics 2026-01-19 Max Großmann , Marc Thieme , Malte Grunert , Erich Runge

We present a detailed calculation of the electronic structure of SrVO$_{3}$ based on the GW+DMFT method. We show that a proper inclusion of the frequency-dependent Hubbard U and the nonlocal self-energy via the GW approximation, as well as…

Strongly Correlated Electrons · Physics 2013-12-13 R. Sakuma , Ph. Werner , F. Aryasetiawan

By recasting the non-linear frequency-dependent $GW$ quasiparticle equation into a linear eigenvalue problem, we explain the appearance of multiple solutions and unphysical discontinuities in various physical quantities computed within the…

Chemical Physics · Physics 2022-06-16 Enzo Monino , Pierre-François Loos

We present an implementation of all-electron density-functional theory for massively parallel GPGPU-based platforms, using localized atom-centered basis functions and real-space integration grids. Special attention is paid to domain…

Computational Physics · Physics 2020-07-24 William Huhn , Björn Lange , Victor Wen-zhe Yu , Mina Yoon , Volker Blum

This paper presents a weak Galerkin (WG) finite element method for linear elasticity on general polygonal and polyhedral meshes, free from convexity constraints, by leveraging bubble functions as central analytical tools. The proposed…

Numerical Analysis · Mathematics 2024-11-28 Chunmei Wang , Shangyou Zhang

In this paper, we construct an efficient numerical scheme for full-potential electronic structure calculations of periodic systems. In this scheme, the computational domain is decomposed into a set of atomic spheres and an interstitial…

Numerical Analysis · Mathematics 2024-12-20 Xiaoxu Li , Huajie Chen

We study the spectral function of the homogeneous electron gas using many-body perturbation theory and the cumulant expansion. We compute the angle-resolved spectral function based on the GW approximation and the `GW plus cumulant'…

Materials Science · Physics 2016-11-23 Fabio Caruso , Feliciano Giustino

Using the simple (symmetric) Hubbard dimer, we analyze some important features of the $GW$ approximation. We show that the problem of the existence of multiple quasiparticle solutions in the (perturbative) one-shot $GW$ method and its…

Chemical Physics · Physics 2021-10-12 Stefano Di Sabatino , Pierre-François Loos , Pina Romaniello

Many-body perturbation theory in the GW approximation is a useful method for describing electronic properties associated with charged excitations. A hierarchy of GW methods exists, starting from non-self-consistent G0W0, through partial…

The ground-state many-body electron momentum density, which can be probed by x-ray Compton scattering, holds insights into the electronic structure of materials. Comparisons between the measured so-called Compton profiles and the…

Strongly Correlated Electrons · Physics 2026-05-29 A. D. N. James , J. A. Gould , T. M. Mason , J. Jackson , S. B. Dugdale

We consider theoretically the electron--electron interaction induced exchange-correlation effects in the lowest subband of a quasi-one-dimensional GaAs quantum wire structures. We calculate, within the leading order dynamical screening…

Condensed Matter · Physics 2007-05-23 Ben Yu-Kuang Hu , S. Das Sarma

We propose an approach for the ab initio calculation of materials with strong electronic correlations which is based on all local (fully irreducible) vertex corrections beyond the bare Coulomb interaction. It includes the so-called GW and…

Strongly Correlated Electrons · Physics 2015-03-19 A. Toschi , G. Rohringer , A. A. Katanin , K. Held

An alternative to Density Functional Theory are wavefunction based electronic structure calculations for solids. In order to perform them the Exponential Wall (EW) problem has to be resolved. It is caused by an exponential increase of the…

Chemical Physics · Physics 2017-06-07 Peter Fulde , Hermann Stoll

We calculate the single-particle excitation spectrum and the Landau Fermi liquid parameters for the archetypal model of solids, the three-dimensional uniform electron gas, with the numerically exact variational diagrammatic Monte Carlo…

Strongly Correlated Electrons · Physics 2021-06-08 Kristjan Haule , Kun Chen

This paper describes an all-electron implementation of the self-consistent GW (sc-GW) approach -- i.e. based on the solution of the Dyson equation -- in an all-electron numeric atom-centered orbital (NAO) basis set. We cast Hedin's…

Materials Science · Physics 2013-08-12 Fabio Caruso , Patrick Rinke , Xinguo Ren , Angel Rubio , Matthias Scheffler

A new implementation of the GW approximation (GWA) based on the all-electron Projector-Augmented-Wave method (PAW) is presented, where the screened Coulomb interaction is computed within the Random Phase Approximation (RPA) instead of the…

Materials Science · Physics 2009-11-10 S. Lebègue , B. Arnaud , M. Alouani , P. E. Bloechl

The automation of ab initio simulations is essential in view of performing high-throughput (HT) computational screenings oriented to the discovery of novel materials with desired physical properties. In this work, we propose algorithms and…

The auxiliary-field quantum Monte Carlo (AFQMC) method is a general numerical method for correlated many-electron systems, which is being increasingly applied in lattice models, atoms, molecules, and solids. Here we introduce the theory and…

Computational Physics · Physics 2021-02-24 Hao Shi , Shiwei Zhang