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Determining how energy flows within and between molecules is crucial for understanding chemical reactions, material properties, and even vital processes such as photosynthesis. While the general principles of energy transfer are well…

Other Condensed Matter · Physics 2025-12-16 Ignacio Gustin , Chang Woo Kim , Ignacio Franco

To investigate the effect of quantum coherence on electronic energy transfer, which is the subject of current interest in photosynthesis, we solve the problem of transport for the simplest model of an aggregate of monomers interacting…

Quantum Physics · Physics 2015-03-19 J. S. Briggs , A. Eisfeld

Molecular vibrations in solutions, especially OH stretching and bending in water, drive ultrafast energy relaxation and dephasing in chemical and biological systems. We present a machine learning approach for constructing system-bath models…

Chemical Physics · Physics 2026-03-18 Kwanghee Park , Ju-Yeon Jo , Yoshitaka Tanimura

The Q-cycle mechanism entering the electron and proton transport chain in oxygenic photosynthesis is an example of how biological processes can be efficiently investigated with elementary microscopic models. Here we address the problem of…

Quantum Physics · Physics 2019-11-21 Francesco Tacchino , Antonella Succurro , Oliver Ebenhöh , Dario Gerace

Recently, the dynamics simulation of light-harvesting complexes as an open quantum system, in the weak and strong coupling regimes, has received much attention. In this paper, we investigate a digital quantum simulation approach of the…

Quantum Physics · Physics 2020-10-02 M. Mahdian , H. Davoodi Yeganeh , A. Dehghani

The hierarchical equations of motion (HEOM) method is a numerically exact open quantum system dynamics approach. The method is rooted in an exponential expansion of the bath correlation function, which in essence strategically reshapes a…

Chemical Physics · Physics 2023-06-14 Yaling Ke

We investigate the evolution of entanglement in the Fenna-Matthew-Olson (FMO) complex based on simulations using the scaled hierarchy equation of motion (HEOM) approach. We examine the role of multipartite entanglement in the FMO complex by…

Chemical Physics · Physics 2012-08-23 Jing Zhu , Sabre Kais , Alán Aspuru-Guzik , Sam Rodriques , Ben Brock , Peter J. Love

The most recent crystal structure of the Fenna-Matthews-Olson (FMO) protein complex indicates that each subunit contains an additional eighth chromophore. It has been proposed that this extra site functions as a link between the chlorosome…

Biological Physics · Physics 2011-09-16 Jeremy Moix , Jianlan Wu , Pengfei Huo , David Coker , Jianshu Cao

Following the calculation of optimal energy transfer in thermal environment in our first paper (Wu et al., New J. Phys., 2010, 12, 105012), full quantum dynamics and leading-order `classical' hopping kinetics are compared in the seven-site…

Chemical Physics · Physics 2015-05-30 Jianlan Wu , Fan Liu , Jian Ma , Robert J. Silbey , Jianshu Cao

During the first steps of photosynthesis, the energy of impinging solar photons is transformed into electronic excitation energy of the light-harvesting biomolecular complexes. The subsequent energy transfer to the reaction center is…

Using a formalism adapted to study transport in quantum open systems, that is the nonequilibrium Green's function formalism, we revisit the working principle of the most popular photosynthetic complex, namely the Fenna Matthews-Olson…

Biological Physics · Physics 2024-10-23 A. -M Daré , C Demarez , J Missirian , F Michelini

Quantum effects in photosynthetic energy transport in nature, especially for the typical Fenna-Matthews-Olson (FMO) complexes, are extensively studied in quantum biology. Such energy transport processes can be investigated as open quantum…

Primitive photosynthetic cells appear over three billion years prior to any other more complex life-forms, thus it is reasonable to assume that Nature has designed a photosynthetic mechanism using minimal resources but honed to perfection…

Quantum Physics · Physics 2011-06-23 B. Cui , X. Y. Zhang , X. X. Yi

Open quantum systems that feature non-Markovian dynamics are routinely solved using techniques such as the Hierarchical Equations of Motion (HEOM). However, their usage of the entire system density-matrix renders them intractable for…

Quantum Physics · Physics 2025-06-30 Kai Müller , Kimmo Luoma , Christian Schäfer

Using quantum algorithms to simulate complex physical processes and correlations in quantum matter has been a major direction of quantum computing research, towards the promise of a quantum advantage over classical approaches. In this work…

Quantum Physics · Physics 2022-06-01 Zixuan Hu , Kade Head-Marsden , David A. Mazziotti , Prineha Narang , Sabre Kais

The application of open quantum systems in biological processes such as photosynthetic complexes has recently received renewed attention. In this paper, we introduce a quantum algorithm for simulation of Markovian dynamics of the…

Quantum Physics · Physics 2020-10-28 M. Mahdian , H. Davoodi Yeganeh

We present a study on the evolution of the Fenna-Matthews-Olson bacterial photosynthetic pigment-protein complex. This protein complex functions as an antenna. It transports absorbed photons - excitons - to a reaction center where…

The excitation energy transfer (EET) in Fenna-Matthews-Olson (FMO) complex has been investigated in the presence of realistic inhomogeneous protein environment around different bacteriochlorophyll-a (BChla) sites of a 8-site monomer. We…

Biological Physics · Physics 2018-05-17 Davinder Singh , Shubhrangshu Dasgupta

Coherent energy transfer in pigment-protein complexes has been studied by mapping the quantum network to a kinetic network. This gives an analytic way to find parameter values for optimal transfer efficiency. In the case of the…

Quantum Physics · Physics 2012-01-30 David K Moser

An open quantum system refers to a system that is further coupled to a bath system consisting of surrounding radiation fields, atoms, molecules, or proteins. The bath system is typically modeled by an infinite number of harmonic…

Chemical Physics · Physics 2020-07-10 Yoshitaka Tanimura