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A model for impedance of a PEM fuel cell cathode catalyst layer under simultaneous application of potential and oxygen concentration perturbations is developed and solved. The resulting expression demonstrates dramatic lowering of the layer…

Chemical Physics · Physics 2023-10-16 Andrei Kulikovsky

Effective water management is essential for the optimal performance of PEM fuel cells. We have developed an impedance model for liquid water transport through the membrane and coupled it with the two-phase model for cathode side impedance.…

Chemical Physics · Physics 2026-01-16 Andrei Kulikovsky , Tatyana Reshetenko

We have developed a non-isothermal analytical model for the impedance of the cathode catalyst layer (CCL) in a PEM fuel cell. In-phase harmonic perturbations to the current density and temperature reduce the impedance and the static…

Chemical Physics · Physics 2026-03-20 Andrei Kulikovsky

A PEM fuel cell was specially constructed to determine kinetics under conditions of well-defined gas phase composition and cell temperature. Steady state multiplicity was discovered in the autohumidification PEM fuel cell, resulting from a…

Chemical Physics · Physics 2016-09-08 J. B. Benziger , J. Moxley , S. Tulyani , A. Turner , A. B. Bocarsly , Y. G. Kevrekidis

Five parameters of a model of a polymer electrolyte membrane fuel cell cathode (the porosity of the gas diffusion layer, the porosity of the catalyst layer, the exchange current density of the oxygen reduction reaction, the effective ionic…

Materials Science · Physics 2013-08-22 Qingzhi Guo , Vijay A. Sethuraman , Ralph E. White

Analytical model for impedance of oxygen transport in the gas--diffusion layer (GDL) and cathode channel of a PEM fuel cell is developed. The model is based on transient oxygen mass conservation equations coupled to the proton current…

Chemical Physics · Physics 2021-11-09 Andrei Kulikovsky

Fluid, heat and species transport and oxygen reduction in the cathode of a PEM fuel cell are simulated using multi relaxation lattice Boltzmann method. Heat generation due to oxygen reduction and its effects on transport and reaction are…

Fluid Dynamics · Physics 2021-03-03 M. Jithin , Saurabh Siddharth , Malay K. Das , Ashoke De

Impedance of all oxygen transport processes in PEM fuel cell has negative real part in some frequency domain. A model function (kernel) for calculation of distribution of relaxation times (DRT) of a PEM fuel cell is suggested. The kernel is…

Chemical Physics · Physics 2021-09-30 Andrei Kulikovsky

Under typical PEM fuel cell operating conditions, part of membrane electrode assembly is subjected to humidity cycling due to variation of inlet gas RH and/or flow rate. Cyclic membrane hydration/dehydration would cause cyclic…

Water produced in a Polymer Electrolyte Membrane (PEM) fuel cell enhances membrane proton conductivity; this positive feedback loop can lead to current ignition. Using a segmented anode fuel cell we study the effect of gas phase convection…

Pattern Formation and Solitons · Physics 2007-05-23 J. B. Benziger , E. -S. Chia , Y. De Decker , I. G. Kevrekidis

Proton Exchange Membrane Fuel Cell (PEMFC) is widely recognized for its cleanliness and high efficiency, but is still facing challenges in cold environments. At low temperatures, the formation of ice and repeated freezing/thawing cycles may…

Fluid Dynamics · Physics 2026-05-15 Wenzhe Zhang , Xingxiao Tao , Qifeng Li , Kai Sun , Rui Chen , Zhizhao Che , Tianyou Wang

Under the dual background of deep adjustment of global energy pattern and severe challenges of environmental problems, solid oxide fuel cell (SOFC) has become the focus of research on efficient and clean energy conversion technology due to…

Applied Physics · Physics 2025-11-04 Wang Hao , Xie Jiamiao , Hao Wenqian , Li Jingyang , Zhang Peng , Ma Xiaofan , Liu Fu , Wang Xu

A PEM micro fuel cell system is described which is based on self-breathing PEM micro fuel cells in the power range between 1 mW and 1W. Hydrogen is supplied with on-demand hydrogen production with help of a galvanic cell, that produces…

Other Computer Science · Computer Science 2008-12-18 Robert Hahn , Stefan Wagner , Steffen Krumbholz , Herbert Reichl

The design and operation of a differential Polymer Electrolyte Membrane (PEM) fuel cell is described. The fuel cell design is based on coupled Stirred Tank Reactors (STR); the gas phase in each reactor compartment was well mixed. The…

Chemical Physics · Physics 2007-05-23 Jay Benziger , E. Chia , E. Karnas , J. Moxley , C. Teuscher , I. G. Kevrekidis

We present a macrohomogeneous two-phase model of a proton exchange membrane fuel cell (PEMFC). The model takes into account the mechanical compression of the gas diffusion layer (GDL), the two-phase flow of water, the transport of the gas…

A one-dimensional, dynamic, two-phase, isothermal model of proton exchange membrane fuel cell systems using a finite-difference approach has been developed. This model balances the simplicity of lumped-parameter models with the detailed…

Systems and Control · Electrical Eng. & Systems 2026-01-28 Raphaël Gass , Zhongliang Li , Rachid Outbib , Samir Jemei , Daniel Hissel

This paper presents a hierarchical multivariable control and constraint management approach for an air supply system for a proton exchange membrane fuel cell (PEMFC) system. The control objectives are to track desired compressor mass…

Systems and Control · Electrical Eng. & Systems 2025-10-17 Eli Bacher-Chong , Mostafa Ali Ayubirad , Zeng Qiu , Hao Wang , Alireza Goshtasbi , Hamid R. Ossareh

Gas diffusion layers (GDLs) play a crucial role for the performance of proton exchange membrane fuel cells (PEMFCs). The utilization of composite foam-rib flow fields (CFRFFs) can alter the reactant gas transfer pattern, hence improving the…

Fluid Dynamics · Physics 2026-04-03 Wei Gao , Qifeng Li , Kai Sun , Rui Chen , Zhizhao Che , Tianyou Wang

The mechanical properties of PC12 living cells have been studied at the nanoscale with a Force Feedback Microscope using two experimental approaches. Firstly, the local mechanical impedance of the cell membrane has been mapped…

A proton exchange membrane fuel cell (PEMFC) for low power and portable applications is studied with thermal neutron radiography. The PEMFC operates under full passive conditions, with an air-breathing cathode and a dead-end anode supplied…

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