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To solve the many-boson Schr\"odinger equation we utilize the Multiconfigurational time-dependent Hartree method for bosons (MCTDHB). To be able to attack larger systems and/or to propagate the solution for longer times, we implement a…

Quantum Gases · Physics 2011-04-19 Alexej I. Streltsov , Kaspar Sakmann , Ofir E. Alon , Lorenz S. Cederbaum

This paper introduces and analyses the new grid-based tensor approach for approximate solution of the eigenvalue problem for linearized Hartree-Fock equation applied to the 3D lattice-structured and periodic systems. The set of localized…

Numerical Analysis · Mathematics 2014-08-19 Venera Khoromskaia , Boris N. Khoromskij

We present a real-space formulation and higher-order finite-difference implementation of periodic Orbital-free Density Functional Theory (OF-DFT). Specifically, utilizing a local reformulation of the electrostatic and kernel terms, we…

Computational Physics · Physics 2015-12-23 Swarnava Ghosh , Phanish Suryanarayana

To go beyond Gaussian approximation to the Hohenberg-Kohn free energy playing the key role in the density functional theory (DFT), the density functional \textit{integral} representation would be relevant, because field theoretical approach…

Soft Condensed Matter · Physics 2009-10-31 H. Frusawa , R. Hayakawa

Recently we proposed an information entropy based method for electronic structure calculations within the density-matrix functional theory(DMFT) (Phys. Rev. Lett. 128, 013001), dubbed as $i$-DMFT. Comments have been raised regarding the…

Quantum Physics · Physics 2022-07-07 Jian Wang , Evert Jan Baerends

A real-space formalism for density-functional perturbation theory (DFPT) is derived and applied for the computation of harmonic vibrational properties in molecules and solids. The practical implementation using numeric atom-centered…

Materials Science · Physics 2017-03-08 Honghui Shang , Christian Carbogno , Patrick Rinke , Matthias Scheffler

We propose a Forward-Backward Truncated-Newton method (FBTN) for minimizing the sum of two convex functions, one of which smooth. Unlike other proximal Newton methods, our approach does not involve the employment of variable metrics, but is…

Optimization and Control · Mathematics 2019-11-11 Andreas Themelis , Masoud Ahookhosh , Panagiotis Patrinos

We extend density functional perturbation theory for lattice dynamics with fully relativistic ultrasoft pseudopotentials to magnetic materials. Our approach is based on the application of the time-reversal operator to the Sternheimer linear…

Computational Physics · Physics 2019-07-24 Andrea Urru , Andrea Dal Corso

High-level vibrational calculations have been used to investigate anharmonicity in a wide variety of materials using density-functional-theory (DFT) methods. We have developed a new and efficient approach for describing strongly-anharmonic…

Materials Science · Physics 2017-06-20 Joseph C. A. Prentice , R. J. Needs

Exciton formation leads to J-bands in solid pentacene. Describing these exciton bands represents a challenge for both time-dependent (TD) density-functional theory (DFT) and for its semiempirical analogue, namely for TD density-functional…

We introduce a method for calculating the dielectric function of nanostructures with an arbitrary band dispersion and Bloch wave functions. The linear response of a dissipative electronic system to an external electromagnetic field is…

Mesoscale and Nanoscale Physics · Physics 2016-06-07 F. Karimi , A. H. Davoody , I. Knezevic

Response calculations in density functional theory aim at computing the change in ground-state density induced by an external perturbation. At finite temperature these are usually performed by computing variations of orbitals, which involve…

Numerical Analysis · Mathematics 2023-04-04 Eric Cancès , Michael F. Herbst , Gaspard Kemlin , Antoine Levitt , Benjamin Stamm

First-principles calculations using the plane-wave pseudopotential method within the generalized gradient approximation method were performed to study the pressure dependence of the structural, elastic, electronic and optical properties for…

Materials Science · Physics 2021-12-21 M. Radjai , A. Bouhemadou , D. Maouche

In this paper, we present an hp-adaptive hybrid Discontinuous Galerkin/Finite Volume method for simulating compressible, turbulent multi-component flows. Building on a previously established hp-adaptive strategy for hyperbolic gas- and…

In this work, we present an empirical force field for hexagonal boron nitride (hBN) monolayers, derived via a bottom-up strategy from first principles calculations. We aim to deliver a simple analytical force field for boron nitride which…

Mesoscale and Nanoscale Physics · Physics 2025-05-06 Aristotelis P. Sgouros , Markos Arapchatzis , Nektarios N. Lathiotakis , Konstantinos Papagelis , George Kalosakas

We present a first-principles framework for the calculation of phonons in nanostructures with cyclic and/or helical symmetry. In particular, we derive a cyclic- and helical-symmetry-adapted representation of the dynamical matrix at…

Materials Science · Physics 2026-03-27 Abhiraj Sharma , Phanish Suryanarayana

A self-consistent calculation scheme for correlated electron systems is created based on the density-functional theory (DFT). Our scheme is a multi-reference DFT (MR-DFT) calculation in which the electron charge density is reproduced by an…

Strongly Correlated Electrons · Physics 2009-11-13 Koichi Kusakabe , Naoshi Suzuki , Shusuke Yamanaka , Kizashi Yamaguchi

A recently developed density functional method, within Hohenberg-Kohn-Sham framework, is used for faithful description of atoms, molecules in Cartesian coordinate grid, by using an LCAO-MO ansatz. Classical Coulomb potential is obtained by…

Chemical Physics · Physics 2013-07-16 Amlan K. Roy

There has been an increasing interest in developing efficient immersed boundary method (IBM) based on Cartesian grids, recently in the context of high-order methods. IBM based on volume penalization is a robust and easy to implement method…

Numerical Analysis · Mathematics 2021-07-22 Jiaqing Kou , Esteban Ferrer

Electronic structure calculation of atoms and molecules, in the past few decades has largely been dominated by density functional methods. This is primarily due to the fact that this can account for electron correlation effects in a…

Chemical Physics · Physics 2013-07-12 Amlan K. Roy
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