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We present x-ray, neutron scattering and heat capacity data that reveal a coupled first-order magnetic and structural phase transition of the metastable mixed-valence post-spinel compound Mn$_3$O$_4$ at 210 K. Powder neutron diffraction…

Ca2RuO4 is a structurally-driven Mott insulator with a metal-insulator transition at TMI = 357K, followed by a well-separated antiferromagnetic order at TN = 110 K. Slightly substituting Ru with a 3d transition metal ion M effectively…

Strongly Correlated Electrons · Physics 2015-05-30 T. F. Qi , O. B. Korneta , S. Parkin , Jiangping Hu , G. Cao

We present an elaborate electron-spin resonance study of the low-energy dynamics and magnetization in the ordered phase of the magnetically frustrated spinel ZnCr$_2$O$_4$. We observe several resonance modes corresponding to different…

Strongly Correlated Electrons · Physics 2010-11-29 V. N. Glazkov , A. M. Farutin , V. Tsurkan , H. -A. Krug von Nidda , A. Loidl

The inversion and volume effects on magnetism in a spinel-type magnetically frustrated compound, CoAl2O4, and its gallium-substituted system, CoAl2-xGaxO4, were investigated. Magnetically frustrated Co2+ with spin S = 3/2 on the tetrahedral…

Collective behaviour of electrons, frustration induced quantum fluctuations and entanglement in quantum materials underlie some of the emergent quantum phenomena with exotic quasi-particle excitations that are highly relevant for…

We report comprehensive studies of the crystallographic,magnetic, and thermal properties of a spinel-type magnetically frustrated compound, CoAl2O4, and a magnetically diluted system,Co1-xZnxAl2O4. These studies revealed the effects of…

The effects of nonmagnetic Zn and magnetic Ni substitution for Cu site on magnetism are studied by measurements of uniform magnetic susceptibility for lightly doped La_{2-x}Sr_xCu_{1-z}M_zO_4 (M=Zn or Ni) polycrystalline samples. For the…

Superconductivity · Physics 2009-11-10 T. Machi , I. Kato , R. Hareyama , N. Watanabe , Y. Itoh , N. Koshizuka , S. Arai , M. Murakami

Recent experiments on Mn doped multiferroic $CoCr_{2}O_{4}$ indicate that a possible distribution of Mn atoms among tetrahedrally and octahedrally coordinated sites in the spinel lattice give rise to different variations in the structural…

Materials Science · Physics 2017-01-04 Debashish Das , Subhradip Ghosh

Large magnetocaloric effect has been observed in Mn3O4 around its ferrimagnetic transition at TN = 42.75 K. Field-induced isothermal entropy changes (\DeltaS) were derived from both magnetic and calorimetric techniques. The maximum…

Materials Science · Physics 2011-03-04 S. Thota , F. Guillou , V. Hardy , A. Wahl , W. Prellier , J. Kumar

We present high-resolution triple-axis neutron scattering studies of the high-temperature superconductor La1.88Sr0.12CuO4 (Tc=27 K). The temperature dependence of the low-energy incommensurate magnetic fluctuations reveals distinctly glassy…

Lattice modulation and magnetic structures in magnetoelectric compounds Tb1-xDyxMnO3 have been studied around the ferroelectric (FE) Curie temperature T_C by x-ray and neutron diffraction. Temperature-independent modulation vectors through…

Strongly Correlated Electrons · Physics 2009-11-11 T. Arima , A. Tokunaga , T. Goto , H. Kimura , Y. Noda , Y. Tokura

We have synthesized the novel material Na_2IrO_3 and studied its structure, transport, magnetic, and thermal properties using powder x-ray diffraction (PXRD), electrical resistivity, isothermal magnetization M versus magnetic field H,…

Strongly Correlated Electrons · Physics 2010-06-04 Yogesh Singh , P. Gegenwart

Neutron diffraction, magnetization and muon spin relaxation measurements, supplemented by density functional theory (DFT) calculations are employed to unravel temperature-driven magnetization reversal (MR) in inverse spinel Co$_2$VO$_4$.…

Mn1-xZnxCr2O4 (0<x<1) single crystals have been grown by the chemical vapor transport (CVT) method. The crystallographic, magnetic, and thermal transport properties of the single crystals were investigated by the room-temperature X-ray…

Strongly Correlated Electrons · Physics 2016-02-29 G. T. Lin , X. Luo , Q. L. Pei , F. C. Chen , C. Yang , J. Y. Song , L. H. Yin , W. H. Song , Y. P. Sun

We have investigated the structural and magnetic properties of a new cubic spinel LiZn$_{2}$V$_{3}$O$_{8}$ (LZVO) through x-ray diffraction, dc and ac susceptibility, magnetic relaxation, aging, memory effect, heat capacity and $^{7}$Li…

Strongly Correlated Electrons · Physics 2020-01-01 S. Kundu , T. Dey , A. V. Mahajan , N. Büttgen

The spinel NiCr$_2$O$_4$ is known to show a ferrimagnetic transition at $T_c = 70$~K, and magneto-structural transitions at $T_s = 30$~K and $T_o = 20$~K\@. We present a detailed magnetic and magnetocaloric effect (MCE $= -\Delta S_{M}(T)$)…

Strongly Correlated Electrons · Physics 2018-11-20 Anzar Ali , Gyaneshwar Sharma , Yogesh Singh

The spinel-structured lithium manganese oxide (LiMn$_2$O$_4$) is a material currently used as cathode for secondary lithium-ion batteries, but whose properties are not yet fully understood. Here, we report a computational investigation of…

Materials Science · Physics 2018-03-14 David Santos-Carballal , Phuti E. Ngoepe , Nora H. de Leeuw

The spin states at the surface of epitaxial thin films of hematite, both undoped and doped with 1% Ti, Sn or Zn, respectively, were probed with x-ray magnetic linear dichroism (XMLD) spectroscopy. Morin transitions were observed for the…

The magnetic and lattice properties of the $S$=1/2 quantum-spin-chain ferromagnet, CuAs$_2$O$_4$, mineral name trippkeite, were investigated. The crystal structure of CuAs$_2$O$_4$ is characterized by the presence of corrugated CuO$_2$…

Materials Science · Physics 2015-06-18 K. Caslin , R. K. Kremer , F. S. Razavi , A. Schulz , A. Muñoz , F. Pertlik , J. Liu , M. -H. Whangbo , J. M. Law

We report the results of ac and dc magnetization (M) and heat-capacity (C) measurements on the solid solution, Sr$_3$Cu$_{1-x}$Zn$_x$IrO$_6$. While the Zn end member is known to form in a rhombohedral pseudo one-dimensional K$_4$CdCl$_6$…

Strongly Correlated Electrons · Physics 2009-11-07 Asad Niazi , E. V. Sampathkumaran , P. L. Paulose , D. Eckert , A. Handstein , K. -H. Müller