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In many biological materials with a hierarchical structure there is an intriguing and unique mechanism responsible for the 'propagation' of order from the molecular to the nano- or micro-scale level. Here we present a much simpler molecular…

Extended solids that combine unpaired electron spin and structural chirality can host unconventional magnetic behaviors with potential for electronic technologies. A versatile strategy for creating chiral solids is incorporation of chiral…

Chirality refers to the asymmetry of objects that cannot be superimposed on their mirror image. It is a concept that exists in various scientific fields and has profound consequences. Although these are perhaps most widely recognized within…

We unveil the key-role of dimensionality in describing chiroptical properties of molecules embedded inside an optical Fabry-P\'erot cavity. For a 2D-layer configuration, we show that the interplay between molecular chirality and spatial…

Optics · Physics 2024-08-05 R. Avriller , C. Genet

We introduce the concept of purely electronic chirality (PEC), which arises in the absence of structural chirality. In condensed matter physics and chemistry, chirality has conventionally been understood as a mirror-image asymmetry in…

Strongly Correlated Electrons · Physics 2026-02-05 Takayuki Ishitobi , Kazumasa Hattori

Chirality, the property of asymmetry, is of great importance in biological and physical phenomena. This prospective offers an overview of the emerging field of chiral bioinspired plasmonics and metamaterials, aiming to uncover nature's…

A new lattice action is proposed for the overlap Dirac matrix with nonzero chemical potential. It is shown to preserve the full chiral invariance for all values of lattice spacing exactly. It is further demonstrated to arise in the domain…

High Energy Physics - Lattice · Physics 2015-06-11 Rajiv V. Gavai , Sayantan Sharma

Molecular matter-wave interferometry enables novel strategies for manipulating the internal mechanical motion of complex molecules. Here, we show how chiral molecules can be prepared in a quantum superposition of two enantiomers by…

Quantum Physics · Physics 2021-09-22 Benjamin A. Stickler , Mira Diekmann , Robert Berger , Daqing Wang

Exploratory synthesis in novel chemical spaces is the essence of solid-state chemistry. However, uncharted chemical spaces can be difficult to navigate, especially when materials synthesis is challenging. Nitrides represent one such space,…

We investigate one-dimensional periodic chains of alternate type of particles interacting through mirror symmetric potentials. The optimality of the equidistant configuration at fixed density -- also called crystallization -- is shown in…

Optimization and Control · Mathematics 2020-07-13 Laurent Bétermin , Hans Knüpfer , Florian Nolte

Chirality is a universal feature in nature, as observed in fermion interactions and DNA helicity. Much attention has been given to chiral interactions of light, not only regarding its physical interpretation but also focusing on intriguing…

Optics · Physics 2016-09-12 Sunkyu Yu , Hyun Sung Park , Xianji Piao , Bumki Min , Namkyoo Park

Attosecond science is an emerging topic where chirality plays a central role. Here we demonstrate subjecting iodoacetylene, a geometrically achiral molecule, to a pair of simulated non-ionizing ultrafast circularly polarized laser pulses at…

Molecular chirality, a form of stereochemistry most often describing relative spatial arrangements of bonded neighbors around tetrahedral carbon centers, influences the set of 3D conformers accessible to the molecule without changing its 2D…

Machine Learning · Computer Science 2021-10-12 Keir Adams , Lagnajit Pattanaik , Connor W. Coley

We suggest that electromagnetic chirality, generally displayed by 3D or 2D complex chiral structures, can occur in 1D patterned composites whose components are achiral. This feature is highly unexpected in a 1D system which is geometrically…

Optics · Physics 2015-08-05 Carlo Rizza , Andrea Di Falco , Michael Scalora , Alessandro Ciattoni

Progress towards quantum utility in chemistry requires not only algorithmic advances, but also the identification of chemically meaningful problems whose electronic structure fundamentally challenges classical methods. Here, we introduce a…

Chemical Physics · Physics 2026-01-19 Srivathsan Poyyapakkam Sundar , Vibin Abraham , Bo Peng , Ayush Asthana

Chirality in crystals arises from the exclusive presence of proper symmetry operations, such as rotations and screw axes, while lacking improper operations like inversion, mirror planes, and roto-inversions. Crystallographic chirality is…

In simple models side chains are often represented implicitly (e.g., by spin-states) or simplified as one atom. We study side chain effects using square lattice and tetrahedral lattice models, with explicitly side chains of two atoms. We…

Biomolecules · Quantitative Biology 2009-11-10 Jinfeng Zhang , Yu Chen , Rong Chen , Jie Liang

We study numerically the dynamics of acetanilide (ACN) molecules placed on a flat surface of a multilayer hexagonal boron nitride structure. We demonstrate that the ACN molecules, being achiral in three dimensions, become chiral after being…

Mesoscale and Nanoscale Physics · Physics 2023-01-10 Alexander V. Savin , Yuri S. Kivshar

The traditional display of elements in the periodic table is convenient for the study of chemistry and physics. However, the atomic number alone is insufficient for training statistical machine learning models to describe and extract…

Materials Science · Physics 2023-08-25 Anthony Onwuli , Ashish V. Hegde , Kevin Nguyen , Keith T. Butler , Aron Walsh

In equilibrium liquid crystals, chirality leads to a variety of spectacular three-dimensional structures, but chiral and achiral phases with the same broken continuous symmetries have identical long-time, large-scale dynamics. In this…

Soft Condensed Matter · Physics 2021-06-23 S. J. Kole , Gareth P. Alexander , Sriram Ramaswamy , Ananyo Maitra