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The traditional Mpemba effect refers to an anomalous cooling phenomenon when an initial hotter system cools down faster than an initial warm system. Such counterintuitive behavior has been confirmed and explored across phase transitions in…

Soft Condensed Matter · Physics 2026-02-05 Alexander P. Antonov , Hartmut Löwen

The Mpemba effect refers to systems whose thermal relaxation time is a non-monotonic function of the initial temperature. Thus, a system that is initially hot cools to a bath temperature more quickly than the same system, initially warm. In…

Statistical Mechanics · Physics 2021-03-31 Raphaël Chétrite , Avinash Kumar , John Bechhoefer

A system initially far from equilibrium is expected to take more time to reach equilibrium than a system that was initially closer to equilibrium. The old puzzling observation (also called Mpemba effect) that when a sample of hot water and…

Statistical Mechanics · Physics 2010-11-18 P. Chaddah , S. Dash , Kranti Kumar , A. Banerjee

The name "Mpemba effect" was given to the finding that "If two systems are cooled, the water that starts hotter may freeze first", confirmed by numerous of observations. Now this paradoxical state-ment obtained a more general form "the…

Chemical Physics · Physics 2025-03-31 Alexei V. Finkelstein

The behavior of systems far from equilibrium is often complex and unpredictable, challenging and sometimes overturning the physical intuition derived from equilibrium scenarios. One striking example of this is the Mpemba effect, which…

Quantum Physics · Physics 2025-04-02 Stefano Longhi

In a recent paper in Scientific Reports, Burridge \& Linden misinterpret the Mpemba effect as a statement about the rate of cooling of liquid water, when it is in fact a statement about the rate of freezing of water. Debunking an obviously…

Popular Physics · Physics 2017-01-30 J. I. Katz

The Mpemba effect (a counterintuitive thermal relaxation process where an initially hotter system may cool down to the steady state sooner than an initially colder system) is studied in terms of a model of inertial suspensions under shear.…

Statistical Mechanics · Physics 2021-03-10 Satoshi Takada , Hisao Hayakawa , Andrés Santos

In the 1960s, Tanzanian student Erasto Mpemba and his teacher published an article with the title "Cool" in the journal Physics Education (Mpemba, E. B. - Osborne, D. G.: Cool?. In: Physics Education, vol.4, 1969, pp. 172-175.). In this…

Physics Education · Physics 2015-06-05 Marek Balazovic , Boris Tomasik

I suggest that the origin of the Mpemba effect (the freezing of hot water before cold) is freezing-point depression by solutes, either gaseous or solid, whose solubility decreases with increasing temperature so that they are removed when…

Chemical Physics · Physics 2017-01-30 J. I. Katz

An accurate experimental investigation on the Mpemba effect (that is, the freezing of initially hot water before cold one) is carried out, showing that in the adiabatic cooling of water a relevant role is played by supercooling as well as…

Chemical Physics · Physics 2009-11-13 S. Esposito , R. De Risi , L. Somma

We report anomalous heating in a colloidal system, the first observation of the inverse Mpemba effect, where an initially cold system heats up faster than an identical warm system coupled to the same thermal bath. For an overdamped,…

Statistical Mechanics · Physics 2022-01-28 Avinash Kumar , Raphael Chetrite , John Bechhoefer

Despite extensive research, the fundamental physical mechanisms underlying the Mpemba effect, a phenomenon where a substance cools faster after initially being heated, remain elusive. Although historically linked with water, the Mpemba…

Soft Condensed Matter · Physics 2024-04-26 Andrés Santos

The Mpemba effect was originally referred to as the faster icing of a higher-temperature system than a lower-temperature system, and was later generalized to anomalous decays of both classical and quantum observables to equilibrium states.…

Quantum Physics · Physics 2024-10-15 Xuanhua Wang , Jin Wang

The Mpemba effect denotes an anomalous relaxation phenomenon where a system initially at a hot temperature cools faster than a system that starts at a less elevated temperature. We introduce an isothermal analog of this effect for a system…

Statistical Mechanics · Physics 2022-09-02 Julius Degünther , Udo Seifert

The counterintuitive Mpemba effect, wherein a hotter system cools faster, critically lacks a general macroscopic theory. Here, starting from linear irreversible thermodynamics, we formulate a generalized Newton's cooling law,…

Statistical Mechanics · Physics 2026-05-21 Yun-Qian Lin , Z. C. Tu , Yu-Han Ma

The quicker freezing of hotter water, than a colder sample, when quenched to a common lower temperature, is referred to as the Mpemba effect (ME). While this counter-intuitive fact remains a surprize since long, efforts have begun to…

Statistical Mechanics · Physics 2023-09-08 Sohini Chatterjee , Soumik Ghosh , Nalina Vadakkayil , Tanay Paul , Sanat K. Singha , Subir K. Das

The Mpemba effect -- where hot systems cool faster than colder ones -- has intrigued both classical and quantum thermodynamics. As compared to classical systems, quantum systems add complexity due to quantum correlations. Recent works have…

Quantum Physics · Physics 2025-12-01 Stefano Longhi

The inverse Mpemba effect is a counterintuitive phenomenon in which a system, initially in thermal equilibrium and prepared at different temperatures below that of the final equilibrium state, relaxes to the final state more rapidly when…

Statistical Mechanics · Physics 2025-07-08 Koudai Sugimoto , Tomotaka Kuwahara , Keiji Saito

The Mpemba effect has initially been noticed in macroscopic systems -- namely that hot water can freeze faster than cold water -- but recently its extension to open quantum systems has attracted significant attention. This phenomenon can be…

Mesoscale and Nanoscale Physics · Physics 2025-04-08 Juliane Graf , Janine Splettstoesser , Juliette Monsel

In classical thermodynamics, the Mpemba effect refers to the counterintuitive observation that hot water can freeze faster than cold water, manifesting as an anomalous crossing of dynamical trajectories. While analogues of this phenomenon…

Quantum Physics · Physics 2026-05-25 Zhilong Liu , Zehua Tian , Jieci Wang