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The metastable nature of the ferroelectric phase of HfO$_2$ is a significant impediment to its industrial application as a functional ferroelectric material. In fact, no polar phases exist in the bulk phase diagram of HfO$_2$, which shows a…

Materials Science · Physics 2024-01-11 Binayak Mukherjee , Natalya S. Fedorova , Jorge Íñiguez-González

The geometrically frustrated magnet Ni3V2O8 undergoes a series of competing magnetic ordering at low temperatures. Most importantly, one of the incommensurate phases has been reported to develop a ferroelectric correlation caused by spin…

Materials Science · Physics 2009-06-26 A. K. Singh , D. Jain , V. Ganesan , A. K. Nigam , S. Patnaik

We investigate spin dynamics in $\alpha$-Fe$_{2}$O$_{3}$/Ni$_{80}$Fe$_{20}$ (Py) heterostructures, uncovering a robust mechanism for in-situ modulation of ferromagnetic resonance (FMR) through precise control of temperature, applied…

Ferroelectricity, especially in hafnia-based thin films at nanosizes, has been rejuvenated in the fields of low-power, nonvolatile and Si-compatible modern memory and logic applications. Despite tremendous efforts to explore the formation…

BiFeO3 is a model multiferroic in which the ferroelectric polarization is coupled to ferroelastic lattice distortions, yet deterministic control of its domain structure remains limited by high switching fields and competing polarization…

Abundant chemical diversity and structural tunability make organic-inorganic hybrid perovskites (OIHPs) a rich ore for ferroelectrics. However, compared with their inorganic counterparts such as BaTiO$_3$, their ferroelectric key…

Materials Science · Physics 2023-05-22 Kun Ding , Haoshen Ye , Changyuan Su , Yu-An Xiong , Guowei Du , Yu-Meng You , Zhi-Xu Zhang , Shuai Dong , Yi Zhang , Da-Wei Fu

Ferroic materials (ferromagnetic, ferroelectric, ferroelastic) usually divide into domains with different orientations of their order parameter. Coupling different ferroic systems creates new functionalities, for instance the electrical…

Transition metal oxides hold great potential for the development of new device paradigms because of the field-tunable functionalities driven by their strong electronic correlations, combined with their earth abundance and environmental…

Multiferroics, where two or more ferroic order parameters coexist, is one of the hottest fields in condensed matter physics and materials science[1-9]. However, the coexistence of magnetism and conventional ferroelectricity is physically…

Materials Science · Physics 2016-03-11 Xiangang Wan , Hang-Chen Ding , Sergey Y. Savrasov , Chun-Gang Duan

In this work, the results of first-principles density-functional-theory calculations are used to construct the energy landscapes of HfO$_2$ and its Y and Zr substituted derivatives as a function of symmetry-adapted lattice-mode amplitudes.…

Materials Science · Physics 2021-01-04 Yubo Qi , Karin M. Rabe

HfO$_{2}$-based ferroelectric thin films are promising for their application in ferroelectric devices. Predicting the ultimate magnitude of polarization and understanding its switching mechanism are critical to realize the optimal…

Materials Science · Physics 2023-04-04 Yao Wu , Yuke Zhang , Jie Jiang , Limei Jiang , Minghua Tang , Yichun Zhou , Min Liao , Qiong Yang , Evgeny Y. Tsymbal

In this work, we report on the thermomagnetic characterization and crystalline-electric field (CEF) energy scheme of the disordered defect-fluorite Ho2Zr2O7. This structural phase is distinguished by the coexistence of magnetic frustration…

From an experimental point of view, room temperature ferroelectricity in BiFeO3 is raising many questions. Electric measurements made a long time ago on solid-solutions of BiFeO3 with Pb(Ti,Zr)O3 indicate that a spontaneous electric…

Domain engineering in ferroelectric thin films is crucial for next-generation microelectronic and photonic technologies. Here, a method is demonstrated to precisely control domain configurations in BaTiO$_3$ thin films through low-energy He…

Controlling magnetism by using electric fields is a goal of research towards novel spintronic devices and future nano-electronics. For this reason, multiferroic heterostructures attract much interest. Here we provide experimental evidence,…

Semiconducting ferroelectric materials with low energy polarisation switching offer a platform for next-generation electronics such as ferroelectric field-effect transistors. Ferroelectric domains at symmetry-broken interfaces of transition…

Mesoscale and Nanoscale Physics · Physics 2022-10-07 Laurent Molino , Leena Aggarwal , Vladimir Enaldiev , Ryan Plumadore , Vladimir Falko , Adina Luican-Mayer

There is great interest in hybrid organic-inorganic materials such as metal-organic frameworks (MOFs). The compounds [C(NH$_{2}$)$_{3}$]M(HCOO)$_{3}$, where M=Cu$^{2+}$ or Cr$^{2+}$ are Jahn-Teller (JT) active ions, are MOF with perovskite…

Materials Science · Physics 2014-03-27 Alessandro Stroppa , Paolo Barone , Prashant Jain , Jean Manuel Perez-Mato , Silvia Picozzi

Numerous authors have referred to room-temperature magnetic switching of large electric polarizations as The Holy Grail of magnetoelectricity.We report this long-sought effect using a new physical process of coupling between magnetic and…

Materials Science · Physics 2009-02-24 Ashok Kumar , G. L. Sharma , R. S. Katiyar R. Pirc , R. Blinc J. F. Scott

The discovery of interfacial ferroelectricity in two-dimensional rhombohedral (3R)-stacked semiconductors opens up a new pathway for achieving ultrathin computing-in-memory devices. However, exploring ferroelectricity switching in natural…

The intended use of a magnetic material, from information storage to power conversion, depends crucially on its domain structure, traditionally crafted during materials synthesis. By contrast, we show that an external magnetic field applied…

Materials Science · Physics 2016-09-08 D. M. Silevitch , G. Aeppli , T. F. Rosenbaum