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Machine learning algorithms use error function minimization to fit a large set of parameters in a preexisting model. However, error minimization eventually leads to a memorization of the training dataset, losing the ability to generalize to…

Machine Learning · Computer Science 2018-03-16 Fernando Martin-Maroto , Gonzalo G. de Polavieja

Traditional solution approaches for problems in quantum mechanics scale as $\mathcal O(M^3)$, where $M$ is the number of electrons. Various methods have been proposed to address this issue and obtain linear scaling $\mathcal O(M)$. One…

Mathematical Software · Computer Science 2019-07-03 Denis Davydov , Martin Kronbichler

We propose a refined scheme of deriving an effective low-energy Hamiltonian for materials with strong electronic Coulomb correlations beyond density functional theory (DFT). By tracing out the electronic states away from the target degrees…

Strongly Correlated Electrons · Physics 2017-08-09 Motoaki Hirayama , Takashi Miyake , Masatoshi Imada , Silke Biermann

A formalism for electronic-structure calculations is presented that is based on the functional renormalization group (FRG). The traditional FRG has been formulated for systems that exhibit a translational symmetry with an associated Fermi…

Materials Science · Physics 2016-10-12 Christian Seiler , Ferdinand Evers

A fully analytical approximation for the observable characteristics of many-electron atoms is developed via a complete and orthonormal hydrogen-like basis with a single-effective charge parameter for all electrons of a given atom. The basis…

Quantum Physics · Physics 2017-12-06 O. D. Skoromnik , I. D. Feranchuk , A. U. Leonau , C. H. Keitel

One-dimensional particle states are constructed according to orthogonality conditions, without requiring boundary conditions. Free particle states are constructed using Dirac's delta function orthogonality conditions. The states (doublets)…

Quantum Physics · Physics 2007-05-23 A. Gersten

We present the Electronic Tensor Reconstruction Algorithm (ELECTRA) - an equivariant model for predicting electronic charge densities using floating orbitals. Floating orbitals are a long-standing concept in the quantum chemistry community…

Machine Learning · Computer Science 2026-01-27 Jonas Elsborg , Luca Thiede , Alán Aspuru-Guzik , Tejs Vegge , Arghya Bhowmik

Electron ptychography provides new opportunities to resolve atomic structures with deep sub-angstrom spatial resolution and studying electron-beam sensitive materials with high dose efficiency. In practice, obtaining accurate ptychography…

Materials Science · Physics 2022-04-26 Michael C. Cao , Zhen Chen , Yi Jiang , Yimo Han

Sparse polynomial approximation has become indispensable for approximating smooth, high- or infinite-dimensional functions from limited samples. This is a key task in computational science and engineering, e.g., surrogate modelling in…

Numerical Analysis · Mathematics 2023-11-08 Ben Adcock , Simone Brugiapaglia , Nick Dexter , Sebastian Moraga

The purpose of this paper is (i) to present a generic and fully functional implementation of the density-matrix renormalization group (DMRG) algorithm, and (ii) to describe how to write additional strongly-correlated electron models and…

Strongly Correlated Electrons · Physics 2015-05-13 G. Alvarez

Optimal power flow (OPF) is an important problem for power generation and it is in general non-convex. With the employment of renewable energy, it will be desirable if OPF can be solved very efficiently so its solution can be used in real…

Optimization and Control · Mathematics 2011-09-27 Albert Y. S. Lam , Baosen Zhang , David Tse

In this chapter, we discuss recent advances and new opportunities through methods of machine learning for the field of classical density functional theory, dealing with the equilibrium properties of thermal nano- and micro-particle systems…

Statistical Mechanics · Physics 2024-06-12 Alessandro Simon , Martin Oettel

Asymmetric processors have emerged as an appealing technology for severely energy-constrained environments, especially in the mobile market where heterogeneity in applications is mainstream. In addition, given the growing interest on ultra…

Distributed, Parallel, and Cluster Computing · Computer Science 2015-07-21 Sandra Catalán , Francisco D. Igual , Rafael Mayo , Luis Piñuel , Enrique S. Quintana-Ortí , Rafael Rodríguez-Sánchez

This paper presents a novel mass-conservative mixed multiscale method for solving flow equations in heterogeneous porous media. The media properties (the permeability) contain multiple scales and high contrast. The proposed method solves…

Numerical Analysis · Mathematics 2019-04-01 Eric Chung , Yalchin Efendiev , Wing Tat Leung

We present a method for electronic structure calculations that retains all of the advantages of real space and addresses the inherent inefficiency of a regular grid, which has equal precision everywhere. The computations are carried out on…

Condensed Matter · Physics 2009-10-28 Gil Zumbach , N. A. Modine , Efthimios Kaxiras

This paper derives and demonstrates a new, purely density-based ab initio approach for calculation of the energies and properties of many-electron systems. It is based upon the discovery of relationships that govern the "mechanics" of the…

Chemical Physics · Physics 2024-09-04 James C. Ellenbogen

Variational quantum eigensolver ans\"atze hold considerable promise for ground-state energy calculations on near-term quantum hardware, yet most promising ansatz designs currently strongly depend on how well the molecular orbital basis…

Hybrid density functional approximations (DFAs) offer compelling accuracy for ab initio electronic-structure simulations of molecules, nanosystems, and bulk materials, addressing some deficiencies of computationally cheaper, frequently used…

Orthogonality constrained optimization is widely used in applications from science and engineering. Due to the nonconvex orthogonality constraints, many numerical algorithms often can hardly achieve the global optimality. We aim at…

Optimization and Control · Mathematics 2019-06-18 Honglin Yuan , Xiaoyi Gu , Rongjie Lai , Zaiwen Wen

We propose a machine learning framework to accelerate numerical computations of time-dependent ODEs and PDEs. Our method is based on recasting (generalizations of) existing numerical methods as artificial neural networks, with a set of…

Numerical Analysis · Mathematics 2019-03-08 Siddhartha Mishra
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