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After our first discovery of superconductivity (SC) with $T_C$=3.7 K in TlNi$_2$Se$_2$, we grew successfully a series of TlNi$_2$Se$_{2-x}$S$_x$ (0.0 $\leq$ x $\leq$2.0) single crystals. The measurements of resistivity, susceptibility and…

Superconductivity · Physics 2015-09-22 Hangdong Wang , Chiheng Dong , Qianhui Mao , Rajwali Khan , Xi Zhou , Chenxia Li , Bin Chen , Jinhu Yang , Minghu Fang

We successfully synthesized two new compounds Rb$_x$Fe$_{2-y}$S$_2$ and Cs$_x$Fe$_{2-y}$S$_2$ which were isostructural with K$_x$Fe$_{2-y}$Se$_2$ superconductor. We systematically investigated the resistivity, magnetism and thermoelectric…

Strongly Correlated Electrons · Physics 2012-02-21 J. J. Ying , Z. J. Xiang , Z. Y. Li , Y. J. Yan , M. Zhang , A. F. Wang , X. G. Luo , X. H. Chen

We report the synthesis and characterization of RbNi$_2$Se$_2$, an analog of the iron chalcogenide superconductor Rb$_x$Fe$_2$Se$_2$, via transport, angle resolved photoemission spectroscopy, and density functional theory calculations. A…

The diverse electronic properties of transition metal chalcogenides can be very sensitive to crystal imperfections. A new crystal growth technique, known as horizontal flux transport, offers a route to improved crystal quality. By refining…

Two single crystalline samples with the same nominal composition of Rb0.8Fe2Se2 prepared via slightly different precursor routes under the same thermal processing conditions were investigated at ambient and high pressures. One sample was…

Superconductivity · Physics 2012-07-18 M. Gooch , B. Lv , L. Z. Deng , T. Muramatsu , J. Meen , Y. Y. Xue , B. Lorenz , C. W. Chu

Single crystals of K$_x$Fe$_{2-y}$Se$_2$ are prepared by quenching at various temperatures. The crystals obtained at higher quenching temperatures have a surface morphology with mesh-like texture. They show a sharp superconducting…

The BiS2-based superconductors were discovered recently. The superconductivity has been proved by many other groups. Since the previous experiments were all done on polycrystalline samples, therefore there remains a concern whether the…

Superconductivity · Physics 2014-08-22 Jianzhong Liu , Delong Fang , Zhenyu Wang , Jie Xing , Zengyi Du , Xiyu Zhu , Huan Yang , Hai-Hu Wen

Using the self-flux technique we grew superconducting $(K_{1-z}Na_z)_{x}Fe_{2-y}Se_2$ (z = 0.3) single crystals. The EDX mapping revealed the uniform elements distribution on the crystal surface while the XRD measurements indicate that the…

Single crystals of Tl0.58Rb0.42Fe1.72Se2 are successfully grown with the superconducting transition temperatures Tconset=32K and Tczero=31.4K. The Hall coefficient exhibits a multi-band behavior, which is very similar to that of all other…

Superconductivity · Physics 2011-02-21 Hangdong Wang , Chihen Dong , Zujuan Li , Shasha Zhu , Qianhui Mao , Chunmu Feng , H. Q. Yuan , Minghu Fang

We report the evolution of superconductivity and the phase diagram of the KxFe2-ySe2-zTez (z=0-0.6) crystals grown by a simple one-step synthesis. No structural transition is observed in any crystals, while lattice parameters exhibit a…

We measured the microwave surface impedances and obtained the superfluid density and flux flow resistivity in single crystals of a phosphor-doped iron-based superconductor SrFe$_2$(As$_{1-x}$P$_{x}$)$_2$ single crystals ($x=0.30$, $T_c=25…

High-quality and sizable single crystals are crucial for studying the intrinsic properties of unconventional superconductors, which are lacking in the 1111 phase of the Fe-based superconductors. Here we report the successful growth of…

Superconductivity · Physics 2015-07-03 Yonghui Ma , Hui Zhang , Bo Gao , Kangkang Hu , Qiucheng Ji , Gang Mu , Fuqiang Huang , Xiaoming Xie

We report the synthesis and basic physical properties of single crystals of CaFe2As2, an isostructural compound to BaFe2As2 which has been recently doped to produce superconductivity. CaFe2As2 crystalizes in the ThCr2Si2 structure with…

Strongly Correlated Electrons · Physics 2008-07-10 F. Ronning , T. Klimczuk , E. D. Bauer , H. Volz , J. D. Thompson

We investigated the superconducting and transport properties in FeTe$_{1-x}$Se$_{x}$ (0.1 $\leq$ $x$ $\leq$ 0.4) single crystals prepared by O$_2$-annealing. Sharp superconducting transition width observed in magnetization measurement and…

Superconductivity · Physics 2015-02-17 Yue Sun , Toshihiro Taen , Tatsuhiro Yamada , Yuji Tsuchiya , Sunseng Pyon , Tsuyoshi Tamegai

The Fe-based superconducting KxFe2-ySe2 (0.6 {\leg} x {\leg} 1, 0.2{\leg} y {\leg} 0.4) compounds, unlike the well-known RFe2As2 (R = Ba, Sr, Ca) superconductors, contain complex structural features and notable physical properties, such as…

Superconductivity · Physics 2011-04-29 J. Q. Li , Y. J. Song , H. X. Yang , Z. Wang , H. L. Shi , G. F. Chen , Z. W. Wang , Z. Chen , H. F. Tian

Despite intense experimental efforts, the nature of the unconventional superconducting order parameter of UTe$_2$ remains elusive. This puzzle stems from different reported numbers of superconducting transitions at ambient pressure, as well…

We report a low-temperature specific heat study of high-quality single crystals of the heavily hole doped superconductor Ca$_{0.32}$Na$_{0.68}$Fe$_2$As$_2$. This compound exhibits bulk superconductivity with a transition temperature $T_c…

Single crystals of the compound LaFePO were prepared using a flux growth technique at high temperatures. Electrical resistivity measurements reveal metallic behavior and a resistive transition to the superconducting state at a critical…

Superconductivity · Physics 2008-09-10 J. J. Hamlin , R. E. Baumbach , D. A. Zocco , T. A. Sayles , M. B. Maple

Single crystals of A$_{1-x}$K$_x$Fe$_2$As$_2$ (A=Ba, Sr) with high quality have been grown successfully by FeAs self-flux method. The samples have sizes up to 4 mm with flat and shiny surfaces. The X-ray diffraction patterns suggest that…

Superconductivity · Physics 2009-11-13 Huiqian Luo , Zhaosheng Wang , Huan Yang , Peng Cheng , Xiyu Zhu , Hai-Hu Wen

We report on structural, magnetic, conductivity, and thermodynamic studies of FeSe$_{0.5}$Te$_{0.5}$ single crystals grown by self-flux and Bridgman methods. The samples were prepared from starting materials of different purity at various…

Superconductivity · Physics 2011-03-25 V. Tsurkan , J. Deisenhofer , A. Günther , Ch. Kant , H. -A. Krug von Nidda , F. Schrettle , A. Loidl