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Massive steam and CO$_2$ atmospheres have been proposed for magma ocean outgassing of Earth and terrestrial planets. Yet formation of such atmospheres depends on volatile exchange with the molten interior, governed by volatile solubilities…

A recent study by Ramirez et al. (2014) demonstrated that an atmosphere with 1.3-4 bar of CO2 and H2O, in addition to 5-20% H2, could have raised the mean annual and global surface temperature of early Mars above the freezing point of…

Here we investigate how small amounts of hydrogen (much smaller than the mass of the exoplanet) above a magma ocean on a rocky exoplanet may modify the atmospheric chemistry and atmospheric escape.We use a chemical model of a magma ocean…

This work presents theoretical studies which combine aspects of combustion and explosion theory with exoplanetary atmospheric science. Super Earths could possess a large amount of molecular hydrogen depending on disk, planetary and stellar…

The atmospheres of small exoplanets likely derive from a combination of geochemical outgassing and primordial gases left over from formation. Secondary atmospheres, such as those of Earth, Mars and Venus, are sourced by outgassing.…

The Moon-forming giant impact extensively melts and partially vaporizes the silicate Earth and delivers a substantial mass of metal to Earth's core. Subsequent evolution of the magma ocean and overlying atmosphere has been described by…

The next step on the path toward another Earth is to find atmospheres similar to those of Earth and Venus - high-molecular-weight (secondary) atmospheres - on rocky exoplanets. Many rocky exoplanets are born with thick (> 10 kbar)…

The deuterium-to-hydrogen (D/H or 2H/1H) ratio of Martian atmospheric water (~6x standard mean ocean water, SMOW) is higher than that of known sources, requiring planetary enrichment. A recent measurement by NASA's Mars Science Laboratory…

Earth's water, intrinsic oxidation state, and metal core density are fundamental chemical features of our planet. Studies of exoplanets provide a useful context for elucidating the source of these chemical traits. Planet formation and…

The classical habitable zone is the circular region around a star in which liquid water could exist on the surface of a rocky planet. The outer edge of the traditional N2-CO2-H2O habitable zone (HZ) extends out to nearly 1.7 AU in our Solar…

A magma ocean (MO) is thought to be a ubiquitous stage in the early evolution of rocky planets and exoplanets. During the lifetime of the MO, exchanges between the interior and exterior envelopes of the planet are very efficient. In…

Habitable rocky planets around M dwarfs that have H2-dominated atmospheres, if they exist, would permit characterizing habitable exoplanets with detailed spectroscopy using JWST, owing to their extended atmospheres and small stars. However,…

The existence of liquid water within an oxidized environment on early Mars has been inferred by the Mn-rich rocks found during recent explorations on Mars. The oxidized atmosphere implied by the Mn-rich rocks would basically be comprised of…

We show that collision-induced absorption allows molecular hydrogen to act as an incondensible greenhouse gas, and that bars or tens of bars of primordial H2-He mixtures can maintain surface temperatures above the freezing point of water…

Volatile molecules containing hydrogen, carbon, and nitrogen are key components of planetary atmospheres. In the pebble accretion model for rocky planet formation, these volatile species are accreted during the main planetary formation…

The evidence for abundant liquid water on early Mars despite the faint young Sun is a long-standing problem in planetary research. Here we present new ab initio spectroscopic and line-by-line climate calculations of the warming potential of…

Rocky planet atmospheres form and evolve through interactions between the planet's surface and interior. If a growing rocky planet acquires enough mass prior to the dissipation of the nebular gas disk, it can gravitationally capture a…

Young terrestrial planets can capture or outgas hydrogen-rich atmospheres with tens to hundreds of bars of H2, which persist for 100 Myrs or longer. Although the earliest habitable conditions on Earth and terrestrial exoplanets could thus…

H$_2$-dominated terrestrial exoplanets are highly accessible to atmospheric characterization via transmission spectroscopy, but such atmospheres are generally thought to be unstable to escape. Here, we propose that close-in, eccentric…

The presence of valleys on ancient terrains of Mars suggest that liquid water flowed on the martian surface 3.8 billion years ago or before. The above-freezing temperatures required to explain valley formation could have been transient, in…