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Solving the electronic Schrodinger equation for strongly correlated ground states is a long-standing challenge. We present quantum algorithms for the variational optimization of wavefunctions correlated by products of unitary operators,…

Quantum Physics · Physics 2024-08-06 Mario Motta , Kevin J. Sung , James Shee

The most efficient known quantum circuits for preparing unitary coupled cluster states and applying Trotter steps of the arbitrary basis electronic structure Hamiltonian involve interleaved sequences of fermionic Gaussian circuits and Ising…

Quantum Physics · Physics 2021-09-13 Nicholas C. Rubin , Joonho Lee , Ryan Babbush

The vast use of computers on scientific numerical computation makes the awareness of the limited precision that these machines are able to provide us an essential matter. A limited and insufficient precision allied to the truncation and…

Numerical Analysis · Computer Science 2009-11-13 B. O. Rodrigues , L. A. C. P. da Mota , L. G. S. Duarte

In this paper, we propose a parallel optimization method for electronic structure calculations based on a single orbital-updating approximation. It is shown by our numerical experiments that the method is efficient and reliable for atomic…

Numerical Analysis · Mathematics 2015-11-20 Xiaoying Dai , Zhuang Liu , Xin Zhang , Aihui Zhou

Experiments in coherent nuclear and electron magnetic resonance,and quantum computing in general correspond to control of quantum mechanical systems, guiding them from initial to final target states by unitary transformations. The control…

Quantum Physics · Physics 2015-06-17 Haidong Yuan , Daxiu Wei , Yajuan Zhang , Steffen Glaser , Navin Khaneja

Simulating the dynamics of many-body quantum systems is believed to be one of the first fields that quantum computers can show a quantum advantage over classical computers. Noisy intermediate-scale quantum (NISQ) algorithms aim at…

Quantum Physics · Physics 2021-05-19 Jonathan Wei Zhong Lau , Tobias Haug , Leong Chuan Kwek , Kishor Bharti

Total least squares (TLS) methods have been widely used in data fitting. Compared with the least squares method, for TLS problem we takes into account not only the observation errors, but also the errors in the measurement matrix. This is…

Numerical Analysis · Mathematics 2022-05-03 Qian Zuo , Yimin Wei , Hua Xiang

Gauge theories establish the standard model of particle physics, and lattice gauge theory (LGT) calculations employing Markov Chain Monte Carlo (MCMC) methods have been pivotal in our understanding of fundamental interactions. The present…

The past years have witnessed impressive advances in electronic structure calculation, especially in the complexity and size of the systems studied, as well as in computation time. Linear scaling methods based on empirical tight-binding…

Materials Science · Physics 2007-05-23 Abduxukur Abdurixit , Alexis Baratoff , Giulia Galli

The factorized form of the unitary coupled cluster ansatz is a popular state preparation ansatz for electronic structure calculations of molecules on quantum computers. It often is viewed as an approximation (based on the Trotter product…

Chemical Physics · Physics 2022-02-16 Jia Chen , Hai-Ping Cheng , J. K. Freericks

Hamiltonian simulation, i.e., simulating the real time evolution of a target quantum system, is a natural application of quantum computing. Trotter-Suzuki splitting methods can generate corresponding quantum circuits; however, a faithful…

Quantum Physics · Physics 2024-03-21 Ayse Kotil , Rahul Banerjee , Qunsheng Huang , Christian B. Mendl

Measurements on near-term quantum processors are inevitably subject to hardware imperfections that lead to readout errors. Mitigation of such unavoidable errors is crucial to better explore and extend the power of near-term quantum…

Quantum Physics · Physics 2023-09-19 Kun Wang , Yu-Ao Chen , Xin Wang

We present a balanced truncation model reduction approach for a class of nonlinear systems with time-varying and uncertain inputs. First, our approach brings the nonlinear system into quadratic-bilinear~(QB) form via a process called…

Numerical Analysis · Mathematics 2020-10-29 Boris Kramer , Karen E. Willcox

In this paper, we present a theoretical analysis of the model reduction algorithm for linear switched systems. This algorithm is a reminiscence of the balanced truncation method for linear parameter varying systems. Specifically in this…

Optimization and Control · Mathematics 2013-03-19 Mihaly Petreczky , Rafael Wisniewski , John Leth

Effective field theories (EFTs) organize the description of complex systems into an infinite sequence of decreasing importance. Predictions are made with a finite number of terms, which induces a truncation error that is often left…

Nuclear Theory · Physics 2019-10-16 J. A. Melendez , R. J. Furnstahl , D. R. Phillips , M. T. Pratola , S. Wesolowski

Product formulas can be used to simulate Hamiltonian dynamics on a quantum computer by approximating the exponential of a sum of operators by a product of exponentials of the individual summands. This approach is both straightforward and…

Quantum Physics · Physics 2019-09-04 Andrew M. Childs , Aaron Ostrander , Yuan Su

Quantum algorithms typically demand prohibitively complicated circuits to solve practical problems. Previous studies have shown that classical randomness can accelerate some specific quantum algorithms. In this work, we introduce the…

Quantum Physics · Physics 2026-01-15 Yue Wang , Qi Zhao

Electronic structure calculations of molecular systems are among the most promising applications for fault-tolerant quantum computing (FTQC) in quantum chemistry and drug design. However, while recent algorithmic advancements such as…

Simulating quantum systems is one of the most promising avenues to harness the computational power of quantum computers. However, hardware errors in noisy near-term devices remain a major obstacle for applications. Ideas based on the…

Quantum Physics · Physics 2023-07-26 W. Gong , Yaroslav Kharkov , Minh C. Tran , Przemyslaw Bienias , Alexey V. Gorshkov

An approximate relativistic two-component Hamiltonian for use in molecular electronic structure calculations is derived in the form of a sum of fixed atom-centered kinetic and spin-orbit operators added to the non-relativistic Hamiltonian.…

Chemical Physics · Physics 2019-02-13 Dimitri N. Laikov
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