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The potential energy surface (PES) of interlayer interaction of infinite twisted bilayer graphene is calculated for a set of commensurate moir\'e patterns using the registry-dependent Kolmogorov-Crespi empirical potential. The calculated…

Mesoscale and Nanoscale Physics · Physics 2023-08-15 Alexander S. Minkin , Irina V. Lebedeva , Andrey M. Popov , Sergey A. Vyrko , Nikolai A. Poklonski , Yurii E. Lozovik

The potential energy surface (PES) of interlayer interaction of twisted bilayer graphene with vacancies in one of the layers is investigated via density functional theory (DFT) calculations with van der Waals corrections. These calculations…

Mesoscale and Nanoscale Physics · Physics 2021-10-01 Alexander S. Minkin , Irina V. Lebedeva , Andrey M. Popov , Andrey A. Knizhnik

We present a first principles-quality potential energy surface (PES) describing the inter-atomic forces for hydrogen atoms interacting with free-standing graphene. The PES is a high-dimensional neural network potential that has been…

Twisted graphene layers exhibit extremely low friction for relative sliding. Nevertheless, previous studies suggest that the area contribution to friction for commensurate moir\'e systems is finite and might restrict macroscopic…

Mesoscale and Nanoscale Physics · Physics 2025-11-04 Irina V. Lebedeva , Andrey M. Popov , Yulia G. Polynskaya , Andrey A. Knizhnik , Sergey A. Vyrko , Nikolai A. Poklonski

Principal characteristics of interlayer interaction and relative motion of hexagonal boron nitride (h-BN) layers are investigated by the first-principles method taking into account van der Waals interactions. Dependences of the interlayer…

Mesoscale and Nanoscale Physics · Physics 2016-04-13 Alexander V. Lebedev , Irina V. Lebedeva , Andrey A. Knizhnik , Andrey M. Popov

A detailed characterization of the interaction between the most abundant molecules in air is important for the understanding of a variety of phenomena in atmospherical science. A completely {\em ab initio} global potential energy surface…

Mixed-dimensional heterostructures composed of two-dimensional (2D) and three-dimensional (3D) materials are undisputed next-generation materials for engineered devices due to their changeable properties. The present work computationally…

Materials Science · Physics 2023-07-14 Vidushi Sharma , Dibakar Datta

Both van der Waals corrected density functional theory and classical calculations show that the potential relief of interaction energy between layers of graphite and few-layer graphene can be described by a simple expression containing only…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Andrey M. Popov , Irina V. Lebedeva , Andrey A. Knizhnik , Yurii E. Lozovik , Boris V. Potapkin

The effect of structure relaxation on the potential energy surface (PES) of interlayer interaction of twisted graphene bilayer is studied for a set of commensurate moir\'e systems using the registry-dependent empirical potential of…

Mesoscale and Nanoscale Physics · Physics 2025-02-20 Alexander S. Minkin , Irina V. Lebedeva , Andrey M. Popov , Sergey A. Vyrko , Nikolai A. Poklonski , Yurii E. Lozovik

The interlayer interaction in graphene/boron-nitride heterostructures is studied using density functional theory calculations with the correction for van der Waals interactions. It is shown that the use of the experimental interlayer…

Mesoscale and Nanoscale Physics · Physics 2017-08-30 Alexander V. Lebedev , Irina V. Lebedeva , Andrey M. Popov , Andrey A. Knizhnik

We present an isotropic ab initio (para-H$_2$)$_4$ four-body interaction potential energy surface (PES). The electronic structure calculations are performed at the correlated coupled-cluster theory level, with single, double, and…

Chemical Physics · Physics 2025-06-09 Alexander Ibrahim , Pierre-Nicholas Roy

A new nine-dimensional potential energy surface (PES) for methane has been generated using state-of-the-art \textit{ab initio} theory. The PES is based on explicitly correlated coupled cluster calculations with extrapolation to the complete…

Chemical Physics · Physics 2016-10-12 Alec Owens , Sergey N. Yurchenko , Andrey Yachmenev , Jonathan Tennyson , Walter Thiel

For the prototypical diatomic-molecule - diatomic molecule interactions H2-HX and H2-X2, where X = F, Cl, Br, quantum-chemical ab initio calculations are carried out on grids of the configuration space, which permit a spherical-harmonics…

The potential energy surface (PES) of dissociative adsorption of H_2 on Pd(100) is investigated using density functional theory and the full-potential linear augmented plane wave (FP-LAPW) method. Several dissociation pathways are…

mtrl-th · Physics 2009-10-28 Steffen Wilke , Matthias Scheffler

We introduce an approach to derive realistic Coulomb interaction terms in free standing layered materials and vertical heterostructures from ab-initio modelling of the corresponding bulk materials. To this end, we establish a combination of…

Materials Science · Physics 2015-08-12 M. Rösner , E. Şaşıoğlu , C. Friedrich , S. Blügel , T. O. Wehling

Collisions of metastable antiprotonic helium atoms with atoms of the medium induce, among other processes, transitions between hyperfine structure (HFS) states, as well as shifts and broadening of microwave M1 spectral lines. In order to…

Nuclear Theory · Physics 2019-11-26 A. V. Bibikov , G. Ya. Korenman , S. N. Yudin

A very accurate, (HF)$_2$ potential energy surface (PES) is constructed based on \ai\ calculations performed using the MOLPRO package at the CCSD(T) level of theory with an aug-cc-pvQz-F12 basis set at about 161~000 points. a higher…

Atomic and Molecular Clusters · Physics 2021-07-27 Roman I. Ovsyannikov , Vladimir Yu. Makhnev , Nikolai F. Zobov , Jacek Koput , Jonathan Tennyson

The Lennard-Jones potential is widely used to describe the interlayer interactions within layered materials like graphene. However, it is also widely known that this potential strongly underestimates the frictional properties for layered…

Materials Science · Physics 2015-04-14 Jin-Wu Jiang , Harold S. Park

Research on graphene and other two-dimensional (2D) materials, such as silicene, germanene, phosphorene, hexagonal boron nitride (h-BN), graphitic carbon nitride (g-C3N4), graphitic zinc oxide (g-ZnO) and molybdenum disulphide (MoS2), has…

Materials Science · Physics 2016-03-03 Wei Hu , Jinlong Yang

We present the first fully ab initio calculations of collision-induced broadening and shift of spectral lines in antiprotonic helium ($\bar{p}$He$^{+}$) perturbed by atomic helium. To overcome critical limitations of previous studies, we…

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