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A thermodynamic measure of the fragility of liquids has recently (Ito et al ref.1) been defined in terms of the temperature dependence of the excess entropy of liquid over crystal, scaled by the excess entropy at the glass transition…

Disordered Systems and Neural Networks · Physics 2007-05-23 L. -M. Martinez , C. A. Angell

The most puzzling aspect of the glass transition observed in laboratory is an apparent decoupling of dynamics from structure. In this paper we recount the implication of various theories of glass transition for the static correlation length…

Disordered Systems and Neural Networks · Physics 2017-02-08 S. Davatolhagh

The configurational entropy is among the key observables to characterize experimentally the formation of a glass. Physically, it quantifies the multiplicity of metastable states in which an amorphous material can be found at a given…

Statistical Mechanics · Physics 2014-08-21 Ludovic Berthier , Daniele Coslovich

Liquid crystal droplets are of great interest from physics and applications. Rigorous mathematical analysis is challenging as the problem involves harmonic maps (and in general the Oseen-Frank model), free interfaces and topological defects…

Analysis of PDEs · Mathematics 2020-09-25 Fanghua Lin , Changyou Wang

In this talk, after a short phenomenological introduction on glasses, I will describe some recent progresses that have been done in glasses using the replica method in the definition and in the evaluation of the configurational entropy (or…

Disordered Systems and Neural Networks · Physics 2009-10-31 Giorgio Parisi

The glass transition plays a central role in nature as well as in industry, ranging from biological systems such as proteins and DNA to polymers and metals. Yet the fundamental understanding of the glass transition which is a prerequisite…

Soft Condensed Matter · Physics 2017-09-27 Henriette Wase Hansen , Alejandro Sanz , Karolina Adrjanowicz , Bernhard Frick , Kristine Niss

We provide here a brief perspective on the glass transition field. It is an assessment, written from the point of view of theory, of where the field is and where it seems to be heading. We first give an overview of the main phenomenological…

Statistical Mechanics · Physics 2015-06-15 Giulio Biroli , Juan P. Garrahan

We connect the configurational entropy of a liquid to the geometrical properties of its local energy landscape, using a high-temperature expansion. It is proposed that correlations between local structures arises from their overlap and,…

Soft Condensed Matter · Physics 2016-08-24 Pierre Ronceray , Peter Harrowell

We perform Monte-Carlo simulations to analyse the structure and microscopic dynamics of a viscous Lennard-Jones liquid coupled to a quenched reference configuration of the same liquid. The coupling between the two replicas is introduced via…

Statistical Mechanics · Physics 2015-10-20 Andrea Ninarello , Ludovic Berthier , Daniele Coslovich

A molecular theory of the glass transition of network forming liquids is developed using a combination of self-consistent phonon and liquid state approaches. Both the dynamical transition and the entropy crisis characteristic of random…

Condensed Matter · Physics 2009-11-07 Randall W. Hall , Peter G. Wolynes

We propose a method to study quantitatively the glass transition in a system of interacting particles. In spite of the absence of any quenched disorder, we introduce a replicated version of the hypernetted chain equations. The solution of…

Condensed Matter · Physics 2009-10-28 Marc Mezard , Giorgio Parisi

We give evidence of a clear structural signature of the glass transition, in terms of a static correlation length with the same dependence on the system size which is typical of critical phenomena. Our approach is to introduce an external,…

Statistical Mechanics · Physics 2010-06-25 Majid Mosayebi , Emanuela Del Gado , Patrick Ilg , Hans Christian Ottinger

Vortex states in high-$T_{\rm c}$ superconductors with point defects are studied by large-scale Monte Carlo simulations of the three-dimensional frustrated XY model. A critical point is observed on the first-order phase boundary between the…

Superconductivity · Physics 2007-05-23 Yoshihiko Nonomura , Xiao Hu

We investigate the balanced $M=4$, $p=4$ spin-glass model for a one-dimensional long-range proxy for the finite dimensional short-range $p$-spin glass model to examine the nature of the glass transition beyond mean-field theory. We perform…

Disordered Systems and Neural Networks · Physics 2026-04-20 Prerak Gupta , Auditya Sharma , Bharadwaj Vedula , J. Yeo , M. A. Moore

The excitation-chain theory of the glass transition, proposed in an earlier publication, predicts diverging, super-Arrhenius relaxation times and, {\it via} a similarly diverging length scale, suggests a way of understanding the relations…

Statistical Mechanics · Physics 2009-11-11 J. S. Langer

In supercooled liquids, at a temperature between the glass transition temperature Tg and the melting point Tm, thermodynamic properties remain continuous, while dynamic behavior exhibits anomalies. The origin of such thermodynamics-dynamic…

Soft Condensed Matter · Physics 2025-06-17 X. R. Tian , D. M. Zhang , B. Zhang , D. Y. Sun , X. G. Gong

We investigate the calorimetric liquid-glass transition by performing simulations of a binary Lennard-Jones mixture in one through four dimensions. Starting at a high temperature, the systems are cooled to T=0 and heated back to the ergodic…

Disordered Systems and Neural Networks · Physics 2009-01-01 Ralf Brüning , Denis A. St-Onge , Steve Patterson , Walter Kob

Numerical heat and mass transfer analysis of a configuration where a cool liquid hydrocarbon is suddenly introduced to a hotter gas at supercritical pressure shows that a well-defined phase equilibrium can be established before substantial…

Fluid Dynamics · Physics 2022-04-25 Jordi Poblador-Ibanez , William A. Sirignano

We study the interplay between the fluid-crystal transition and the glass transition of elastic sphere system with polydispersity using nonequilibrium molecular dynamics simulations. It is found that the end point of the crystal-fluid…

Statistical Mechanics · Physics 2010-09-29 Tomoaki Nogawa , Nobuyasu Ito , Hiroshi Watanabe

Enormous enhancement in the viscosity of a liquid near its glass transition is generally connected to the growing many-body static correlations near the transition, often coined as `amorphous ordering'. Estimating the length scales of such…

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