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Linear chains of about 10-13 carbon atoms were predicted to be the most favorable phase on different metal surfaces prior to graphene nucleation. However, unlike the graphene that widely studied both theoretically and experimentally, carbon…

Mesoscale and Nanoscale Physics · Physics 2017-12-15 T. V. Pavlova , S. L. Kovalenko , K. N. Eltsov

Two-dimensional (2D) magnetic materials integrated with graphene offer a compelling platform for next-generation spintronic devices, yet nickel in its 2D form remains largely unexplored, due to fundamental synthesis limitations. Here, we…

High-quality nitrogen-doped graphene on nickel is prepared by exploiting both the catalytic properties of nickel and the solubility of nitrogen atoms into its bulk. Following the standard chemical vapor deposition procedure, a previously…

Nickel nanoparticles (Ni NPs), thanks to their peculiar properties, are interesting materials for many applications including catalysis, hydrogen storage, and sensors. In this work, Ni NPs are synthesized in aqueous solution by a simple and…

Nitrogen-doped epitaxial graphene grown on SiC(000?1) was prepared by exposing the surface to an atomic nitrogen flux. Using Scanning Tunneling Microscopy (STM) and Spectroscopy (STS), supported by Density Functional Theory (DFT)…

The healing of graphene grown from a metallic substrate is investigated using tight-binding Monte Carlo simulations. At temperatures (ranging from 1000 to 2500 K), an isolated graphene sheet can anneal a large number of defects suggesting…

Materials Science · Physics 2010-09-02 Sondes Karoui , Hakim Amara , Christophe Bichara , François Ducastelle

The formation of graphene on the (0001) surface of SiC (the Si-face) is studied by atomic force microscopy, low-energy electron microscopy, and scanning tunneling microscopy/spectroscopy. The graphene forms due to preferential sublimation…

Materials Science · Physics 2023-05-03 Luxmi , N. Srivastava , R. M. Feenstra , P. J. Fisher

Here we report the photoemission studies of intercalation process of Fe underneath graphene layer on Ni(111). The process of intercalation was monitored via XPS of corresponding core levels and UPS of the graphene-derived $\pi$ states in…

Materials Science · Physics 2009-11-13 Yu. S. Dedkov , M. Fonin , U. Rüdiger , C. Laubschat

In this study, we employ a multi-scale computational modeling approach, combining density functional theory (DFT) and self-consistent charge density functional tight binding (SCC-DFTB), to investigate hydrogen (H2) production and…

Materials Science · Physics 2025-10-21 A. Aligayev , U. Jabbarli , U. Samadova , F. J. Dominguez-Gutierrez , S. Papanikolaou , Qing Huang

The nucleation of graphene on a transition metal (TM) surface, either on a terrace or near a step edge, is systematically explored using density functional theory (DFT) calculations and applying the two-dimensional (2D) crystal nucleation…

Materials Science · Physics 2011-04-04 Junfeng Gao , Joanne Yip , Jijun Zhao , Boris I. Yakobson , Feng Ding

We report graphene films composed mostly of one or two layers of graphene grown by controlled carbon precipitation on the surface of polycrystalline Ni thin films during atmospheric chemical vapor deposition(CVD). Controlling both the…

The nucleation of graphene on Ni surface, as well as on the step, is studied using a tight binding method of SCC-DFTB. The result demonstrates that the fcc configuration has the lowest total energy and thus is the most stable one compared…

Mesoscale and Nanoscale Physics · Physics 2012-03-06 Zhou Chen , Hu Jing , Tian Yuan , Zhao Qianying , Miao Ling , Jiang Jianjun

A single-crystal sheet of graphene is synthesized on the low-symmetry substrate Ir(110) by thermal decomposition of C$_2$H$_4$ at 1500 K. Using scanning tunneling microscopy, low-energy electron diffraction, angle-resolved photoemission…

Graphene nanoflakes (GNFs) were synthesized by atmospheric pressure chemical vapour deposition of propane (C3H8) employing Ni (salen) powder without the introduction of a substrate. The graphitic nature of the GNFs was examined by an X-ray…

Applied Physics · Physics 2019-09-10 Joydip Sengupta , Kaustuv Das , U N Nandi , Chacko Jacob

In monolayer graphene, substitutional doping during growth can be used to alter its electronic properties. We used scanning tunneling microscopy (STM), Raman spectroscopy, x-ray spectroscopy, and first principles calculations to…

Films of (111)-textured Cu, Ni, and Cu$_x$Ni$_y$ were evaluated as substrates for chemical vapor deposition of graphene. A metal thickness of 400 nm to 700 nm was sputtered onto a substrate of $\alpha-$Al$_2$O$_3$(0001) at temperatures of…

Materials Science · Physics 2013-05-23 David L. Miller , Mark W. Keller , Justin M. Shaw , Ann N. Chiaramonti , Robert R. Keller

Graphene grown on metal surface, Cu(111), with a boron nitride(BN) buffer layer is studied for the first time. Our first-principles calculations reveal that charge is transferred from the copper substrate to graphene through the BN buffer…

Materials Science · Physics 2007-12-27 Y. H. Lu , P. M. He , Y. P. Feng

The production of multiple types of graphene, such as free standing, epitaxial graphene on silicon carbide and metals, graphene in solution, chemically grown graphene-like molecules, various graphene nanoribbons, and graphene oxide with…

Materials Science · Physics 2013-01-14 D. W. Boukhvalov

An operando investigation of graphene growth on (100) grains of polycrystalline nickel (Ni) surfaces was performed by means of variable-temperature scanning tunneling microscopy complemented by density functional theory simulations. A clear…

We report an approach to synthesize high quality graphene by surface segregation and substrate transfer. Graphene was segregated from Ni surface under the ambient pressure by dissolving carbon in Ni at high temperatures followed by cooling…

Materials Science · Physics 2008-12-09 Qingkai Yu , Jie Lian , Sujitra Siriponglert , Hao Li , Yong Chen , Shin-Shem Pei
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