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Using first-principles calculations based on density functional theory, we have studied the mechanical, electronic, and magnetic properties of Heusler alloys, namely, Ni$_{2}BC$ and Co$_{2}BC$ ($B$ = Sc, Ti, V, Cr and Mn as well as Y, Zr,…

Materials Science · Physics 2016-05-18 Tufan Roy , Dhanshree Pandey , Aparna Chakrabarti

Besides permitting an accurate determination of the ferromagnetic-to-paramagnetic phase transition temperature and the characteristic temperatures for the beginning and end of the growth of martensite (austenite) phase at the expense of…

Materials Science · Physics 2009-11-13 P. K. Mukhopadhyay , S. N. Kaul

The partially overlapped ferroelastic/martensitic and para-ferromagnetic phase transitions of a Ni$_{50.53}$Mn${33.65}$In$_{15.82}$ metamagnetic shape memory alloy have been studied from calorimetric, magnetic and acoustic emission…

The magnetic and thermodynamic properties of a Ni2.19Mn0.81Ga alloy with coupled magnetic and structural (martensitic) phase transitions were studied experimentally and theoretically. The magnetocaloric effect was measured by a direct…

Materials Science · Physics 2009-11-10 A. Aliev , A. Batdalov , S. Bosko , V. Buchelnikov , I. Dikshtein , V. Khovailo , V. Koledov , R. Levitin , V. Shavrov , T. Takagi

We present our recent results on temperature behaviour of magnetization observed in Ni_47Mn_39In_14 Heusler alloys. Three regions can be distinguished in the M-T diagram: (I) low temperature martensitic phase (with the Curie temperature…

An extensive experimental investigation on the structural, static magnetic, and non-equilibrium dynamical properties of polycrystalline Mn$_2$CuGe Heusler alloy using powder X-ray diffraction, DC magnetization, magnetic relaxation, magnetic…

A new method that characterizes thermal properties during a first-order phase transition is described. The technique consists in exciting the sample by a series of constant frequency thermal pulses which one in every N pulses (N is a small…

Materials Science · Physics 2024-04-30 F. J. Romero , M. C. Gallardo , J. -M. Martín-Olalla , J. del Cerro

In this paper, we report results of the first studies on the thermoelectric power (TEP) of the magnetic heusler alloy Ni$_{2.19}$Mn$_{0.81}$Ga. We explain the observed temperature dependence of the TEP in terms of the crystal field (CF)…

Strongly Correlated Electrons · Physics 2009-11-10 K. R. Priolkar , P. A. Bhobe , Shannol Dias Sapeco , Rajkumar Paudel

MnMX (M = Co or Ni, X = Si or Ge) alloys, experiencing structural transformation between Ni2In-type hexagonal and TiNiSi-type orthorhombic phases, attract considerable attention due to their potential applications as room-temperature solid…

Materials Science · Physics 2021-08-03 Tingting Zhang , Yuanyuan Gong , Bin Wang , Dongyu Cen , Feng Xu

Large thermal hysteresis in the MnFe(P, Si, B) system hinders the heat exchange rate and thus limits the magnetocaloric applications at high frequencies. Substitution of Mn by V in Mn1-xVxFe0.95P0.593Si0.33B0.077 and…

The connection between hysteresis and thermal relaxation in magnetic materials is studied from both the experimental and the theoretical viewpoint. Hysteresis and viscosity effects are measured in Finemet-type nanocrystalline materials…

Materials Science · Physics 2009-10-31 Vittorio Basso , Cinzia Beatrice , Martino LoBue , Paola Tiberto , Giorgio Bertotti

Ferromagnetic solids acquire nontrivial magnetic and caloric properties when the temperature of the structural phase transition approaches the Curie point. Deciphering magneto-structural transitions, i.e. determining their characteristic…

The irreversibility of the martensite transition in magnetic shape memory alloys (MSMAs) with respect to external magnetic field is one of the biggest challenges that limits their application as giant caloric materials. This transition is a…

Improvement of functional and structural fatigue endurance for applications of ferroelastic materials requires an optimization of their composition. A strategy for finding alloy compositions that minimize the transformation hysteresis is…

Materials Science · Physics 2025-10-21 O. Goisot , H. vanLandeghem , R. Haettel , F. Robaut , O. Robach , L. Porcar , M. Verdier

Off-stoichiometric Ni$_2$MnIn Heusler alloys have drawn recent attention due to their large magnetocaloric entropy change associated with the first-order magneto-structural transition. Here we present crystal structural, calorimetric and…

The thermal memory effect, TME, has been studied in Ni55Fe19Ga26 shape memory alloys, fabricated as ribbons via melt-spinning and as pellets via arc-melting, to evaluate its dependence on the martensitic structure and the macrostructure of…

Magnetocaloric effect (MCE), magnetization, specific heat, and magnetostriction measurements were performed in both pulsed and steady high magnetic fields to investigate the magnetocaloric properties of Heusler alloys Ni50-xCoxMn31.5Ga18.5…

Materials Science · Physics 2021-03-24 T. Kihara , T. Roy , X. Xu , A. Miyake , M. Tsujikawa , H. Mitamura , M. Tokunaga , Y. Adachi , T. Eto , T. Kanomata

Ni-Mn-based Heusler alloys, in particular all-d-metal Ni(-Co)-Mn-Ti, are highly promising materials for energy-efficient solid-state refrigeration as large multicaloric effects can be achieved across their magnetostructural martensitic…

Adding thermal conductivity enhancements to increase thermal power in solid-liquid phase-change thermal energy storage modules compromises volumetric energy density and often times reduces the mass and volume of active phase change material…

Materials Science · Physics 2020-11-26 Darin J. Sharar , Asher C. Leff , Adam A. Wilson , Andrew Smith

We study isothermal magnetization processes in the Cu-Al-Mn intermetallic alloy. Hysteresis is observed at temperatures below the spin-freezing of the system. The characteristics of the hysteresis cycles as a function of temperature and Mn…

Materials Science · Physics 2009-10-31 Eduard Obrado , Eduard Vives , Antoni Planes