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Based on large-scale molecular dynamics simulations, we propose a new charging method that should be capable of charging a Lithium-ion battery in a fraction of the time needed when using traditional methods. This charging method uses an…

Chemical Physics · Physics 2010-03-11 Ibrahim Abou Hamad , M. A. Novotny , D. Wipf , P. A. Rikvold

The correct assessment of battery states is essential to maximize battery pack performances while ensuring reliable and safe operation. This work introduces EIS2MOD, a novel modelling framework for Li-ion cells based on Distribution of…

Systems and Control · Electrical Eng. & Systems 2022-03-17 Pietro Iurilli , Claudio Brivio , Rafael E. Carrillo , Vanessa Wood

Compton scattering imaging using high-energy synchrotron x-rays allows the visualization of the spatio-temporal lithiation state in lithium-ion batteries probed in-operando. Here, we apply this imaging technique to the commercial 18650-type…

Further technological advancement of both lithium-ion and emerging battery technologies can be catalyzed by an improved understanding of the chemistry and working mechanisms of the solid electrolyte interphases (SEIs) that form at…

We present calculations that reconstruct electronic current densities in two stacked layers at known depths, using magnetic field data. Solving this inverse problem requires knowledge of the magnetic field in two planes -- one above both…

There is a need for techniques for efficient and accurate measurement of the impedance of rechargeable batteries at extra-low frequencies (ELFs, typically below 10uHz), as these reflect real usage and cycling patterns, and their importance…

Instrumentation and Detectors · Physics 2022-02-17 Christopher Dunn , Jonathan Scott

A major challenge in the development of new battery materials is understanding their fundamental mechanisms of operation and degradation. Their microscopically inhomogeneous nature calls for characterization tools that provide operando and…

Electrochemical impedance spectroscopy (EIS) is the most informative diagnostic for lithium-ion batteries: its frequency-resolved spectra decompose cell behavior into distinct electrochemical processes, revealing mechanism-specific…

Systems and Control · Electrical Eng. & Systems 2026-05-18 Shafayeth Jamil , Rehan Kapadia

Non-circuit theory drift-diffusion numerical simulation of standard potentiostatic impedance spectroscopy (IS) is a well-known strategy for characterization of materials and electronic devices. It implies the time-dependent solutions from…

Reliable health assessment of retired lithium-ion batteries is essential for safe and economically viable second-life deployment, yet remains difficult due to sparse measurements, incomplete historical records, heterogeneous chemistries,…

Signal Processing · Electrical Eng. & Systems 2025-12-02 Song Zhang , Ruohan Guo , Xiaohua Ge , Perter Mahon , Weixiang Shen

In this paper we develop an analytical framework for the study of electrochemical impedance of mixed ionic and electronic conductors (MIEC). The framework is based on first-principles and it features the coupling of electrochemical…

Chemical Physics · Physics 2017-08-23 Francesco Ciucci , Yong Hao , David G. Goodwin

Electrochemical Impedance Spectroscopy (EIS) and Equivalent Circuit Models (ECMs) are widely used to characterize the impedance and estimate parameters of electrochemical systems such as batteries. We use a generic ECM with ten parameters…

Systems and Control · Electrical Eng. & Systems 2024-03-18 Vladimir Sovljanski , Mario Paolone

Recent years have seen a rapidly escalating demand for battery technologies capable of storing more energy, charging more quickly and having longer usable lifetimes, driven largely by increased electrification of transport and by grid-scale…

Understanding battery degradation in electric vehicles (EVs) under real-world conditions remains a critical yet under-explored area of research. Central to this investigation is the challenge of estimating the specific degradation modes in…

Optimization and Control · Mathematics 2024-05-20 Raja Abhishek Appana , Faissal El Idrissi , Prashanth Ramesh , Marcello Canova , Chun Yong Kang , Kimoon Um

We have developed a novel in situ methodology for the direct study of mass transport properties in oxides with spatial and unprecedented time resolution, based on Raman spectroscopy coupled to isothermal isotope exchanges. Changes in the…

In this paper, we study a suitable experimental design of electrochemical impedance spectroscopy (EIS) to reduce the number of frequency points while not significantly affecting the uncertainties of the estimated cell's equivalent circuit…

Systems and Control · Electrical Eng. & Systems 2025-01-13 Vladimir Sovljanski , Mario Paolone , Sylvain Tant , Damien Pierre Sainflou

This paper proposes a fully unsupervised methodology for the reliable extraction of latent variables representing the characteristics of lithium-ion batteries (LIBs) from electrochemical impedance spectroscopy (EIS) data using information…

Signal Processing · Electrical Eng. & Systems 2021-07-14 Seongyoon Kim , Yun Young Choi , Jung-Il Choi

We consider cell line classification using multivariate time series data obtained from electric cell-substrate impedance sensing (ECIS) technology. The ECIS device, which monitors the attachment and spreading of mammalian cells in real time…

Quantitative Methods · Quantitative Biology 2019-11-21 Megan L. Gelsinger , Laura L. Tupper , David S. Matteson

Electrochemical impedance spectroscopy (EIS) is an effective method for studying the electrochemical systems. The interpretation of EIS is the biggest challenge in this technology, which requires reasonable modeling. However, the modeling…

Data Analysis, Statistics and Probability · Physics 2019-07-04 Shan Zhu , Xinyang Sun , Yuxuan Wang , Naiqin Zhao , Junwei Sha

Energy efficient, safe and reliable Li-ion batteries (LIBs) are required for a wide range of applications. Charging capabilities of thick electrodes still holding their stored high-energy is a most desirable characteristic in future…