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The random-phase approximation with exchange (RPAE) is used with a $B$-spline basis to compute dynamic dipole polarizabilities of noble-gas atoms and several other closed-shell atoms (Be, Mg, Ca, Zn, Sr, Cd, and Ba). From these, values of…

Atomic Physics · Physics 2015-07-08 A. R. Swann , J. A. Ludlow , G. F. Gribakin

Electron correlations in molecules can be divided in short range dynamical correlations, long range Van der Waals type interactions and near degeneracy static correlations. In this work we analyze for a one-dimensional model of a…

Chemical Physics · Physics 2014-05-13 K. J. H. Giesbertz , R. van Leeuwen

Exploiting the similarities between the Helmholtz wave equation and the Klein-Gordon equation, the former is linearized using the Feschbach-Villars procedure used for linearizing the Klein-Gordon equation. Then the Foldy-Wouthuysen…

Optics · Physics 2010-02-23 Sameen Ahmed Khan

Van der Waals interactions between flat surfaces in uniaxial anisotropic media are investigated in the nonretarded limit. The main focus is the effect of nonzero tilt between the optical axis and the surface normal on the strength of van…

Soft Condensed Matter · Physics 2018-03-13 Pavel Kornilovitch

An approximation-free, numerically efficient algorithm is presented for the Hamiltonian eigen-states of the Stark-Hydrogen problem describing a quantum particle exposed to the central Coulomb force and a homogeneous external field. As an…

Atomic Physics · Physics 2022-03-17 Seyedmohammad Yusofsani , Mroslav Kolesik

We have computed the widely neglected first-order interaction between neutral atoms. At interatomic separations typical of condensed media, it is nearly equal to the 1/r^6 second-order London energy inferred from interactions in gasses. Our…

Biomolecules · Quantitative Biology 2007-07-01 Kevin Cahill , V. Adrian Parsegian

We study the contribution of electron-atom interaction to the equation of state for partially ionized hydrogen plasma using the cluster-virial expansion. For the first time, we use the Beth-Uhlenbeck approach to calculate the second virial…

Plasma Physics · Physics 2015-05-18 Yultuz A. Omarbakiyeva , Carsten Fortmann , T. S. Ramazanov , Gerd Röpke

A partial separation of the variables is practicable for the solution of Schroedinger's temporally independent equation in cartesian coordinates x,y,z, which yields moderately simple algebraic formulae for the amplitude functions involving…

General Physics · Physics 2017-09-15 J. F. Ogilvie

We have studied a simple effective model of charge ordered insulators. The tight binding Hamiltonian consists of the effective on-site interaction U and the intersite density-density interaction Wij (both: nearest-neighbor and…

Strongly Correlated Electrons · Physics 2023-07-19 Konrad Kapcia , Stanisław Robaszkiewicz

We predict a discriminatory interaction between a chiral molecule and an achiral molecule which is mediated by a chiral body. To achieve this, we generalize the van der Waals interaction potential between two ground-state molecules with…

Quantum Physics · Physics 2017-05-19 Pablo Barcellona , Hassan Safari , A. Salam , Stefan Yoshi Buhmann

A new implementation is proposed for including van der Waals interactions in Density Functional Theory using the Maximally-Localized Wannier functions. With respect to the previous DFT/vdW-WF method, the present DFT/vdW-WF2 approach, which…

Strongly Correlated Electrons · Physics 2015-06-03 A. Ambrosetti , P. L. Silvestrelli

Optical dynamics in van der Waals heterobilayers is of fundamental scientific and practical interest. Based on a time-dependent adiabatic GW approach, we discover a new many-electron (excitonic) channel for converting photoexcited…

Materials Science · Physics 2023-05-30 Chen Hu , Mit H. Naik , Yang-Hao Chan , Steven G. Louie

In some respects, a cluster consisting of many atoms may be regarded as a single large atom. Knowing the dielectric properties of such a cluster permits one to evaluate the form of the van der Waals (dispersion) interactions between two…

Soft Condensed Matter · Physics 2009-11-07 M. M. Calbi , S. M. Gatica , D. Velegol , M. W. Cole

The positron-hydrogen atom scattering system is considered within the S-wave model. Convergence in the elastic scattering, excitation, ionization, and positronium formation channels is studied as a function of the number and type of states…

Atomic Physics · Physics 2009-10-31 Alisher S. Kadyrov , Igor Bray

New types of stationary solutions of a one-dimensional driven sixth-order Cahn-Hilliard type equation that arises as a model for epitaxially growing nano-structures such as quantum dots, are derived by an extension of the method of matched…

Mathematical Physics · Physics 2008-11-14 M. D. Korzec , P. L. Evans , A. Münch , B. Wagner

By generalizing Bo Gao's approach [Phys. Rev. A 58, 1728 (1998)] for solving the Schr\"{o}dinger equation for an isotropic van der Waals (vdW) potential to the systems with a multi-scale anisotropic long-range interaction, we derive the…

Quantum Gases · Physics 2022-07-22 Ruijie Du , Ran Qi , Peng Zhang

We consider the van der Waals energy of an atom near the infinitely thin sphere with finite conductivity which model the fullerene. We put the sphere into spherical cavity inside the infinite dielectric media, then calculate the energy of…

Quantum Physics · Physics 2011-03-30 Nail R. Khusnutdinov

Ubiquitous Van der Waals interactions between atoms and molecules are important for many molecular and solid structures. These systems are often studied from first principles using the Density Functional Theory (DFT). However, the commonly…

Materials Science · Physics 2009-11-13 Pier Luigi Silvestrelli

The dissipative dynamics anticipated in the proof of 't Hooft's existence theorem -- "For any quantum system there exists at least one deterministic model that reproduces all its dynamics after prequantization" -- is constructed here…

Quantum Physics · Physics 2009-02-10 Hans-Thomas Elze

It is an undisputed textbook fact that non-retarded van der Waals (vdW) interactions between isotropic dimers are attractive, regardless of the polarizability of the interacting systems or spatial dimensionality. The universality of vdW…

Mesoscale and Nanoscale Physics · Physics 2017-05-31 Mainak Sadhukhan , Alexandre Tkatchenko