English
Related papers

Related papers: The spontaneous symmetry breaking in Ta$_2$NiSe$_5…

200 papers

The origin of the second order phase transition at 328K in Ta$_2$NiSe$_5$, a prominent candidate for direct gap excitonic insulator, remains under fervent debate. The driving force for the transition can be revealed by identification of the…

Strongly Correlated Electrons · Physics 2021-03-05 G. Blumberg

On cooling through a temperature $T_S$ of around 324 K, Ta$_2$NiSe$_5$ undergoes a transition from a semimetallic state to one with a gapped electronic spectrum which is suspected to be an excitonic insulator. However, at this transition…

Strongly Correlated Electrons · Physics 2025-04-16 Elliott Rosenberg , Joss Ayres-Sims , Andrew Millis , David Cobden , Jiun-Haw Chu

Realizing an excitonic insulator phase from narrow-gap semiconductors remains challenging, as unambiguous experimental signatures are difficult to establish. Ta$_2$NiSe$_5$ has been widely regarded as a leading candidate, yet the nature of…

Materials Science · Physics 2025-12-11 Keyu Wei , Yixuan Luo , Kenji Watanabe , Takashi Taniguchi , Yanfeng Guo , Xiaoxiang Xi

The excitonic insulator Ta$_2$NiSe$_5$ experiences a first-order structural transition under pressure from rippled to flat layer-structure at Ps = 3 GPa, which drives the system from an almost zero-gap semiconductor to a semimetal. The…

We study the electronic phase diagram of the excitonic insulator candidates Ta$_2$Ni(Se$_{1-x}$S$_x$)$_5$ [x=0, ... ,1] using Raman spectroscopy. Critical excitonic fluctuations are observed, that diminish with $x$ and ultimately shift to…

Strongly Correlated Electrons · Physics 2021-12-30 Pavel A. Volkov , Mai Ye , Himanshu Lohani , Irena Feldman , Amit Kanigel , Girsh Blumberg

We investigate the non-equilibrium electronic structure and characteristic time scales in a candidate excitonic insulator, Ta$_2$NiSe$_5$, using time- and angle-resolved photoemission spectroscopy with a temporal resolution of 50 fs.…

In this study, the optical response to a terahertz pulse was investigated in the transition metal chalcogenide Ta$_2$NiSe$_5$, a candidate excitonic insulator. First, by irradiating a terahertz pulse with a relatively weak electric field…

Transition metal chalcogenide Ta$_2$NiSe$_5$, a promising material for the excitonic insulator, is investigated on the basis of the quasi-one-dimensional three-chain Hubbard model with two conduction ($c$) bands and one valence ($f$) band.…

Strongly Correlated Electrons · Physics 2018-06-19 Kaoru Domon , Takemi Yamada , Yoshiaki Ōno

An excitonic insulator phase is expected to arise from the spontaneous formation of electron-hole pairs (excitons) in semiconductors where the exciton binding energy exceeds the size of the electronic band gap. At low temperature, these…

Strongly Correlated Electrons · Physics 2022-09-02 Selene Mor , Marc Herzog , Claude Monney , Julia Stähler

TiSe$_2$ is thought to be an insulator with a bandgap of ~0.1eV. It has attracted a much interest because, among of a rich array of unique properties, many have thought TiSe$_2$ is a rare realisation of an excitonic insulator. Below 200 K,…

Materials Science · Physics 2025-06-10 Ross E. Larsen , Dimitar Pashov , Matthew D. Watson , Swagata Acharya , Mark van Schilfgaarde

In the presence of electron-phonon coupling, an excitonic insulator harbors two degenerate ground states described by an Ising-type order parameter. Starting from a microscopic Hamiltonian, we derive the equations of motion for the Ising…

Strongly Correlated Electrons · Physics 2020-12-25 H. Ning , O. Mehio , M. Buchhold , T. Kurumaji , G. Refael , J. G. Checkelsky , D. Hsieh

We investigate an interesting anisotropic van der Waals material, Ta$_{2}$NiSe$_{5}$, using optical spectroscopy. Ta$_{2}$NiSe$_{5}$ has been known as one of the few excitonic insulators proposed over 50 years ago. Ta$_{2}$NiSe$_{5}$ has…

Materials Science · Physics 2018-08-21 Yu-Seong Seo , Man Jin Eom , Jun Sung Kim , Chang-Jong Kang , Byung Il Min , Jungseek Hwang

Femtosecond time-resolved mid-infrared reflectivity is used to investigate the electron and phonon dynamics occurring at the direct band gap of the excitonic insulator Ta$_2$NiSe$_5$ below the critical temperature of its structural phase…

Excitons, quasiparticles of electrons and holes bound by Coulombic attraction, are created transiently by light and play an important role in optoelectronics, photovoltaics and photosynthesis. While they are also predicted to form…

Strongly Correlated Electrons · Physics 2021-09-29 Keisuke Fukutani , Roland Stania , Chang Il Kwon , Jun Sung Kim , Ki Jeong Kong , Jaeyoung Kim , Han Woong Yeom

The three-chain Hubbard model for Ta$_2$NiSe$_5$ known as a candidate material for the excitonic insulator is investigated over the wide range of energy gap $D$ between the two-fold degenerate conduction bands and the nondegenerate valence…

Strongly Correlated Electrons · Physics 2016-04-12 Takemi Yamada , Kaoru Domon , Yoshiaki Ōno

We present a first-principles study based on density functional theory (DFT) on the electronic and structural properties of Ta2NiSe5, a layered transition metal chalcogenide that has been considered as a possible candidate for an excitonic…

Materials Science · Physics 2025-09-23 Weichen Tang , Zhenglu Li , Cheng Chen , Yu He , Steven G. Louie

The excitonic insulator (EI) is an exotic ground state of narrow-gap semiconductors and semimetals arising from spontaneous condensation of electron-hole pairs bound by attractive Coulomb interaction. Despite research on EIs dating back to…

We reveal an ultrafast purely electronic phase transition in \TNS, which is a plausible excitonic insulator, after excited by an ultrafast infrared laser pulse. Specifically, the order parameter of the strong electron-hole binding shrinks…

Strongly Correlated Electrons · Physics 2020-07-01 Tangwei Tang , Hongyuan Wang , Shafeng Duan , Yuanyuan Yang , Chaozhi Huang , Yanfeng Guo , Dong Qian , Wentao Zhang

We utilized high-energy-resolution resonant inelastic X-ray scattering (RIXS) at both the Ta and Ni $L_3$-edges to map out element-specific particle-hole excitations in Ta$_2$NiSe$_5$ across the phase transition. Our results reveal a…

Excitonic insulators are long-sought-after quantum materials predicted to spontaneously open a gap by the Bose condensation of bound electron-hole pairs, namely, excitons, in their ground state. Since the theoretical conjecture, extensive…