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We present an approach to renormalized second-order Green's function perturbation theory (GF2) which avoids all dependency on continuous variables, grids or explicit Green's functions, and is instead formulated entirely in terms of static…

Chemical Physics · Physics 2020-06-26 Oliver J. Backhouse , Max Nusspickel , George H. Booth

We show how to construct an effective Hamiltonian whose dimension scales linearly with system size, and whose eigenvalues systematically approximate the excitation energies of GW theory. This is achieved by rigorously expanding the…

Chemical Physics · Physics 2023-07-18 Charles J. C. Scott , Oliver J. Backhouse , George H. Booth

A reliable and efficient computation of the entire single-particle spectrum of correlated molecules is an outstanding challenge in the field of quantum chemistry, with standard density functional theory approaches often giving an inadequate…

Chemical Physics · Physics 2021-10-08 Oliver J. Backhouse , Alejandro Santana-Bonilla , George H. Booth

Despite recent advances, systematic quantitative treatment of the electron correlation problem in extended systems remains a formidable task. Systematically improvable Green's function methods capable of quantitatively describing weak and…

Chemical Physics · Physics 2016-11-15 Alexander A. Rusakov , Dominika Zgid

We derive semiclassical approximations for wavefunctions, Green's functions and expectation values for classically chaotic quantum systems. Our method consists of applying singular and regular perturbations to quantum Hamiltonians. The…

Chaotic Dynamics · Physics 2010-03-09 Martin Sieber

The Green's function method in the \emph{Quasiparticle Time Blocking Approximation} is applied to nuclear excitations in $^{132}$Sn and $^{208}$Pb. The calculations are performed self-consistently using a Skyrme interaction. The method…

Nuclear Theory · Physics 2008-11-26 N. Lyutorovich , J. Speth , A. Avdeenkov , F. Gruemmer , S. Kamerdzhiev , S. Krewald , V. I. Tselyaev

We develop and analyze a fault-tolerant quantum algorithm for computing $n$-th order response properties necessary for analysis of non-linear spectroscopies of molecular and condensed phase systems. We use a semi-classical description in…

Quantum Physics · Physics 2024-04-23 Tyler Kharazi , Torin F. Stetina , Liwen Ko , Guang Hao Low , K. Birgitta Whaley

Inspired by the quantum computing algorithms for Linear Algebra problems [HHL,TaShma] we study how the simulation on a classical computer of this type of "Phase Estimation algorithms" performs when we apply it to solve the Eigen-Problem of…

Data Structures and Algorithms · Computer Science 2017-04-07 Michael Ben-Or , Lior Eldar

An outline is given of an extended perturbative solution of Euclidean QCD which systematically accounts for a class of nonperturbative effects, while allowing renormalization by the perturbative counterterms. Proper vertices Gamma are…

High Energy Physics - Theory · Physics 2014-11-18 M. Stingl

The self-consistent theory of the correlation effects in Highly Correlated Systems(HCS) is presented. The novel Irreducible Green's Functions(IGF) method is discused in detail for the Hubbard model and random Hubbard model. The…

Strongly Correlated Electrons · Physics 2008-02-03 A. L. Kuzemsky

Cubic phonon interactions are now regularly computed from first principles, and the quartic interactions have begun to receive more attention. Given this realistic anharmonic vibrational Hamiltonian, the classical phonon Green's function…

Materials Science · Physics 2023-11-21 Enda Xiao , Chris A. Marianetti

A new scheme of first-principles computation for strongly correlated electron systems is proposed. This scheme starts from the local-density approximation (LDA) at high-energy band structure, while the low-energy effective Hamiltonian is…

Materials Science · Physics 2007-05-23 Yoshiki Imai , Igor V. Solovyev , Masatoshi Imada

The second-order Green's function method (GF2) was shown recently to be an accurate self-consistent approach for electronic structure of correlated systems since the self-energy accounts for both the weak and some of the strong correlation.…

Chemical Physics · Physics 2016-03-31 Daniel Neuhauser , Roi Baer , Dominika Zgid

In this work, we introduce a new approach for constructing a renormalized and regularized Fock matrix for self-consistent field calculations. The scheme relies on second-order perturbation theory and is conceptually related to quasiparticle…

Chemical Physics · Physics 2026-01-06 Joshua Krieger , Johannes Tölle

We extend the concept of the multichannel Dyson equation that we have recently derived to model photoemission spectra by coupling the one- and the three-body Green's functions, to higher-order Green's functions and to other spectroscopies.…

Strongly Correlated Electrons · Physics 2025-01-09 Gabriele Riva , Théodore Fischer , Stefano Paggi , J. Arjan Berger , Pina Romaniello

Microscopic calculations of the electromagnetic response of medium-mass nuclei are now feasible thanks to the availability of realistic nuclear interactions with accurate saturation and spectroscopic properties, and the development of…

Nuclear Theory · Physics 2019-06-12 F. Raimondi , C. Barbieri

In this work, we present a new diagrammatic method for computing the effective Hamiltonian of driven nonlinear oscillators. At the heart of our method is a self-consistent perturbation expansion developed in phase space, which establishes a…

We develop a cubic scaling approach to excited-state-specific second order perturbation theory in which the completeness of a local correlation treatment is carefully matched between the ground and excited state. With this matching, the…

Chemical Physics · Physics 2025-05-14 Rachel Clune , Eric Neuscamman

In the present work we study the two-point correlation function $R(\epsilon)$ of the quantum mechanical spectrum of a classically chaotic system. Recently this quantity has been computed for chaotic and for disordered systems using periodic…

Condensed Matter · Physics 2009-10-30 Daniel L. Miller

We present a real-time second-order Green's function (GF) method for computing excited states in molecules and nanostructures, with a computational scaling of $O(N_{\rm e}^3$), where $N_{\rm e}$ is the number of electrons. The cubic scaling…

Chemical Physics · Physics 2024-01-29 Leopoldo Mejía , Jia Yin , David R. Reichman , Roi Baer , Chao Yang , Eran Rabani
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