Related papers: Effect of microstructure on polymer chain dynamics…
We perform a two-dimensional molecular-dynamics study of a model for sheared bidisperse granular systems under conditions of simple shear and Poiseuille flow. We propose a mechanism for particle-size segregation based on the observation…
Deviations between macrorheological and particle-based microrheological measurements are often considered a nuisance and neglected. We study aqueous poly(ethylene oxide) (PEO) hydrogels for varying PEO concentrations and chain lengths that…
The microstructural geometry (MG) of materials has a significant influence on their macroscopic response, all the more when the process is essentially microscopic as for microstructural degradation processes. However, the MG tends to be…
This study investigated the coalescence of polymer solution drops on the solid substrates. When two drops meet at their contact line on a substrate, the liquid bridge connecting the two drops increases in size with time. The height and…
In this work, we derive particle schemes, based on micro-macro decomposition, for linear kinetic equations in the diffusion limit. Due to the particle approximation of the micro part, a splitting between the transport and the collision part…
We study a heuristic, core-scale model for the transport of polymer particles in a two phase (oil and water) porous medium. We are motivated by recent experimental observations which report increased oil recovery when polymers are injected…
The close packing density of log-normal and bimodal distributed, surface-adsorbed particles or discs in 2D is studied by numerical simulation. For small spread in particle size, the system orders in a polycrystalline structure of hexagonal…
Small angle X-ray scattering (SAXS) studies in poly[2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylene vinylene] (MEH-PPV) with varying conjugation, and polyethylene dioxythiophene complexed with polystyrene sulfonate (PEDOT-PSS) in different…
Both the dispersion state of nanoparticles (NPs) within polymer nanocomposites (PNCs) and the dynamical state of the polymer altered by the presence of the NP/polymer interfaces have a strong impact on the macroscopic properties of PNCs. In…
We investigate the mechanisms by which inertial particles dispersed at semi-dilute conditions cause significant drag-reduction in a turbulent channel flow at $\mathrm{Re}_\tau = 180$. We consider a series of four-way coupled Euler-Lagrange…
Coalescence of micrometer-scale droplets is impacted by several parameters, including droplet size, viscosities of the two phases, droplet velocity and angle of approach, as well as interfacial tension and surfactant coverage. The dynamics…
To evaluate shear viscosity of ethylene glycol oligomers (EGO)/water binary mixture by means of coarse-grained molecular dynamics (CG-MD) simulations, we proposed the self-diffusion-coefficient-based parameterization of non-bonded…
Successful assembly of suspended nanoscale rod-like particles depends on fundamental phenomena controlling rotational and translational diffusion. Despite the significant developments in fluidic fabrication of nanostructured materials, the…
Dense ceramics are irreplaceable in applications requiring high mechanical stiffness, chemical and temperature resistance and low weight. To improve their toughness, ceramics can be reinforced with elongated inclusions. Recent manufacturing…
Recently singular solutions have been discovered in purely elongational flows of visco-elastic fluids. We surmise that these solutions are the mathematical structures underlying the so-called birefringent strands seen experimentally. In…
Microgels are soft colloidal particles constituted by cross-linked polymer networks with a high potential for applications. In particular, after adsorption at a fluid interface, interfacial tension provides two-dimensional (2D) confinement…
The effect of silica nanoparticles on transient microemulsion networks made of microemulsion droplets and telechelic copolymer molecules in water is studied, as a function of droplet size and concentration, amount of copolymer, and…
We study the structural and dynamical mechanisms of reinforcement of a polymer nanocomposite (PNC) via coarse-grained molecular dynamics simulations. In a regime of strong polymer-filler interactions, the stress at failure of the PNC is…
Mucus is a biological gel covering the surface of several tissues and insuring key biological functions, including as a protective barrier against dehydration, pathogens penetration, or gastric acids. Mucus biological functioning requires a…
We address a novel method for analytical determinations that combines simplicity, rapidity, low consumption of chemicals, and portability with high analytical performance taking into account parameters such as precision, linearity,…