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Practical applicability of quantum optimisation on near term devices is constrained by limited qubit counts and hardware noise, which restricts the scalability of quantum optimisation algorithms for combinatorial problems. The simulation of…

Quantum Physics · Physics 2026-05-01 Namasi G Sankar , Georgios Miliotis , Simon Caton

This study benchmarks the GFN family of semiempirical methods (GFN1-xTB, GFN2-xTB, GFN0-xTB, and GFN-FF) against density functional theory (DFT) for the evaluation of optimized molecular geometries and electronic properties of small organic…

Chemical short-range order (SRO) provides new opportunities for tuning alloy properties, but conventional computational thermodynamics frameworks such as CALPHAD, based on Bragg-Williams mean-field approximations, cannot properly describe…

Materials Science · Physics 2025-08-12 Chuliang Fu

We present implementation of second- and third-order algebraic diagrammatic construction theory for efficient and accurate computations of molecular electron affinities (EA), ionization potentials (IP), and densities of states…

Chemical Physics · Physics 2020-07-28 Samragni Banerjee , Alexander Yu. Sokolov

Organizing sensor nodes in clusters is an effective method for energy preservation in a Wireless Sensor Network (WSN). Throughout this research work we present a novel hybrid clustering scheme, that combines a typical gradient clustering…

Distributed, Parallel, and Cluster Computing · Computer Science 2020-12-07 Basilis Mamalis , Marios Perlitis

We demonstrate that the effective Hamiltonians obtained with the downfolding procedure based on double unitary coupled cluster (DUCC) ansatz can be used in the context of Greens function coupled cluster (GFCC) formalism to calculate…

Computational Physics · Physics 2020-12-02 Nicholas P Bauman , Bo Peng , Karol Kowalski

Multipole moments are the first order responses of the energy to spatial derivatives of the electric field strength. The quality of density functional theory (DFT) prediction of molecular multipole moments thus characterizes errors in…

Chemical Physics · Physics 2021-02-23 Diptarka Hait , Yu Hsuan Liang , Martin Head-Gordon

We present GridFF, an efficient method for simulating molecules on rigid substrates, derived from techniques used in protein-ligand docking in biochemistry. By projecting molecule-substrate interactions onto precomputed spatial grids with…

Chemical Physics · Physics 2025-08-22 Indranil Mal , Milan Kočí , Paolo Nicolini , Prokop Hapala

Except for small molecules, it is impossible to solve many electrons systems without imposing severe approximations. If the configuration interaction approaches (CI) or Coupled Clusters techniques \cite{FuldeBook} are applicable for…

Strongly Correlated Electrons · Physics 2009-11-11 J. P. Julien , Johann Bouchet

We present a new linear scaling method for the energy minimization step of semiempirical and first-principles Hartree-Fock and Kohn-Sham calculations. It is based on the self-consistent calculation of the optimum localized orbitals of any…

Materials Science · Physics 2009-11-10 Luis Seijo , Zoila Barandiaran

This paper presents an accelerated spherical K-means clustering algorithm for large-scale and high-dimensional sparse document data sets. We design an algorithm working in an architecture-friendly manner (AFM), which is a procedure of…

Machine Learning · Statistics 2024-11-19 Kazuo Aoyama , Kazumi Saito

Currently, identification of crystallization pathways in polymers is being carried out using molecular simulation-based data on a preset cut-off point on a single order parameter (OP) to define nucleated or crystallized regions. Aside from…

Computational Physics · Physics 2025-07-25 Elyar Tourani , Brian J. Edwards , Bamin Khomami

We introduce an algorithm based on Generalized Dual Method (GDM) to efficiently study the dynamics of a particle in quasiperiodic environments without the need to use periodic approximations or to save the information of the vertices that…

Chaotic Dynamics · Physics 2022-04-28 Alan Rodrigo Mendoza Sosa , Atahualpa S. Kraemer

Model Order Reduction (MOR) can significantly reduce the computational cost of vibroacoustic simulations. While most MOR research focuses on single-domain systems (e.g., structural dynamics or computational fluid mechanics), this work…

Applied Physics · Physics 2026-02-05 Sander Metting van Rijn , Linus Taenzer , Paolo Tiso , Bart Van Damme

We assess the performance of the Quantum Flow (QFlow) algorithm employing cost-effective solvers based on the unitary coupled-cluster ansatz with single and double excitations (QFlow-SD). The resulting energies are benchmarked against those…

Chemical Physics · Physics 2026-05-05 Bhumika Jayee , Nathan M. Myers , Duo Song , Eric J. Bylaska , Karol Kowalski , Nicholas P. Bauman

Neutral atom quantum computing's great scaling potential has resulted in it emerging as a popular modality in recent years. For state preparation, atoms are loaded stochastically and have to be detected and rearranged at runtime to create a…

Emerging Technologies · Computer Science 2025-09-16 Jonas Winklmann , Martin Schulz

In a recent paper, J. Chem. Phys. 162, 214101 (2025), a novel approach for the rigidification of a molecular cluster was proposed, in which starting with an all-atom (AA) potential, a coarse-grained (CG) potential for the associated cluster…

Chemical Physics · Physics 2025-09-08 João V. M. Pimentel , Vladimir A. Mandelshtam

Elastodynamic Green's functions are an essential ingredient in seismology as they form the connection between direct observations of seismic waves and the earthquake source. They are also fundamental to various seismological techniques…

Geophysics · Physics 2025-02-06 John M. Rekoske , Dave A. May , Alice-Agnes Gabriel

A new method for implementing the kinetic energy operator for real-space, grid-based electronic structure codes is developed. It is based on multi-order Adaptive Finite Differencing (AFD) and uses atomic pseudo orbitals produced by the…

Computational Physics · Physics 2023-05-23 E. L. Briggs , Wenchang Lu , J. Bernholc

A method based on separated integration to estimate anharmonic corrections to energy and vibration of molecules in a second-order diagrammatic vibrational many-body Green's function formalism has already been presented. A severe bottleneck…

Chemical Physics · Physics 2019-09-17 Prashant Rai , Khachik Sargsyan , Habib Najm , So Hirata
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