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Monolayer hexagonal boron nitride (hBN) has recently become the focus of intense research as a material to host quantum emitters. Although it is well known that such emission is associated with point defects, so far no conclusive…

Defect states in 2D materials present many possible uses but both experimental and computational characterization of their spectroscopic properties is difficult. We provide and compare results from 13 DFT and ab initio computational methods…

Computational Physics · Physics 2018-02-12 Jeffrey R. Reimers , Ali Sajid , Rika Kobayashi , Michael J. Ford

Charged defects in 2D materials have emerging applications in quantum technologies such as quantum emitters and quantum computation. Advancement of these technologies requires rational design of ideal defect centers, demanding reliable…

Materials Science · Physics 2017-12-13 Feng Wu , Galatas Andrew , Ravishankar Sundararaman , Dario Rocca , Yuan Ping

The $V_N N_B$ defect in hexagonal boron nitride (h-BN), comprising a nitrogen vacancy adjacent to a nitrogen-for-boron substitution, is modelled in regard to its possible usefulness in a nanophotonics device. The modelling is done on both a…

Materials Science · Physics 2020-10-21 A. Sajid , Jeffrey R. Reimers , Rika Kobayashi , Michael J. Ford

Defects in hexagonal boron nitride (hBN) exhibit single-photon emission (SPE) and are thus attracting broad interest as platforms for quantum information and spintronic applications. However, the atomic structure and the specific impact of…

Recently, numerous techniques have been reported for generating optically active defects in exfoliated hexagonal boron nitride (hBN), which hold transformative potential for quantum photonic devices. However, achieving on-demand generation…

Atomic defects in solid-state materials are building blocks for future quantum technologies, such as quantum communication networks, computers, and sensors. Until recently, a handful of defects in a small selection of host materials have…

Mesoscale and Nanoscale Physics · Physics 2025-10-07 Tobias Vogl , Viktor Ivády , Isaac J. Luxmoore , Hannah L. Stern

Hexagonal boron nitride (hBN) is a wide band gap, van der Waals material that is highly promising for solid-state quantum technologies as a host of optically addressable, paramagnetic spin defects. Intrinsic and extrinsic point defects…

Quantum Physics · Physics 2025-09-12 Petros-Panagis Filippatos , Tom J. P. Irons , Katherine Inzani

Hexagonal boron nitride (hBN) is attracting a lot of attention in the last years, thanks to its many remarkable properties. These include the presence of single-photon emitters with superior optical properties, which make it an ideal…

Color centers in hexagonal boron nitride (hBN) have become an intensively researched system due to their potential applications in quantum technologies. There has been a large variety of defects being fabricated, yet, for many of them, the…

Quantum Physics · Physics 2024-08-02 Chanaprom Cholsuk , Ashkan Zand , Asli Cakan , Tobias Vogl

Spin defects in hexagonal boron nitride (hBN) are promising quantum systems for the design of flexible two-dimensional quantum sensing platforms. Here we rely on hBN crystals isotopically enriched with either $^{10}$B or $^{11}$B to…

Materials Science · Physics 2023-10-03 A. Haykal , R. Tanos , N. Minotto , A. Durand , F. Fabre , J. Li , J. H. Edgar , V. Ivady , A. Gali , T. Michel , A. Dréau , B. Gil , G. Cassabois , V. Jacques

Crystal defects in the two-dimensional insulator hexagonal boron nitride (hBN) can host localised electronic states that are candidates for applications in quantum technology, yet the precise chemical and structural nature of the defects…

Materials Science · Physics 2019-12-18 A Sajid , Kristian S Thygesen , Jeffrey R Reimers , Michael J Ford

The signature of defects in the optical spectra of hexagonal boron nitride (BN) is investigated using many body perturbation theory. A single BN-sheet serves as a model for different layered BN- nanostructures and crystals. In the sheet we…

Mesoscale and Nanoscale Physics · Physics 2011-05-03 C. Attaccalite , M. Bockstedte , A. Marini , A. Rubio , L. Wirtz

Evaluation of the defect levels in low-dimensional materials is an important aspect of quantum science. In this article, we report a facile synthesis method of hexagonal boron nitride (h-BN) and evaluate the defects and their light emission…

Mesoscale and Nanoscale Physics · Physics 2022-03-30 Ashly Sunny , Aniket Balapure , Ramakrishnan Ganesan , R. Thamankar

The controlled creation and manipulation of defects in 2D materials has become increasingly popular as a means to design and tune new material functionalities. However, defect characterization by direct atomic imaging is often severely…

Materials Science · Physics 2023-12-06 Dana O. Byrne , Jim Ciston , Frances I. Allen

Creation of defect with predetermined optical, chemical and other characteristics is a powerful tool to enhance the functionalities of materials. Herewith, we utilize density functional theory to understand the microscopic mechanisms of…

Materials Science · Physics 2022-08-31 P. Huang , M. Grzeszczyk , K. Vaklinova , K. Watanabe , T. Taniguchi , K. S. Novoselov , M. Koperski

Key properties of nine possible defect sites in hexagonal boron nitride (h-BN) are predicted using density-functional theory and are corrected by applying results from high-level ab initio calculations. Observed h-BN electron-paramagnetic…

Computational Physics · Physics 2018-02-12 A. Sajid , Jeffrey R. Reimers , Michael J. Ford

Quantum emitters in hexagonal boron nitride (hBN) have gained significant attention due to a wide range of defects that offer high quantum efficiency and single-photon purity at room temperature. Most theoretical studies on hBN defects…

Quantum Physics · Physics 2025-12-01 Chanaprom Cholsuk , Sujin Suwanna , Tobias Vogl

Paramagnetic substitutional carbon (C$_\text{B}$, C$_\text{N}$) defects in hexagonal boron nitride (hBN) are discussed as candidates for quantum bits. Their identification and suitability are approached by means of photoluminescence (PL),…

Quantum Physics · Physics 2021-08-11 Philipp Auburger , Adam Gali

Extensive photochemical and spectroscopic properties of the $V_B^-$ defect in hexagonal boron nitride are calculated, concluding that the observed photoemission associated with recently observed optically-detected magnetic resonance is most…

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