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Related papers: Highly ordered lead-free double perovskite halides…

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Lead-free iodide double perovskites are an interesting class of materials since they combine a relatively low toxicity (compared to the lead counterpart) with the small bandgap typical of iodide-based perovskite structures. Their reported…

Recent observations indicated that the photoelectric conversion properties of perovskite materials are intimately related to the presence of superlattice structures and other unusual nanoscale features in them. The low dimensional or mixed…

Mesoscale and Nanoscale Physics · Physics 2021-05-11 Susmita Bhattacharya , Goutam Kumar Chandra , P. Predeep

Halide perovskites are promising materials for light-emitting and light-harvesting applications. In this context, two-dimensional perovskites such as nanoplatelets or Ruddlesden-Popper and Dion-Jacobson layered structures are important…

Applied Physics · Physics 2021-10-25 Sushant Ghimire , Christian Klinke

Organic-inorganic hybrid double perovskites have attracted increasing interest in the commercialization of lead-free and nontoxic perovskites due to their unique optoelectronic properties compared with inorganic perovskites. In this study,…

Applied Physics · Physics 2023-06-14 A. Johnson , B. A. Ikyo , T. J. Ikyumbur , F. Gbaorun , A. A. Nathan

Heterovalent substitution of toxic lead is an increasingly popular design strategy to obtain environmentally sustainable variants of the exciting material class of halide perovskites. Perovskite nanocrystals (NCs) obtained through…

Materials Science · Physics 2023-01-24 Fiona Treber , Kilian Frank , Bert Nickel , Carola Lampe , Alexander S. Urban

Stability and toxicity issues with the hybrid lead iodide perovskite MAPbI$_3$ necessitate a hunt for potential alternatives. Here, we shed light on promising photovoltaic properties of gold mixed-valence halide perovskites…

Materials Science · Physics 2020-01-07 Jiban Kangsabanik , Supriti Ghorui , M. Aslam , Aftab Alam

Lead halide perovskites are a remarkable class of materials that have emerged over the past decade as being suitable for application in a broad range of devices, such as solar cells, light-emitting diodes, lasers, transistors, and memory…

Applied Physics · Physics 2020-08-03 Katelyn P. Goetz , Alexander D. Taylor , Fabian Paulus , Yana Vaynzof

Halide perovskites are currently under intense investigation due to their potential applications in optoelectronics and solar cells. Among them several crystallize in low symmetry lattice structures like trigonal, hexagonal, orthorhombic…

Materials Science · Physics 2017-11-15 A. Koliogiorgos , S. Baskoutas , I. Galanakis

Realizing semiconductors with high symmetry of their crystallographic structures has been a virtue of inorganic materials and has resulted in novel physical behaviors. In contrast, hybrid (organic and inorganic) crystals such as…

Using density-functional theory calculations, we analyze the optical absorption properties of lead (Pb)-free metal halide perovskites (AB$^{2+}$X$_3$) and double perovskites (AB$^+$B$^{3+}$X$_6$) (A = Cs or monovalent organic ion, B$^{2+}$…

Materials Science · Physics 2017-06-19 Weiwei Meng , Xiaoming Wang , Zewen Xiao , Jianbo Wang , David Mitzi , Yanfa Yan

Metal halide perovskites are promising materials for optoelectronic applications owing to their outstanding optical and electronic properties. Among them, all-inorganic perovskites such as CsPbBr$_3$ offer superior thermal and chemical…

The high photoluminescence efficiency, color purity, extended gamut, and solution processability make low-dimensional hybrid perovskites attractive for light-emitting diode (PeLED) applications. However, controlling the microstructure of…

Lead-free halide double perovskites with the formula of quaternary A$_2^+$B'B'$^{3+}$X$_6^-$ have recently attracted intense interest as alternatives to lead-halide-perovskite-based optoelectronic materials for their non-toxicity and…

Materials Science · Physics 2018-08-17 Tianshu Li , Xingang Zhao , Dongwen Yang , Mao-Hua Du , Lijun Zhang

The lead-free halide double perovskite class of materials offers a promising venue for resolving issues related to toxicity of Pb and long-term stability of the lead-containing halide perovskites. We present a first-principles study of the…

Materials Science · Physics 2020-07-29 Johan Klarbring , Olle Hellman , Igor A. Abrikosov , Sergei I. Simak

Lead-halide perovskites have demonstrated astonishing increases in power conversion efficiency in photovoltaics over the last decade. The most efficient perovskite devices now outperform industry-standard multi-crystalline silicon solar…

Applied Physics · Physics 2023-02-20 Yi-Teng Huang , Sean R. Kavanagh , David O. Scanlon , Aron Walsh , Robert L. Z. Hoye

Lead halide perovskites have emerged as promising materials for optoelectronic applications due to their exceptional properties. In the all-inorganic CsPbBr3 perovskites, ferroelastic domains formed during phase transitions enhance bulk…

Metal halide perovskites (MHPs) are low-temperature processable hybrid semiconductor materials with exceptional performances that are revolutionizing the field of optoelectronic devices. Despite their great potential, commercial deployment…

Lead-free halide double perovskites provide a promising solution for the long-standing issues of lead-containing halide perovskites, i.e., the toxicity of Pb and the low stability under ambient conditions and high-intensity illumination.…

Materials Science · Physics 2024-06-14 Guang Wang , Jiongzhi Zheng , Jie Xue , Yixin Xu , Qiye Zheng , Geoffroy Hautier , Haipeng Lu , Yanguang Zhou

Novel halide perovskites with improved stability and optoelectronic properties can be designed via composition engineering at cation and/or anion sites. Data-driven methods, especially high-throughput first principles computations and…

Materials Science · Physics 2023-02-13 Jiaqi Yang , Panayotis Manganaris , Arun Mannodi-Kanakkithodi

Lead poisoning and notorious ambient instability in lead-based halide perovskites pave the way for the exploration of alternative materials for affordable and efficient solar cell fabrication. An important prerequisite to this end is the…