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A better understanding of interfacial mechanisms is needed to improve the performances of electrochemical devices. Yet, simulating an electrode surface at fixed electrolyte composition remains a challenge. Here we apply a finite electric…

Materials Science · Physics 2019-11-13 Thomas Dufils , Guillaume Jeanmairet , Benjamin Rotenberg , Michiel Sprik , Mathieu Salanne

Surfaces of ionic solids interacting with an ionic solution can build up charge by exchange of ions. The surface charge is compensated by a strip of excess charge at the border of the electrolyte forming an electric double layer. These…

Chemical Physics · Physics 2016-12-21 Chao Zhang , Michiel Sprik

The goal of this paper is to study the electrostatic field due to an arbitrary charge distribution on a dielectric layer in a dielectric-loaded rectangular waveguide. In order to obtain this electrostatic field, the potential due to a point…

Classical Physics · Physics 2020-05-05 A. Berenguer , A. Coves , F. Mesa , E. Bronchalo , B. Gimeno , V. Boria

For a wide class of noninteracting tight-binding models in one dimension we present an analytical solution for all scattering and edge states on a half-infinite system. Without assuming any symmetry constraints we consider models with…

Mesoscale and Nanoscale Physics · Physics 2020-04-14 Mikhail Pletyukhov , Dante M. Kennes , Jelena Klinovaja , Daniel Loss , Herbert Schoeller

We develop an efficient Ewald method of molecular dynamics simulation for calculating the electrostatic interactions among charged and polar particles between parallel metallic plates, where we may apply an electric field with an arbitrary…

Soft Condensed Matter · Physics 2013-10-01 Kyohei Takae , Akira Onuki

Globular proteins as well as recently synthesized colloids engineered with differently charged surface regions have in common a reduced bonding valence and a complex interaction pattern dominated by like-charge attraction and…

Soft Condensed Matter · Physics 2024-02-02 Daniele Notarmuzi , Emanuela Bianchi

We develop an exact electrostatic formulation for a finite-length conducting cylindrical shell of finite thickness separating two dielectric media with arbitrary permittivity contrast. The boundary-value problem is reduced to a coupled…

Classical Physics · Physics 2026-01-06 J. Ricardo de Sousa

The study of the electrical double layer lies at the heart of colloidal and interfacial science. The standard mean-field Poisson-Boltzmann (PB) theory is incapable of modeling many phenomena originated from ion correlation. An important…

Soft Condensed Matter · Physics 2022-09-26 Nikhil R. Agrawal , Rui Wang

The response of a model micro-electrochemical system to a time-dependent applied voltage is analyzed. The article begins with a fresh historical review including electrochemistry, colloidal science, and microfluidics. The model problem…

Soft Condensed Matter · Physics 2009-11-10 Martin Z. Bazant , Katsuyo Thornton , Armand Ajdari

We study the problem of charge regulation and its effects on electrostatic interactions between dissociable charge groups immersed in a univalent electrolyte, within a family of one dimensional exactly solvable models. We consider the case…

Soft Condensed Matter · Physics 2015-06-23 A. C. Maggs , R. Podgornik

A finite difference method is constructed for a singularly perturbed convection diffusion problem posed on an annulus. The method involves combining polar coordinates, an upwind finite difference operator and a piecewise-uniform Shishkin…

Numerical Analysis · Mathematics 2018-04-20 Alan F. Hegarty , Eugene O'Riordan

In this work, the electrohydrodynamic (EHD) instability induced by a unipolar charge injection is extended from a single-phase dielectric liquid to a two-phase system that consists of a liquid-air interface. A volume of fluid (VOF) model…

Fluid Dynamics · Physics 2022-01-05 Qiang Liu , Alberto T. Pérez , R. Deepak Selvakumar , Pengfei Yang , Jian Wu

Two main approaches in particle-based simulations for modeling a charged surface are using explicit, discrete charges and continuum, uniform charges. It is well-known that these two approaches could lead to substantially distinct ionic…

Soft Condensed Matter · Physics 2022-08-02 Jiaxing Yuan , Yanwei Wang

We present a graph-based numerical method for solving hyperbolic systems of conservation laws using discontinuous finite elements. This work fills important gaps in the theory as well as practice of graph-based schemes. In particular, four…

Numerical Analysis · Mathematics 2025-05-21 Martin Kronbichler , Matthias Maier , Ignacio Tomas

This paper deals with a non-standard finite difference scheme defined on a quasi-uniform mesh for approximate solutions of the MHD boundary layer flow of an incompressible fluid past a flat plate for a wide range of the magnetic parameter.…

Numerical Analysis · Mathematics 2020-03-16 Riccardo Fazio , Alessandra Jannelli

We describe theoretically ``electrolubrication'' in liquid mixtures, the phenomenon where an electric field applied transverse to the confining surfaces leads to concentration gradients that alter the flow profile significantly. When the…

Fluid Dynamics · Physics 2024-05-08 Roni Kroll , Yoav Tsori

In a model of a gate-patterned quantum device it is important to choose the correct electrostatic boundary conditions (BCs) in order to match experiment. In this study, we model gated-patterned devices in doped and undoped GaAs…

We propose a finite element method for the numerical simulation of electroconvection of thin liquid crystals. The liquid is located in between two concentric circular electrodes which are either assumed to be of infinite height or slim.…

Numerical Analysis · Mathematics 2020-01-29 Andrea Bonito , Peng Wei

Two-dimensional (2D) electronic materials are of significant technological interest due to their exceptional properties and broad applicability in engineering. The transition from nanoscale physics, that dictates their stable…

Analysis of PDEs · Mathematics 2025-09-23 Shoham Sen , Yang Wang , Timothy Breitzman , Kaushik Dayal

Manipulation of the charge of the dielectric interface between two bulk liquids not only enables the adjustment of the interfacial tension but also controls the storage capacity of ions in the ionic double layers adjacent to each side of…

Soft Condensed Matter · Physics 2018-03-14 Marise J. E. Westbroek , Niels Boon , René van Roij
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