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The metal-insulator transition (MIT) of VO2 is discussed with particular emphasis on the structural instability of the rutile compounds toward dimerization. Ti substitution experiments reveal that the MIT is robust up to 20% Ti…

Strongly Correlated Electrons · Physics 2022-02-01 Zenji Hiroi

The metal-insulator transition and unconventional metallic transport in vanadium dioxide (VO$_2$) are investigated with a combination of spectroscopic ellipsometry and reflectance measurements. The data indicates that electronic…

Strongly Correlated Electrons · Physics 2009-11-11 M. M. Qazilbash , K. S. Burch , D. Whisler , D. Shrekenhamer , B. G. Chae , H. T. Kim , D. N. Basov

We investigated optical absorption coefficient spectra of an epitaxial VO2 film in wide photon energy (0.5 - 5.0 eV) and temperature (100 - 380 K) regions. In its insulating phase, we observed two d-d transition peaks around 1.3 eV and 2.7…

Strongly Correlated Electrons · Physics 2007-05-23 C. H. Koo , J. S. Lee , M. W. Kim , Y. J. Chang , T. W. Noh , J. H. Jung B. G. Chae , H. -T. Kim

The metal-insulator transition (MIT) observed in vanadium dioxide (VO2) has been a topic of great research interest for past decades, with the underlying physics yet not fully understood due to the complex electron interactions and…

Materials Science · Physics 2023-05-23 Atul Atul , Majid Ahmadi , Panagiotis Koutsogiannis , Heng Zhang , Bart J. Kooi

We directly trace the near- and mid-infrared transmission change of a VO$_2$ thin film during an ultrafast insulator-to-metal transition triggered by high-field multi-terahertz transients. Non-thermal switching into a metastable metallic…

Strongly Correlated Electrons · Physics 2015-06-11 B. Mayer , C. Schmidt , A. Grupp , J. Bühler , J. Oelmann , R. E. Marvel , R. F. Haglund , T. Oka , D. Brida , A. Leitenstorfer , A. Pashkin

Thin films of VO$_2$ on different substrates, Al$_2$O$_3$ and SiO$_2$/Si, have been prepared and characterized from room temperature up to 360 K. From the band structure in the rutile metallic phase and in the monoclinic insulating phase…

Strongly Correlated Electrons · Physics 2016-09-21 Tobias Peterseim , Martin Dressel , Marc Dietrich , Angelika Polity

We investigate the differences in the dynamics of the ultrafast photo-induced metal-insulator transition (MIT) of two VO$_2$ thin films deposited on different substrates, TiO$_2$ and Al$_2$O$_3$, and in particular the temperature dependence…

The correlation-driven metal-insulator transition (MIT) of BaVS$_3$ was studied by polarized infrared spectroscopy. In the metallic state two types of electrons coexist at the Fermi energy: The quasi 1D metallic transport of $A_{1g}$…

Strongly Correlated Electrons · Physics 2014-01-15 I. Kezsmarki , G. Mihaly , R. Gaal , N. Barisic , A. Akrap , H. Berger , L. Forro , C. C. Homes , L. Mihaly

Iron oxide is a key compound to understand the state of the deep Earth. It has been believed that previously known oxides such as FeO and Fe2O3 will be dominant at the mantle conditions. However, recent observation of FeO2 shed another…

Strongly Correlated Electrons · Physics 2017-03-01 Bo Gyu Jang , Duck Young Kim , Ji Hoon Shim

We combine ultrafast electron diffraction and time-resolved terahertz spectroscopy measurements to unravel the connection between structure and electronic transport properties during the photoinduced insulator-metal transitions in vanadium…

We present evidence that the metal-insulator transition (MIT) in a tensile strained NdNiO3 (NNO) film is facilitated by a redistribution of electronic density and neither requires Ni charge disproportionation nor symmetry change [1, 2].…

Strongly Correlated Electrons · Physics 2015-07-20 M. H. Upton , Yongseong Choi , Jian Liu , D. Meyers , S. Middey , J. Chakhalian , Jong-Woo Kim , Philip J. Ryan

The metal-to-insulator transition (MIT) in rutile VO$_2$ has proven uniquely difficult to characterize because of the complex interplay between electron correlations and atomic structure. Here we report the discovery of the sudden collapse…

We use polarization- and temperature-dependent x-ray absorption spectroscopy, in combination with photoelectron microscopy, x-ray diffraction and electronic transport measurements, to study the driving force behind the insulator-metal…

Long regarded as a model system for studying insulator-to-metal phase transitions, the correlated electron material vanadium dioxide (VO$_2$) is now finding novel uses in device applications. Two of its most appealing aspects are its…

Mesoscale and Nanoscale Physics · Physics 2016-04-18 M. A. Huber , M. Plankl , M. Eisele , R. E. Marvel , F. Sandner , T. Korn , C. Schüller , R. F. Haglund, , R. Huber , T. L. Cocker

Using spin-assisted ab-initio random structure searches, we explore an exhaustive quantum phase diagram of archetypal interfaced Mott insulators, i.e. lanthanum-iron and lanthanum-titanium oxides. In particular, we report that the charge…

Strongly Correlated Electrons · Physics 2021-04-29 Carla Lupo , Evan Sheridan , Edoardo Fertitta , David Dubbink , Chris J. Pickard , Cedric Weber

The electrodynamics near the metal-to-insulator transitions (MIT) induced, in V3O5 single crystals, by both temperature (T) and pressure (P) has been studied by infrared spectroscopy. The T- and P-dependence of the optical conductivity may…

Strongly Correlated Electrons · Physics 2009-11-13 L. Baldassarre , A. Perucchi , E. Arcangeletti , D. Nicoletti , D. Di Castro , P. Postorino , V. A. Sidorov , S. Lupi

We present the influence of spin correlation on the metal-insulator transitions (MIT) in two-orbital Hubbard models by the Kotliar-Ruckenstein slave-boson approach. In the asymmetric half-filling situation, the two orbits simultaneously…

Strongly Correlated Electrons · Physics 2015-03-19 Ya-Min Quan , Liang-Jian Zou , Hai-Qing Lin

Transition metal oxides such as vanadium dioxide (VO$_2$), niobium dioxide (NbO$_2$), and titanium sesquioxide (Ti$_2$O$_3$) are known to undergo a temperature-dependent metal-insulator transition (MIT) in conjunction with a structural…

Correlated electron systems are among the centerpieces of modern condensed matter sciences, where many interesting physical phenomena, such as metal-insulator transition and high-Tc superconductivity appear. Recent efforts have been focused…

Strongly Correlated Electrons · Physics 2013-08-05 You Zhou , Shriram Ramanathan

Electronic states in disordered conductors on the verge of localization are predicted to exhibit critical spatial characteristics indicative of the proximity to a metal- insulator phase transition. We have used scanning tunneling microscopy…

Strongly Correlated Electrons · Physics 2015-05-18 Anthony Richardella , Pedram Roushan , Shawn Mack , Brian Zhou , David A. Huse , David D. Awschalom , Ali Yazdani
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